Facile synthesis of heterojunctions by hydrothermal decoration of CdS on electrospun BiVO4 nanofibers with boosted photocatalytic activity

Bismuth vanadate (BiVO 4 ) is a promising photocatalyst material for photocatalytic degradation of organic pollutions. However, the fast recombination of photo-induced charge and insufficient light absorption often lead to poor photocatalytic performance. Herein, novel fibrous BiVO 4 /CdS (BVO/CdS)...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2021-08, Vol.32 (15), p.20891-20902
Hauptverfasser: Peng, Long-Gui, Ni, Fu-Rong, Liu, Jun, Sun, Meng, Chang, Meng-Jie, Xi, Tong, Li, Hui-Lu, Du, Hui-Ling, Yang, Jie, Li, Ying
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container_end_page 20902
container_issue 15
container_start_page 20891
container_title Journal of materials science. Materials in electronics
container_volume 32
creator Peng, Long-Gui
Ni, Fu-Rong
Liu, Jun
Sun, Meng
Chang, Meng-Jie
Xi, Tong
Li, Hui-Lu
Du, Hui-Ling
Yang, Jie
Li, Ying
description Bismuth vanadate (BiVO 4 ) is a promising photocatalyst material for photocatalytic degradation of organic pollutions. However, the fast recombination of photo-induced charge and insufficient light absorption often lead to poor photocatalytic performance. Herein, novel fibrous BiVO 4 /CdS (BVO/CdS) heterostructures are constructed by uniformly modifying caterpillar shaped electrospun BiVO 4 nanofibers with controllable quantity of CdS nanoparticles through hydrothermal reaction. The absorption of visible light and separation efficiency of photo-generated charge of BiVO 4 are significantly promoted after the decoration of CdS nanoparticles. As a result, the photocatalytic efficiency of the optimized BVO/CdS sample (BVO/CdS-2 stands for the sample synthesized with 0.05 mmol Cd(CH 3 COO) 2 and CH 4 N 2 S) is 90.43%, which is 3.3 times as high as that of pure BiVO 4 after 180 min irradiation under visible light, respectively. Moreover, the .O 2 − and .OH are the predominant active species for the degradation process indicated by scavengers added photocatalytic experiments. Due to the simple, low-cost and controllable synthetic process, the BVO/CdS heterojunctions are suitable for practical usage.
doi_str_mv 10.1007/s10854-021-06605-y
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However, the fast recombination of photo-induced charge and insufficient light absorption often lead to poor photocatalytic performance. Herein, novel fibrous BiVO 4 /CdS (BVO/CdS) heterostructures are constructed by uniformly modifying caterpillar shaped electrospun BiVO 4 nanofibers with controllable quantity of CdS nanoparticles through hydrothermal reaction. The absorption of visible light and separation efficiency of photo-generated charge of BiVO 4 are significantly promoted after the decoration of CdS nanoparticles. As a result, the photocatalytic efficiency of the optimized BVO/CdS sample (BVO/CdS-2 stands for the sample synthesized with 0.05 mmol Cd(CH 3 COO) 2 and CH 4 N 2 S) is 90.43%, which is 3.3 times as high as that of pure BiVO 4 after 180 min irradiation under visible light, respectively. Moreover, the .O 2 − and .OH are the predominant active species for the degradation process indicated by scavengers added photocatalytic experiments. Due to the simple, low-cost and controllable synthetic process, the BVO/CdS heterojunctions are suitable for practical usage.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-021-06605-y</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Bismuth oxides ; Catalytic activity ; Characterization and Evaluation of Materials ; Charge efficiency ; Chemistry and Materials Science ; Decoration ; Electromagnetic absorption ; Electrospinning ; Heterojunctions ; Heterostructures ; Hydrothermal reactions ; Materials Science ; Nanofibers ; Nanoparticles ; Optical and Electronic Materials ; Photocatalysis ; Photodegradation ; Vanadates</subject><ispartof>Journal of materials science. 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Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>Bismuth vanadate (BiVO 4 ) is a promising photocatalyst material for photocatalytic degradation of organic pollutions. However, the fast recombination of photo-induced charge and insufficient light absorption often lead to poor photocatalytic performance. Herein, novel fibrous BiVO 4 /CdS (BVO/CdS) heterostructures are constructed by uniformly modifying caterpillar shaped electrospun BiVO 4 nanofibers with controllable quantity of CdS nanoparticles through hydrothermal reaction. The absorption of visible light and separation efficiency of photo-generated charge of BiVO 4 are significantly promoted after the decoration of CdS nanoparticles. 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Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2021-08-01</date><risdate>2021</risdate><volume>32</volume><issue>15</issue><spage>20891</spage><epage>20902</epage><pages>20891-20902</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>Bismuth vanadate (BiVO 4 ) is a promising photocatalyst material for photocatalytic degradation of organic pollutions. However, the fast recombination of photo-induced charge and insufficient light absorption often lead to poor photocatalytic performance. Herein, novel fibrous BiVO 4 /CdS (BVO/CdS) heterostructures are constructed by uniformly modifying caterpillar shaped electrospun BiVO 4 nanofibers with controllable quantity of CdS nanoparticles through hydrothermal reaction. The absorption of visible light and separation efficiency of photo-generated charge of BiVO 4 are significantly promoted after the decoration of CdS nanoparticles. 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subjects Bismuth oxides
Catalytic activity
Characterization and Evaluation of Materials
Charge efficiency
Chemistry and Materials Science
Decoration
Electromagnetic absorption
Electrospinning
Heterojunctions
Heterostructures
Hydrothermal reactions
Materials Science
Nanofibers
Nanoparticles
Optical and Electronic Materials
Photocatalysis
Photodegradation
Vanadates
title Facile synthesis of heterojunctions by hydrothermal decoration of CdS on electrospun BiVO4 nanofibers with boosted photocatalytic activity
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