Study on conductive mechanism of graphene conductive and anticorrosive coatings on steel bar surface in concrete
When conductive and anticorrosive coatings are applied on the surface of reinforcing bars, electrochemical protection measures can be taken when the construction need secondary maintenance. Because graphene is a sp2 hybrid honeycomb structure, higher conductivity can be obtained by adding a small am...
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Veröffentlicht in: | IOP conference series. Earth and environmental science 2019-09, Vol.304 (5), p.52101 |
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description | When conductive and anticorrosive coatings are applied on the surface of reinforcing bars, electrochemical protection measures can be taken when the construction need secondary maintenance. Because graphene is a sp2 hybrid honeycomb structure, higher conductivity can be obtained by adding a small amount of graphene in the coating. In this paper, graphene-based conductive anticorrosive coatings were prepared with mixed conductive fillers (acetylene carbon black, conductive carbon black, graphite, graphene and zinc powder). The conductive mechanism was determined by studying the effects of conductive properties on the change of the content of different conductive fillers and analyzing the microstructural characteristics of conductive coatings with XRD, SEM, TEM and Raman spectroscopy tests. The results show that the conductivity of mixed fillers with different shapes in coatings is better than that of single filler in coatings when the filler content is the same. Because of the flexible structure and thin layer of graphene, the isolated fillers and conductive paths in different areas of the coatings can be connected with it and the conductive efficiency can be improved. The conductive paths are formed by the contact among conductive fillers in the coatings. Finally, the conductive mechanism model of graphene conductive and anticorrosive coatings was established. |
doi_str_mv | 10.1088/1755-1315/304/5/052101 |
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Because graphene is a sp2 hybrid honeycomb structure, higher conductivity can be obtained by adding a small amount of graphene in the coating. In this paper, graphene-based conductive anticorrosive coatings were prepared with mixed conductive fillers (acetylene carbon black, conductive carbon black, graphite, graphene and zinc powder). The conductive mechanism was determined by studying the effects of conductive properties on the change of the content of different conductive fillers and analyzing the microstructural characteristics of conductive coatings with XRD, SEM, TEM and Raman spectroscopy tests. The results show that the conductivity of mixed fillers with different shapes in coatings is better than that of single filler in coatings when the filler content is the same. Because of the flexible structure and thin layer of graphene, the isolated fillers and conductive paths in different areas of the coatings can be connected with it and the conductive efficiency can be improved. The conductive paths are formed by the contact among conductive fillers in the coatings. Finally, the conductive mechanism model of graphene conductive and anticorrosive coatings was established.</description><identifier>ISSN: 1755-1307</identifier><identifier>EISSN: 1755-1315</identifier><identifier>DOI: 10.1088/1755-1315/304/5/052101</identifier><language>eng</language><publisher>Bristol: IOP Publishing</publisher><subject>Acetylene ; Black carbon ; Carbon ; Carbon black ; Coatings ; Concrete ; Conductivity ; Corrosion prevention ; Electrochemistry ; Fillers ; Flexible structures ; Graphene ; Honeycomb structures ; Protective coatings ; Raman spectroscopy ; Rebar</subject><ispartof>IOP conference series. Earth and environmental science, 2019-09, Vol.304 (5), p.52101</ispartof><rights>Published under licence by IOP Publishing Ltd</rights><rights>2019. This work is published under http://creativecommons.org/licenses/by/3.0/ (the “License”). 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Earth and environmental science</title><addtitle>IOP Conf. Ser.: Earth Environ. Sci</addtitle><description>When conductive and anticorrosive coatings are applied on the surface of reinforcing bars, electrochemical protection measures can be taken when the construction need secondary maintenance. Because graphene is a sp2 hybrid honeycomb structure, higher conductivity can be obtained by adding a small amount of graphene in the coating. In this paper, graphene-based conductive anticorrosive coatings were prepared with mixed conductive fillers (acetylene carbon black, conductive carbon black, graphite, graphene and zinc powder). The conductive mechanism was determined by studying the effects of conductive properties on the change of the content of different conductive fillers and analyzing the microstructural characteristics of conductive coatings with XRD, SEM, TEM and Raman spectroscopy tests. The results show that the conductivity of mixed fillers with different shapes in coatings is better than that of single filler in coatings when the filler content is the same. Because of the flexible structure and thin layer of graphene, the isolated fillers and conductive paths in different areas of the coatings can be connected with it and the conductive efficiency can be improved. The conductive paths are formed by the contact among conductive fillers in the coatings. Finally, the conductive mechanism model of graphene conductive and anticorrosive coatings was established.