New Heterocyclization Reactions of N′-Substituted N-(2,2-Dichloro-1-cyanoethenyl)ureas with Aliphatic Amines
The reaction of substituted 3,3-dichloroprop-2-enenitriles containing an N -methylurea or N,N -dimethylurea residue in the second position with secondary aliphatic amines gives rise to previously unknown 2,5-bis(alkylamino)-1,3-oxazole-4-carbonitriles. In the case of the reaction of N -(2,2-dichloro...
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| Veröffentlicht in: | Russian journal of general chemistry 2021-06, Vol.91 (6), p.966-970 |
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| container_title | Russian journal of general chemistry |
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| creator | Kornii, Yu. E. Chumachenko, S. A. Shablykin, O. V. Rusanov, E. B. Brovarets, V. S. |
| description | The reaction of substituted 3,3-dichloroprop-2-enenitriles containing an
N
-methylurea or
N,N
-dimethylurea residue in the second position with secondary aliphatic amines gives rise to previously unknown 2,5-bis(alkylamino)-1,3-oxazole-4-carbonitriles. In the case of the reaction of
N
-(2,2-dichloro-1-cyanoethenyl)-
N′
-methylureas with benzylamines, 4,5-bis(alkylamino)-1-methyl-1
H
-imidazol-2(5
H
)-ones were obtained. |
| doi_str_mv | 10.1134/S1070363221060025 |
| format | Article |
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N
-methylurea or
N,N
-dimethylurea residue in the second position with secondary aliphatic amines gives rise to previously unknown 2,5-bis(alkylamino)-1,3-oxazole-4-carbonitriles. In the case of the reaction of
N
-(2,2-dichloro-1-cyanoethenyl)-
N′
-methylureas with benzylamines, 4,5-bis(alkylamino)-1-methyl-1
H
-imidazol-2(5
H
)-ones were obtained.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363221060025</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aliphatic amines ; Amines ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Oxazole ; Oxazoles ; Substitutes</subject><ispartof>Russian journal of general chemistry, 2021-06, Vol.91 (6), p.966-970</ispartof><rights>Pleiades Publishing, Ltd. 2021</rights><rights>COPYRIGHT 2021 Springer</rights><rights>Pleiades Publishing, Ltd. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c307t-a50d24db0c1d6de2b1e091cfd681783ce90d3475e7121a6f9db251fdf80743b13</cites><orcidid>0000-0003-4266-8773 ; 0000-0001-6810-9860 ; 0000-0001-6668-3412 ; 0000-0001-7020-8622 ; 0000-0002-7678-0985</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070363221060025$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070363221060025$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Kornii, Yu. E.</creatorcontrib><creatorcontrib>Chumachenko, S. A.</creatorcontrib><creatorcontrib>Shablykin, O. V.</creatorcontrib><creatorcontrib>Rusanov, E. B.</creatorcontrib><creatorcontrib>Brovarets, V. S.</creatorcontrib><title>New Heterocyclization Reactions of N′-Substituted N-(2,2-Dichloro-1-cyanoethenyl)ureas with Aliphatic Amines</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>The reaction of substituted 3,3-dichloroprop-2-enenitriles containing an
N
-methylurea or
N,N
-dimethylurea residue in the second position with secondary aliphatic amines gives rise to previously unknown 2,5-bis(alkylamino)-1,3-oxazole-4-carbonitriles. In the case of the reaction of
N
-(2,2-dichloro-1-cyanoethenyl)-
N′
-methylureas with benzylamines, 4,5-bis(alkylamino)-1-methyl-1
H
-imidazol-2(5
H
