Divergent α-functionalization of cyclic amines via ring construction by molecular O2 oxidized dearomatization and ring deconstruction by aromatization-driven C–C σ-bond cleavage

An efficient approach to achieve the divergent α-C(sp3)–H functionalization of cyclic amines through a rationally designed ring construction and ring deconstruction strategy was developed. A variety of spiro cyclohexadienone decorated cyclic amines were obtained via ring construction by molecular O2...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Green chemistry : an international journal and green chemistry resource : GC 2021-01, Vol.23 (15), p.5535-5541
Hauptverfasser:	Hu, Fangzhi, Wang, Liang, Ge, Chunyan, Li, Xinyao, Ding, Zhanshuai, Lubin, Xu, Li, Shuai-Shuai
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines Cleavage Construction Covalent bonds Crystallography Deconstruction Green chemistry Hydrogen bonds Reagents
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!