Antioxidant and UV-blocking glucose-crosslinked sericin films with enhanced structural integrity
The utilization of sericin should be expanded to increase the availability of silkworm silk. However, the poor mechanical properties and susceptibility to moisture of sericin have continuously restricted its use. In this study, a facile crosslinked sericin film was prepared using a glucose-induced M...
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| Veröffentlicht in: | Reactive & functional polymers 2021-08, Vol.165, p.104942, Article 104942 |
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| container_title | Reactive & functional polymers |
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| creator | Oh, Subin Park, Jinseok Nam, Jeongmin Hyun, Yujin Jin, Hyoung-Joon Kwak, Hyo Won |
| description | The utilization of sericin should be expanded to increase the availability of silkworm silk. However, the poor mechanical properties and susceptibility to moisture of sericin have continuously restricted its use. In this study, a facile crosslinked sericin film was prepared using a glucose-induced Maillard reaction, and the physicochemical properties and antioxidant functionality of the crosslinking reaction were investigated. The glucose-induced Maillard reaction can be conducted in an environmentally friendly manner through a simple heat treatment of sericin at 90 °C, and the degree of crosslinking can be adjusted by controlling the amount of added glucose. The glucose-induced Maillard reaction improves the mechanical properties of the sericin film, reduces its vulnerability in a moist environment, and provides UV protection and improved antioxidant activity.
[Display omitted]
•Using glucose as an eco-friendly crosslinking agent, a Maillard-reacted silk sericin film was successfully fabricated.•The Maillard reaction between sericin-glucose effectively improved the structural integrity of the sericin film.•The glucose-crosslinked sericin films exhibited enhanced UV-blocking and antioxidative properties. |
| doi_str_mv | 10.1016/j.reactfunctpolym.2021.104942 |
| format | Article |
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[Display omitted]
•Using glucose as an eco-friendly crosslinking agent, a Maillard-reacted silk sericin film was successfully fabricated.•The Maillard reaction between sericin-glucose effectively improved the structural integrity of the sericin film.•The glucose-crosslinked sericin films exhibited enhanced UV-blocking and antioxidative properties.</description><identifier>ISSN: 1381-5148</identifier><identifier>EISSN: 1873-166X</identifier><identifier>DOI: 10.1016/j.reactfunctpolym.2021.104942</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Antioxidant properties ; Antioxidants ; Crosslinking ; Crosslinking polymerization ; Glucose ; Heat treatment ; Maillard reaction ; Mechanical properties ; Sericin ; Silk ; Silkworms ; Structural integrity ; Thin films ; Ultraviolet radiation</subject><ispartof>Reactive & functional polymers, 2021-08, Vol.165, p.104942, Article 104942</ispartof><rights>2021 Elsevier B.V.</rights><rights>Copyright Elsevier BV Aug 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c361t-c1d7db0df6e04b64b6a70e84b0d1a1eee85a670f8bf3e3f97990b84ef7a66ef33</citedby><cites>FETCH-LOGICAL-c361t-c1d7db0df6e04b64b6a70e84b0d1a1eee85a670f8bf3e3f97990b84ef7a66ef33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.reactfunctpolym.2021.104942$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Oh, Subin</creatorcontrib><creatorcontrib>Park, Jinseok</creatorcontrib><creatorcontrib>Nam, Jeongmin</creatorcontrib><creatorcontrib>Hyun, Yujin</creatorcontrib><creatorcontrib>Jin, Hyoung-Joon</creatorcontrib><creatorcontrib>Kwak, Hyo Won</creatorcontrib><title>Antioxidant and UV-blocking glucose-crosslinked sericin films with enhanced structural integrity</title><title>Reactive & functional polymers</title><description>The utilization of sericin should be expanded to increase the availability of silkworm silk. However, the poor mechanical properties and susceptibility to moisture of sericin have continuously restricted its use. In this study, a facile crosslinked sericin film was prepared using a glucose-induced Maillard reaction, and the physicochemical properties and antioxidant functionality of the crosslinking reaction were investigated. The glucose-induced Maillard reaction can be conducted in an environmentally friendly manner through a simple heat treatment of sericin at 90 °C, and the degree of crosslinking can be adjusted by controlling the amount of added glucose. The glucose-induced Maillard reaction improves the mechanical properties of the sericin film, reduces its vulnerability in a moist environment, and provides UV protection and improved antioxidant activity.
