Radical Cascade Bicyclization/Aromatization of 1,7‐Enynes with 1,3‐Dicarbonyl Compounds towards 2,3‐Dihydro‐1H‐cyclopentanaphthalenes

Radical Cascade Bicyclization/Aromatization of 1,7‐Enynes with 1,3‐Dicarbonyl Compounds towards 2,3‐Dihydro‐1H‐cyclopentanaphthalenes

An Ag‐catalyzed radical cascade bicyclization/aromatization of C‐linked 1,7‐enynes with 1,3‐dicarbonyls has been achieved, providing a step‐ and atom‐economy approach for the construction of 2,3‐dihydro‐1H‐cyclopenta[a]naphthalenes, an important structural scaffold existed in biologically active com...

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Veröffentlicht in:Advanced synthesis & catalysis 2021-08, Vol.363 (15), p.3750-3755
Hauptverfasser: Cai, Tao, Zhang, Zhebing, Li, Peiqin, Sun, Tao, Chen, Xinyu, Ni, Yuqi, Chen, Jianhui, Xu, Huiting, Xu, Yanfei, Wu, Chunlei, Shen, Runpu, Gao, Yuzhen
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Carbonyl compounds
Regioselectivity
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container_issue 15
container_start_page 3750
container_title Advanced synthesis & catalysis
container_volume 363
creator Cai, Tao
Zhang, Zhebing
Li, Peiqin
Sun, Tao
Chen, Xinyu
Ni, Yuqi
Chen, Jianhui
Xu, Huiting
Xu, Yanfei
Wu, Chunlei
Shen, Runpu
Gao, Yuzhen
description An Ag‐catalyzed radical cascade bicyclization/aromatization of C‐linked 1,7‐enynes with 1,3‐dicarbonyls has been achieved, providing a step‐ and atom‐economy approach for the construction of 2,3‐dihydro‐1H‐cyclopenta[a]naphthalenes, an important structural scaffold existed in biologically active compounds. From this transformation, structurally diverse 2,3‐dihydro‐1H‐cyclopenta[a]naphthalenes were obtained in moderate to good yields with high regioselectivity. Moreover, the further product derivatizations were also exemplified.
doi_str_mv 10.1002/adsc.202100678
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subjects Carbonyl compounds
Regioselectivity
title Radical Cascade Bicyclization/Aromatization of 1,7‐Enynes with 1,3‐Dicarbonyl Compounds towards 2,3‐Dihydro‐1H‐cyclopentanaphthalenes
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