Effect of coke orientation on the electrochemical properties of lithium-ion battery anode
In this study, Needle and Regular coke, which has different crystalline and orientation characteristics, were graphitized, and the effect of crystal changes on electrochemical performance was investigated. The initial efficiency and capacity were mainly influenced by the shapes and specific surface...
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Veröffentlicht in: | Journal of applied electrochemistry 2021-10, Vol.51 (10), p.1407-1418 |
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creator | Lee, Seung Eun Kim, Ji Hong Lee, Young-Seak Im, Ji Sun |
description | In this study, Needle and Regular coke, which has different crystalline and orientation characteristics, were graphitized, and the effect of crystal changes on electrochemical performance was investigated. The initial efficiency and capacity were mainly influenced by the shapes and specific surface areas of the particles, and the graphitized sample showed excellent initial efficiency due to having a lower specific surface area (decrease in exposed edge surfaces) than the coke. However, rate performance shows excellent in the graphitized sample of regular coke due to its defects and short lithium-ion transport path.
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doi_str_mv | 10.1007/s10800-021-01581-x |
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Graphic abstract</description><identifier>ISSN: 0021-891X</identifier><identifier>EISSN: 1572-8838</identifier><identifier>DOI: 10.1007/s10800-021-01581-x</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Anode effect ; Batteries ; Chemistry ; Chemistry and Materials Science ; Coke ; Crystal defects ; Crystal structure ; Electrochemical analysis ; Electrochemistry ; Graphitization ; Industrial Chemistry/Chemical Engineering ; Ion transport ; Lithium ; Lithium-ion batteries ; Orientation effects ; Physical Chemistry ; Rechargeable batteries ; Research Article ; Specific surface ; Surface area</subject><ispartof>Journal of applied electrochemistry, 2021-10, Vol.51 (10), p.1407-1418</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-232e71b61523bf0ad61145bdb92282f869e7ffdc0c8c0524e9cc4bfbf7fd6a643</citedby><cites>FETCH-LOGICAL-c319t-232e71b61523bf0ad61145bdb92282f869e7ffdc0c8c0524e9cc4bfbf7fd6a643</cites><orcidid>0000-0003-2375-3024</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10800-021-01581-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10800-021-01581-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Lee, Seung Eun</creatorcontrib><creatorcontrib>Kim, Ji Hong</creatorcontrib><creatorcontrib>Lee, Young-Seak</creatorcontrib><creatorcontrib>Im, Ji Sun</creatorcontrib><title>Effect of coke orientation on the electrochemical properties of lithium-ion battery anode</title><title>Journal of applied electrochemistry</title><addtitle>J Appl Electrochem</addtitle><description>In this study, Needle and Regular coke, which has different crystalline and orientation characteristics, were graphitized, and the effect of crystal changes on electrochemical performance was investigated. The initial efficiency and capacity were mainly influenced by the shapes and specific surface areas of the particles, and the graphitized sample showed excellent initial efficiency due to having a lower specific surface area (decrease in exposed edge surfaces) than the coke. However, rate performance shows excellent in the graphitized sample of regular coke due to its defects and short lithium-ion transport path.
Graphic abstract</description><subject>Anode effect</subject><subject>Batteries</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coke</subject><subject>Crystal defects</subject><subject>Crystal structure</subject><subject>Electrochemical analysis</subject><subject>Electrochemistry</subject><subject>Graphitization</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Ion transport</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Orientation effects</subject><subject>Physical Chemistry</subject><subject>Rechargeable batteries</subject><subject>Research Article</subject><subject>Specific surface</subject><subject>Surface area</subject><issn>0021-891X</issn><issn>1572-8838</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKt_wNOC5-gk-5U9SqkfUPCioKeQzU5s6nZTkxTqvzfrCt6EgTnM-8wMDyGXDK4ZQH0TGAgACpxRYKVg9HBEZqysORUiF8dkBuNINOz1lJyFsAGAhlfFjLwtjUEdM2cy7T4wc97iEFW0bshSxTVm2KeAd3qNW6tVn-2826GPFsNI9Tau7X5LR6BVMaL_ytTgOjwnJ0b1AS9--5y83C2fFw909XT_uLhdUZ2zJlKec6xZW7GS560B1VWMFWXbtQ3nghtRNVgb02nQQkPJC2y0LlrTmtp0laqKfE6upr3pr889hig3bu-HdFLysirK5KcYU3xKae9C8Gjkztut8l-SgRwVykmhTJ7kj0J5SFA-QSGFh3f0f6v_ob4BEBp17A</recordid><startdate>20211001</startdate><enddate>20211001</enddate><creator>Lee, Seung Eun</creator><creator>Kim, Ji Hong</creator><creator>Lee, Young-Seak</creator><creator>Im, Ji Sun</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2375-3024</orcidid></search><sort><creationdate>20211001</creationdate><title>Effect of coke orientation on the electrochemical properties of lithium-ion battery anode</title><author>Lee, Seung Eun ; Kim, Ji Hong ; Lee, Young-Seak ; Im, Ji Sun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-232e71b61523bf0ad61145bdb92282f869e7ffdc0c8c0524e9cc4bfbf7fd6a643</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Anode effect</topic><topic>Batteries</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coke</topic><topic>Crystal defects</topic><topic>Crystal structure</topic><topic>Electrochemical analysis</topic><topic>Electrochemistry</topic><topic>Graphitization</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Ion transport</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Orientation effects</topic><topic>Physical Chemistry</topic><topic>Rechargeable batteries</topic><topic>Research Article</topic><topic>Specific surface</topic><topic>Surface area</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lee, Seung Eun</creatorcontrib><creatorcontrib>Kim, Ji Hong</creatorcontrib><creatorcontrib>Lee, Young-Seak</creatorcontrib><creatorcontrib>Im, Ji Sun</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of applied electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lee, Seung Eun</au><au>Kim, Ji Hong</au><au>Lee, Young-Seak</au><au>Im, Ji Sun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of coke orientation on the electrochemical properties of lithium-ion battery anode</atitle><jtitle>Journal of applied electrochemistry</jtitle><stitle>J Appl Electrochem</stitle><date>2021-10-01</date><risdate>2021</risdate><volume>51</volume><issue>10</issue><spage>1407</spage><epage>1418</epage><pages>1407-1418</pages><issn>0021-891X</issn><eissn>1572-8838</eissn><abstract>In this study, Needle and Regular coke, which has different crystalline and orientation characteristics, were graphitized, and the effect of crystal changes on electrochemical performance was investigated. The initial efficiency and capacity were mainly influenced by the shapes and specific surface areas of the particles, and the graphitized sample showed excellent initial efficiency due to having a lower specific surface area (decrease in exposed edge surfaces) than the coke. However, rate performance shows excellent in the graphitized sample of regular coke due to its defects and short lithium-ion transport path.
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subjects | Anode effect Batteries Chemistry Chemistry and Materials Science Coke Crystal defects Crystal structure Electrochemical analysis Electrochemistry Graphitization Industrial Chemistry/Chemical Engineering Ion transport Lithium Lithium-ion batteries Orientation effects Physical Chemistry Rechargeable batteries Research Article Specific surface Surface area |
title | Effect of coke orientation on the electrochemical properties of lithium-ion battery anode |
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