[Display omitted]
•Using glucose as an eco-friendly crosslinking agent, a Maillard-reacted silk sericin film was successfully fabricated.•The Maillard reaction between sericin-glucose effectively improved the structural integrity of the sericin film.•The glucose-crosslinked sericin films exhibited enhanced UV-blocking and antioxidative properties.</description><subject>Antioxidant properties</subject><subject>Antioxidants</subject><subject>Crosslinking</subject><subject>Crosslinking polymerization</subject><subject>Glucose</subject><subject>Heat treatment</subject><subject>Maillard reaction</subject><subject>Mechanical properties</subject><subject>Sericin</subject><subject>Silk</subject><subject>Silkworms</subject><subject>Structural integrity</subject><subject>Thin films</subject><subject>Ultraviolet radiation</subject><issn>1381-5148</issn><issn>1873-166X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqNUEFOwzAQtBBIlMIfLCGOKXaSOsmBQ4WgIFXiQhE34zjr1m1qF9sB-nscwokT0kq72tmd0QxCV5RMKKHsejNxIGRQnZFhb9vDbpKSlEYsr_L0CI1oWWQJZez1OM5ZSZMpzctTdOb9hhBaRGSE3mYmaPulG2ECFqbBy5ekbq3carPCq7aT1kMinfW-1WYLDfbgtNQGK93uPP7UYY3BrIWRPRZcJ0PnRIu1CbByOhzO0YkSrYeL3z5Gy_u759uHZPE0f7ydLRKZMRoSSZuiqUmjGJC8ZrFEQaDM44oKCgDlVLCCqLJWGWSqKqqK1GUOqhCMgcqyMbocePfOvnfgA9_YzpkoydMpoxWLMiRe3QxXP5YcKL53eifcgVPC-1D5hv8Jlfeh8iHU-D8f_iFa-dDguJcaevPagQy8sfqfTN_sg402</recordid><startdate>202108</startdate><enddate>202108</enddate><creator>Oh, Subin</creator><creator>Park, Jinseok</creator><creator>Nam, Jeongmin</creator><creator>Hyun, Yujin</creator><creator>Jin, Hyoung-Joon</creator><creator>Kwak, Hyo Won</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>202108</creationdate><title>Antioxidant and UV-blocking glucose-crosslinked sericin films with enhanced structural integrity</title><author>Oh, Subin ; Park, Jinseok ; Nam, Jeongmin ; Hyun, Yujin ; Jin, Hyoung-Joon ; Kwak, Hyo Won</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-c1d7db0df6e04b64b6a70e84b0d1a1eee85a670f8bf3e3f97990b84ef7a66ef33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Antioxidant properties</topic><topic>Antioxidants</topic><topic>Crosslinking</topic><topic>Crosslinking polymerization</topic><topic>Glucose</topic><topic>Heat treatment</topic><topic>Maillard reaction</topic><topic>Mechanical properties</topic><topic>Sericin</topic><topic>Silk</topic><topic>Silkworms</topic><topic>Structural integrity</topic><topic>Thin films</topic><topic>Ultraviolet radiation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Oh, Subin</creatorcontrib><creatorcontrib>Park, Jinseok</creatorcontrib><creatorcontrib>Nam, Jeongmin</creatorcontrib><creatorcontrib>Hyun, Yujin</creatorcontrib><creatorcontrib>Jin, Hyoung-Joon</creatorcontrib><creatorcontrib>Kwak, Hyo Won</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Reactive & functional polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oh, Subin</au><au>Park, Jinseok</au><au>Nam, Jeongmin</au><au>Hyun, Yujin</au><au>Jin, Hyoung-Joon</au><au>Kwak, Hyo Won</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Antioxidant and UV-blocking glucose-crosslinked sericin films with enhanced structural integrity</atitle><jtitle>Reactive & functional polymers</jtitle><date>2021-08</date><risdate>2021</risdate><volume>165</volume><spage>104942</spage><pages>104942-</pages><artnum>104942</artnum><issn>1381-5148</issn><eissn>1873-166X</eissn><abstract>The utilization of sericin should be expanded to increase the availability of silkworm silk. However, the poor mechanical properties and susceptibility to moisture of sericin have continuously restricted its use. In this study, a facile crosslinked sericin film was prepared using a glucose-induced Maillard reaction, and the physicochemical properties and antioxidant functionality of the crosslinking reaction were investigated. The glucose-induced Maillard reaction can be conducted in an environmentally friendly manner through a simple heat treatment of sericin at 90 °C, and the degree of crosslinking can be adjusted by controlling the amount of added glucose. The glucose-induced Maillard reaction improves the mechanical properties of the sericin film, reduces its vulnerability in a moist environment, and provides UV protection and improved antioxidant activity.
[Display omitted]
•Using glucose as an eco-friendly crosslinking agent, a Maillard-reacted silk sericin film was successfully fabricated.•The Maillard reaction between sericin-glucose effectively improved the structural integrity of the sericin film.•The glucose-crosslinked sericin films exhibited enhanced UV-blocking and antioxidative properties.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.reactfunctpolym.2021.104942</doi></addata></record> |
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| issn | 1381-5148 1873-166X |
| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Antioxidant properties Antioxidants Crosslinking Crosslinking polymerization Glucose Heat treatment Maillard reaction Mechanical properties Sericin Silk Silkworms Structural integrity Thin films Ultraviolet radiation |
| title | Antioxidant and UV-blocking glucose-crosslinked sericin films with enhanced structural integrity |
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