Study on pyrolysis characteristics and kinetics of mixed plastic waste

Different types of plastic wastes have caused serious environmental problems. Co-pyrolysis and separation techniques are being widely used because of the complex components of plastic wastes. In this study, Thermogravimetric Analysis for mixed plastics with different compositions (Polypropylene/Poly...

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Veröffentlicht in:Journal of material cycles and waste management 2021-09, Vol.23 (5), p.1984-1994
Hauptverfasser: Yin, Fengfu, Zhuang, Qianxiao, Chang, Tianhao, Zhang, Chao, Sun, Huadong, Sun, Qikun, Wang, Chuansheng, Li, Lin
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container_end_page 1994
container_issue 5
container_start_page 1984
container_title Journal of material cycles and waste management
container_volume 23
creator Yin, Fengfu
Zhuang, Qianxiao
Chang, Tianhao
Zhang, Chao
Sun, Huadong
Sun, Qikun
Wang, Chuansheng
Li, Lin
description Different types of plastic wastes have caused serious environmental problems. Co-pyrolysis and separation techniques are being widely used because of the complex components of plastic wastes. In this study, Thermogravimetric Analysis for mixed plastics with different compositions (Polypropylene/Polyvinyl chloride and Polypropylene/Polyvinyl chloride/Polystyrene mixtures) was carried out under three heating rates. Aiming at the complex pyrolysis reaction process of mixed plastics, a model-free method and a model-fitting method were combined to obtain the complete kinetics, which makes the results more reliable. The activation energy of the mixture pyrolysis process was carried out by the model-free method, and two stages of pyrolysis mechanism functions were summarized in the model-fitting method. Verification test proves that the mechanism function of this research can be reliable to express the pyrolysis reaction process. This research can provide support for the optimization of pyrolysis process parameters and the design of pyrolysis reactors for chlorine-containing mixed plastics.
doi_str_mv 10.1007/s10163-021-01271-y
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Co-pyrolysis and separation techniques are being widely used because of the complex components of plastic wastes. In this study, Thermogravimetric Analysis for mixed plastics with different compositions (Polypropylene/Polyvinyl chloride and Polypropylene/Polyvinyl chloride/Polystyrene mixtures) was carried out under three heating rates. Aiming at the complex pyrolysis reaction process of mixed plastics, a model-free method and a model-fitting method were combined to obtain the complete kinetics, which makes the results more reliable. The activation energy of the mixture pyrolysis process was carried out by the model-free method, and two stages of pyrolysis mechanism functions were summarized in the model-fitting method. Verification test proves that the mechanism function of this research can be reliable to express the pyrolysis reaction process. 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issn 1438-4957
1611-8227
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subjects Chlorides
Chlorine
Civil Engineering
Design parameters
Engineering
Environmental Management
Kinetics
Optimization
Original Article
Plastic debris
Plastics
Polypropylene
Polystyrene
Polystyrene resins
Polyvinyl chloride
Process parameters
Pyrolysis
Separation techniques
Thermogravimetric analysis
Waste Management/Waste Technology
Wastes
title Study on pyrolysis characteristics and kinetics of mixed plastic waste
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