Study on pyrolysis characteristics and kinetics of mixed plastic waste
Different types of plastic wastes have caused serious environmental problems. Co-pyrolysis and separation techniques are being widely used because of the complex components of plastic wastes. In this study, Thermogravimetric Analysis for mixed plastics with different compositions (Polypropylene/Poly...
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Veröffentlicht in: | Journal of material cycles and waste management 2021-09, Vol.23 (5), p.1984-1994 |
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container_end_page | 1994 |
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container_issue | 5 |
container_start_page | 1984 |
container_title | Journal of material cycles and waste management |
container_volume | 23 |
creator | Yin, Fengfu Zhuang, Qianxiao Chang, Tianhao Zhang, Chao Sun, Huadong Sun, Qikun Wang, Chuansheng Li, Lin |
description | Different types of plastic wastes have caused serious environmental problems. Co-pyrolysis and separation techniques are being widely used because of the complex components of plastic wastes. In this study, Thermogravimetric Analysis for mixed plastics with different compositions (Polypropylene/Polyvinyl chloride and Polypropylene/Polyvinyl chloride/Polystyrene mixtures) was carried out under three heating rates. Aiming at the complex pyrolysis reaction process of mixed plastics, a model-free method and a model-fitting method were combined to obtain the complete kinetics, which makes the results more reliable. The activation energy of the mixture pyrolysis process was carried out by the model-free method, and two stages of pyrolysis mechanism functions were summarized in the model-fitting method. Verification test proves that the mechanism function of this research can be reliable to express the pyrolysis reaction process. This research can provide support for the optimization of pyrolysis process parameters and the design of pyrolysis reactors for chlorine-containing mixed plastics. |
doi_str_mv | 10.1007/s10163-021-01271-y |
format | Article |
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Co-pyrolysis and separation techniques are being widely used because of the complex components of plastic wastes. In this study, Thermogravimetric Analysis for mixed plastics with different compositions (Polypropylene/Polyvinyl chloride and Polypropylene/Polyvinyl chloride/Polystyrene mixtures) was carried out under three heating rates. Aiming at the complex pyrolysis reaction process of mixed plastics, a model-free method and a model-fitting method were combined to obtain the complete kinetics, which makes the results more reliable. The activation energy of the mixture pyrolysis process was carried out by the model-free method, and two stages of pyrolysis mechanism functions were summarized in the model-fitting method. Verification test proves that the mechanism function of this research can be reliable to express the pyrolysis reaction process. This research can provide support for the optimization of pyrolysis process parameters and the design of pyrolysis reactors for chlorine-containing mixed plastics.</description><identifier>ISSN: 1438-4957</identifier><identifier>EISSN: 1611-8227</identifier><identifier>DOI: 10.1007/s10163-021-01271-y</identifier><language>eng</language><publisher>Tokyo: Springer Japan</publisher><subject>Chlorides ; Chlorine ; Civil Engineering ; Design parameters ; Engineering ; Environmental Management ; Kinetics ; Optimization ; Original Article ; Plastic debris ; Plastics ; Polypropylene ; Polystyrene ; Polystyrene resins ; Polyvinyl chloride ; Process parameters ; Pyrolysis ; Separation techniques ; Thermogravimetric analysis ; Waste Management/Waste Technology ; Wastes</subject><ispartof>Journal of material cycles and waste management, 2021-09, Vol.23 (5), p.1984-1994</ispartof><rights>Springer Japan KK, part of Springer Nature 2021</rights><rights>Springer Japan KK, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-7a558506779d067583826065166771d25f17e33d2e9ec67b7ce6e9ccf44d5153</citedby><cites>FETCH-LOGICAL-c319t-7a558506779d067583826065166771d25f17e33d2e9ec67b7ce6e9ccf44d5153</cites><orcidid>0000-0001-6626-5210</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10163-021-01271-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10163-021-01271-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Yin, Fengfu</creatorcontrib><creatorcontrib>Zhuang, Qianxiao</creatorcontrib><creatorcontrib>Chang, Tianhao</creatorcontrib><creatorcontrib>Zhang, Chao</creatorcontrib><creatorcontrib>Sun, Huadong</creatorcontrib><creatorcontrib>Sun, Qikun</creatorcontrib><creatorcontrib>Wang, Chuansheng</creatorcontrib><creatorcontrib>Li, Lin</creatorcontrib><title>Study on pyrolysis characteristics and kinetics of mixed plastic waste</title><title>Journal of material cycles and waste management</title><addtitle>J Mater Cycles Waste Manag</addtitle><description>Different types of plastic wastes have caused serious environmental problems. Co-pyrolysis and separation techniques are being widely used because of the complex components of plastic wastes. In this study, Thermogravimetric Analysis for mixed plastics with different compositions (Polypropylene/Polyvinyl chloride and Polypropylene/Polyvinyl chloride/Polystyrene mixtures) was carried out under three heating rates. Aiming at the complex pyrolysis reaction process of mixed plastics, a model-free method and a model-fitting method were combined to obtain the complete kinetics, which makes the results more reliable. The activation energy of the mixture pyrolysis process was carried out by the model-free method, and two stages of pyrolysis mechanism functions were summarized in the model-fitting method. Verification test proves that the mechanism function of this research can be reliable to express the pyrolysis reaction process. This research can provide support for the optimization of pyrolysis process parameters and the design of pyrolysis reactors for chlorine-containing mixed plastics.</description><subject>Chlorides</subject><subject>Chlorine</subject><subject>Civil Engineering</subject><subject>Design parameters</subject><subject>Engineering</subject><subject>Environmental Management</subject><subject>Kinetics</subject><subject>Optimization</subject><subject>Original Article</subject><subject>Plastic debris</subject><subject>Plastics</subject><subject>Polypropylene</subject><subject>Polystyrene</subject><subject>Polystyrene resins</subject><subject>Polyvinyl chloride</subject><subject>Process parameters</subject><subject>Pyrolysis</subject><subject>Separation techniques</subject><subject>Thermogravimetric analysis</subject><subject>Waste Management/Waste 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Co-pyrolysis and separation techniques are being widely used because of the complex components of plastic wastes. In this study, Thermogravimetric Analysis for mixed plastics with different compositions (Polypropylene/Polyvinyl chloride and Polypropylene/Polyvinyl chloride/Polystyrene mixtures) was carried out under three heating rates. Aiming at the complex pyrolysis reaction process of mixed plastics, a model-free method and a model-fitting method were combined to obtain the complete kinetics, which makes the results more reliable. The activation energy of the mixture pyrolysis process was carried out by the model-free method, and two stages of pyrolysis mechanism functions were summarized in the model-fitting method. Verification test proves that the mechanism function of this research can be reliable to express the pyrolysis reaction process. This research can provide support for the optimization of pyrolysis process parameters and the design of pyrolysis reactors for chlorine-containing mixed plastics.</abstract><cop>Tokyo</cop><pub>Springer Japan</pub><doi>10.1007/s10163-021-01271-y</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0001-6626-5210</orcidid></addata></record> |
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subjects | Chlorides Chlorine Civil Engineering Design parameters Engineering Environmental Management Kinetics Optimization Original Article Plastic debris Plastics Polypropylene Polystyrene Polystyrene resins Polyvinyl chloride Process parameters Pyrolysis Separation techniques Thermogravimetric analysis Waste Management/Waste Technology Wastes |
title | Study on pyrolysis characteristics and kinetics of mixed plastic waste |
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