Characterization of the interfacial Li-ion exchange process in a ceramic-polymer composite by solid state NMR
Solid-state electrolytes are key for the development of high energy density and safe Li-batteries. A very strong research effort has been made for the development of ceramic-polymer composite solid electrolytes that combine the high ionic conductivity of the ceramic phase with the ease of processabi...
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| Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2021-09, Vol.9 (33), p.17812-1782 |
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| container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
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| creator | Ranque, Pierre Zagórski, Jakub Devaraj, Shanmukaraj Aguesse, Frédéric López del Amo, Juan Miguel |
| description | Solid-state electrolytes are key for the development of high energy density and safe Li-batteries. A very strong research effort has been made for the development of ceramic-polymer composite solid electrolytes that combine the high ionic conductivity of the ceramic phase with the ease of processability of the polymeric membrane. A crucial question for the development of such composite membranes is the detection and quantification of the Li-ion exchange processes existing at the interface between the polymer and ceramic particles. Using multidimensional solid-state NMR experiments, we unequivocally demonstrate and characterize in this work the Li-ion exchange process present in a PEO:LiTFSI-LLZO composite material. The exchange process is observed between bulk Li-ion populations in both phases, and is not only restricted to the exchange processes occurring at the interface. LiOH is detected in the composite material and its role in the polymer-ceramic Li-ion exchange process is discussed. The results obtained in this work illustrate the suitability of solid-state NMR for the characterization and rational design of interfacial Li-ion exchange properties in next generation polymer-ceramic composite materials.
Li-ion exchange mechanism in ceramic-polymer composite electrolytes. |
| doi_str_mv | 10.1039/d1ta03720j |
| format | Article |
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Li-ion exchange mechanism in ceramic-polymer composite electrolytes.</description><subject>Batteries</subject><subject>Ceramics</subject><subject>Composite materials</subject><subject>Curve fitting</subject><subject>Electrolytes</subject><subject>Flux density</subject><subject>Ion currents</subject><subject>Ion exchange</subject><subject>Ionic mobility</subject><subject>Lithium</subject><subject>Lithium ions</subject><subject>Membranes</subject><subject>Molten salt electrolytes</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Polymer matrix composites</subject><subject>Polymers</subject><subject>Solid electrolytes</subject><subject>Solid state</subject><subject>X-ray diffraction</subject><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpFkEtLAzEUhQdRsGg37oWAO2E070mWpb6pClLXQyaT2JSZSU1SsP56Uyv1bu7r49zLKYozBK8QJPK6RUlBUmG4PChGGDJYVlTyw30txHExjnEJcwgIuZSjop8uVFA6meC-VXJ-AN6CtDDADXlmlXaqAzNXbjfmSy_U8GHAKnhtYswMUECboHqny5XvNr0JQPt-5aNLBjQbEH3nWhCTyu3L89tpcWRVF834L58U73e38-lDOXu9f5xOZqXGAqXSkraFouGItryB1DKtWaMwl0TQRlJhKG6xZarilZEcKYtZC61kjFa0sYqQk-Jip5s__VybmOqlX4chn6wx40QQIRjN1OWO0sHHGIytV8H1KmxqBOuto_UNmk9-HX3K8PkODlHvuX_HyQ80VXMK</recordid><startdate>20210907</startdate><enddate>20210907</enddate><creator>Ranque, Pierre</creator><creator>Zagórski, Jakub</creator><creator>Devaraj, Shanmukaraj</creator><creator>Aguesse, Frédéric</creator><creator>López del Amo, Juan Miguel</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7ST</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0003-3222-0983</orcidid><orcidid>https://orcid.org/0000-0001-8315-2699</orcidid></search><sort><creationdate>20210907</creationdate><title>Characterization of the interfacial Li-ion exchange process in a ceramic-polymer composite by solid state NMR</title><author>Ranque, Pierre ; Zagórski, Jakub ; Devaraj, Shanmukaraj ; Aguesse, Frédéric ; López del Amo, Juan Miguel</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-f3dd08b614d6b04f5cc5ba269384b948e42d2f5a767e961af25d0f955474bfa33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Batteries</topic><topic>Ceramics</topic><topic>Composite materials</topic><topic>Curve fitting</topic><topic>Electrolytes</topic><topic>Flux density</topic><topic>Ion currents</topic><topic>Ion exchange</topic><topic>Ionic mobility</topic><topic>Lithium</topic><topic>Lithium ions</topic><topic>Membranes</topic><topic>Molten salt electrolytes</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Polymer matrix composites</topic><topic>Polymers</topic><topic>Solid electrolytes</topic><topic>Solid state</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ranque, Pierre</creatorcontrib><creatorcontrib>Zagórski, Jakub</creatorcontrib><creatorcontrib>Devaraj, Shanmukaraj</creatorcontrib><creatorcontrib>Aguesse, Frédéric</creatorcontrib><creatorcontrib>López del Amo, Juan Miguel</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ranque, Pierre</au><au>Zagórski, Jakub</au><au>Devaraj, Shanmukaraj</au><au>Aguesse, Frédéric</au><au>López del Amo, Juan Miguel</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of the interfacial Li-ion exchange process in a ceramic-polymer composite by solid state NMR</atitle><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle><date>2021-09-07</date><risdate>2021</risdate><volume>9</volume><issue>33</issue><spage>17812</spage><epage>1782</epage><pages>17812-1782</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>Solid-state electrolytes are key for the development of high energy density and safe Li-batteries. A very strong research effort has been made for the development of ceramic-polymer composite solid electrolytes that combine the high ionic conductivity of the ceramic phase with the ease of processability of the polymeric membrane. A crucial question for the development of such composite membranes is the detection and quantification of the Li-ion exchange processes existing at the interface between the polymer and ceramic particles. Using multidimensional solid-state NMR experiments, we unequivocally demonstrate and characterize in this work the Li-ion exchange process present in a PEO:LiTFSI-LLZO composite material. The exchange process is observed between bulk Li-ion populations in both phases, and is not only restricted to the exchange processes occurring at the interface. LiOH is detected in the composite material and its role in the polymer-ceramic Li-ion exchange process is discussed. The results obtained in this work illustrate the suitability of solid-state NMR for the characterization and rational design of interfacial Li-ion exchange properties in next generation polymer-ceramic composite materials.
Li-ion exchange mechanism in ceramic-polymer composite electrolytes.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1ta03720j</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-3222-0983</orcidid><orcidid>https://orcid.org/0000-0001-8315-2699</orcidid></addata></record> |
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| ispartof | Journal of materials chemistry. A, Materials for energy and sustainability, 2021-09, Vol.9 (33), p.17812-1782 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Batteries Ceramics Composite materials Curve fitting Electrolytes Flux density Ion currents Ion exchange Ionic mobility Lithium Lithium ions Membranes Molten salt electrolytes NMR Nuclear magnetic resonance Polymer matrix composites Polymers Solid electrolytes Solid state X-ray diffraction |
| title | Characterization of the interfacial Li-ion exchange process in a ceramic-polymer composite by solid state NMR |
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