Particularities of Radiation Defect Formation in Ceramic Barium Cerate

The effects of irradiation with electrons, ions of noble gases (Ne, Ar, Kr) and oxygen on the structure and properties of neodymium-doped barium cerate have been studied using the methods of X-ray diffraction analysis, scanning electron and atomic force microscopy, thermal desorption spectroscopy. I...

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Veröffentlicht in:IOP conference series. Materials Science and Engineering 2015-04, Vol.81 (1), p.12037
Hauptverfasser: Khromushin, I V, Aksenova, T I, Tuseev, T, Munasbaeva, K K, Ermolaev, Yu V, Ermolaev, V N, Seitov, A S
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container_issue 1
container_start_page 12037
container_title IOP conference series. Materials Science and Engineering
container_volume 81
creator Khromushin, I V
Aksenova, T I
Tuseev, T
Munasbaeva, K K
Ermolaev, Yu V
Ermolaev, V N
Seitov, A S
description The effects of irradiation with electrons, ions of noble gases (Ne, Ar, Kr) and oxygen on the structure and properties of neodymium-doped barium cerate have been studied using the methods of X-ray diffraction analysis, scanning electron and atomic force microscopy, thermal desorption spectroscopy. It was shown that irradiation by low-energy ions of noble gases stimulates the blistering processes on the sample surface, while the high-energy ions contribute to formation of the structures on the irradiated surface that resemble the various stages of spherulitegrowth. The similar structures were not observed in the case of irradiation with high-energy oxygen ions. According to the data on thermal desorption of water and oxygen molecules from the irradiated barium cerate it was supposed that irradiation by the noble gas ions promotes neodymium oxidation state change. It was noticed that the electron irradiation leads to the formation of the nano-sized acicular structures on the cerate surface.
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It was shown that irradiation by low-energy ions of noble gases stimulates the blistering processes on the sample surface, while the high-energy ions contribute to formation of the structures on the irradiated surface that resemble the various stages of spherulitegrowth. The similar structures were not observed in the case of irradiation with high-energy oxygen ions. According to the data on thermal desorption of water and oxygen molecules from the irradiated barium cerate it was supposed that irradiation by the noble gas ions promotes neodymium oxidation state change. 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subjects Acicular structure
Atomic force microscopy
Barium
Blistering
Desorption
Electron irradiation
Neodymium
Oxidation
Oxygen ions
Rare gases
Thermal desorption spectroscopy
Valence
title Particularities of Radiation Defect Formation in Ceramic Barium Cerate
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