</description><subject>Acetylene</subject><subject>Black carbon</subject><subject>Carbon</subject><subject>Carbon black</subject><subject>Coatings</subject><subject>Concrete</subject><subject>Conductivity</subject><subject>Corrosion prevention</subject><subject>Electrochemistry</subject><subject>Fillers</subject><subject>Flexible structures</subject><subject>Graphene</subject><subject>Honeycomb structures</subject><subject>Protective coatings</subject><subject>Raman spectroscopy</subject><subject>Rebar</subject><issn>1755-1307</issn><issn>1755-1315</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>O3W</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNqFkF1LwzAUhoMoOKd_QQLeeFObjyZpL2XMKQy8mF6HNB9bx9bUpBX2722tTAXBi8M55Lzve8gDwDVGdxjleYoFYwmmmKUUZSlLESMY4RMwOS5OjzMS5-Aixi1CXGS0mIBm1XbmAH0Nta9Np9vq3cK91RtVV3EPvYProJqNre1PgapNX22lfQg-Di_aq7aq13FIiq21O1iqAGMXnNIWVp_xOtjWXoIzp3bRXn31KXh9mL_MHpPl8-Jpdr9MNCUEJ7k2peDGYU0L5GiBDdFEIG4KQnOOC2MQFUXmMmswUjkXyqESUUyopqXKOJ2CmzG3Cf6ts7GVW9-Fuj8pCWMi50xkolfxUaX7f8RgnWxCtVfhIDGSA105gJMDRNnTlUyOdHsjGY2Vb76T_zXd_mGaz1e_ZLIxjn4AUt2Jsg</recordid><startdate>20190901</startdate><enddate>20190901</enddate><creator>Zhang, Xingduo</creator><creator>Sun, Hongyao</creator><creator>Qian, Benlei</creator><creator>Sun, Gaoxia</creator><general>IOP Publishing</general><scope>O3W</scope><scope>TSCCA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>PATMY</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PYCSY</scope></search><sort><creationdate>20190901</creationdate><title>Study on conductive mechanism of graphene conductive and anticorrosive coatings on steel bar surface in concrete</title><author>Zhang, Xingduo ; Sun, Hongyao ; Qian, Benlei ; Sun, Gaoxia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3221-8cdb76df1c390f391d2c2706d9238619dd03794f4ed10a867af0b03123c3ba463</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Acetylene</topic><topic>Black carbon</topic><topic>Carbon</topic><topic>Carbon black</topic><topic>Coatings</topic><topic>Concrete</topic><topic>Conductivity</topic><topic>Corrosion prevention</topic><topic>Electrochemistry</topic><topic>Fillers</topic><topic>Flexible structures</topic><topic>Graphene</topic><topic>Honeycomb structures</topic><topic>Protective coatings</topic><topic>Raman spectroscopy</topic><topic>Rebar</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Xingduo</creatorcontrib><creatorcontrib>Sun, Hongyao</creatorcontrib><creatorcontrib>Qian, Benlei</creatorcontrib><creatorcontrib>Sun, Gaoxia</creatorcontrib><collection>IOP Publishing Free Content</collection><collection>IOPscience (Open Access)</collection><collection>CrossRef</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Environmental Science Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Environmental Science Collection</collection><jtitle>IOP conference series. Earth and environmental science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Xingduo</au><au>Sun, Hongyao</au><au>Qian, Benlei</au><au>Sun, Gaoxia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study on conductive mechanism of graphene conductive and anticorrosive coatings on steel bar surface in concrete</atitle><jtitle>IOP conference series. Earth and environmental science</jtitle><addtitle>IOP Conf. Ser.: Earth Environ. Sci</addtitle><date>2019-09-01</date><risdate>2019</risdate><volume>304</volume><issue>5</issue><spage>52101</spage><pages>52101-</pages><issn>1755-1307</issn><eissn>1755-1315</eissn><abstract>When conductive and anticorrosive coatings are applied on the surface of reinforcing bars, electrochemical protection measures can be taken when the construction need secondary maintenance. Because graphene is a sp2 hybrid honeycomb structure, higher conductivity can be obtained by adding a small amount of graphene in the coating. In this paper, graphene-based conductive anticorrosive coatings were prepared with mixed conductive fillers (acetylene carbon black, conductive carbon black, graphite, graphene and zinc powder). The conductive mechanism was determined by studying the effects of conductive properties on the change of the content of different conductive fillers and analyzing the microstructural characteristics of conductive coatings with XRD, SEM, TEM and Raman spectroscopy tests. The results show that the conductivity of mixed fillers with different shapes in coatings is better than that of single filler in coatings when the filler content is the same. Because of the flexible structure and thin layer of graphene, the isolated fillers and conductive paths in different areas of the coatings can be connected with it and the conductive efficiency can be improved. 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subjects | Acetylene Black carbon Carbon Carbon black Coatings Concrete Conductivity Corrosion prevention Electrochemistry Fillers Flexible structures Graphene Honeycomb structures Protective coatings Raman spectroscopy Rebar |
title | Study on conductive mechanism of graphene conductive and anticorrosive coatings on steel bar surface in concrete |
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