)-ones were obtained.</description><subject>Aliphatic amines</subject><subject>Amines</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Oxazole</subject><subject>Oxazoles</subject><subject>Substitutes</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kcGKFDEQhhtxwXXXB_DW4EVhs1Yl3enu47C6rrCM4Oq5SSeVnSw9yZikWcaTz-Qj-SRmGMGDSB2qqPq_vwqqql4iXCKK5u0dQgdCCs4RJABvn1SnKKFnQrTwtNRlzA7zZ9XzlB4AEEDy08qv6bG-oUwx6L2e3XeVXfD1Z1L6UKQ62Hr968dPdrdMKbu8ZDL1mr3mF5y9c3ozhxgYMr1XPlDekN_Pb5ZIKtWPLm_q1ex2m2Kp69XWeUrn1YlVc6IXf_JZ9fX6_ZerG3b76cPHq9Ut0wK6zFQLhjdmAo1GGuITEgyorZE9dr3QNIARTddShxyVtIOZeIvW2B66RkwozqpXR99dDN8WSnl8CEv0ZeXI21b2sm_6pqguj6p7NdPovA05Kl3C0Nbp4Mm60l912It-aAdRADwCOoaUItlxF91Wxf2IMB7-MP7zh8LwI5OK1t9T_HvK_6HfyVaJ8A</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Kornii, Yu. E.</creator><creator>Chumachenko, S. A.</creator><creator>Shablykin, O. V.</creator><creator>Rusanov, E. B.</creator><creator>Brovarets, V. S.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-4266-8773</orcidid><orcidid>https://orcid.org/0000-0001-6810-9860</orcidid><orcidid>https://orcid.org/0000-0001-6668-3412</orcidid><orcidid>https://orcid.org/0000-0001-7020-8622</orcidid><orcidid>https://orcid.org/0000-0002-7678-0985</orcidid></search><sort><creationdate>20210601</creationdate><title>New Heterocyclization Reactions of N′-Substituted N-(2,2-Dichloro-1-cyanoethenyl)ureas with Aliphatic Amines</title><author>Kornii, Yu. E. ; Chumachenko, S. A. ; Shablykin, O. V. ; Rusanov, E. B. ; Brovarets, V. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c307t-a50d24db0c1d6de2b1e091cfd681783ce90d3475e7121a6f9db251fdf80743b13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aliphatic amines</topic><topic>Amines</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Oxazole</topic><topic>Oxazoles</topic><topic>Substitutes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kornii, Yu. E.</creatorcontrib><creatorcontrib>Chumachenko, S. A.</creatorcontrib><creatorcontrib>Shablykin, O. V.</creatorcontrib><creatorcontrib>Rusanov, E. B.</creatorcontrib><creatorcontrib>Brovarets, V. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kornii, Yu. E.</au><au>Chumachenko, S. A.</au><au>Shablykin, O. V.</au><au>Rusanov, E. B.</au><au>Brovarets, V. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New Heterocyclization Reactions of N′-Substituted N-(2,2-Dichloro-1-cyanoethenyl)ureas with Aliphatic Amines</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2021-06-01</date><risdate>2021</risdate><volume>91</volume><issue>6</issue><spage>966</spage><epage>970</epage><pages>966-970</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>The reaction of substituted 3,3-dichloroprop-2-enenitriles containing an
N
-methylurea or
N,N
-dimethylurea residue in the second position with secondary aliphatic amines gives rise to previously unknown 2,5-bis(alkylamino)-1,3-oxazole-4-carbonitriles. In the case of the reaction of
N
-(2,2-dichloro-1-cyanoethenyl)-
N′
-methylureas with benzylamines, 4,5-bis(alkylamino)-1-methyl-1
H
-imidazol-2(5
H
)-ones were obtained.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070363221060025</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-4266-8773</orcidid><orcidid>https://orcid.org/0000-0001-6810-9860</orcidid><orcidid>https://orcid.org/0000-0001-6668-3412</orcidid><orcidid>https://orcid.org/0000-0001-7020-8622</orcidid><orcidid>https://orcid.org/0000-0002-7678-0985</orcidid></addata></record> |
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| issn | 1070-3632 1608-3350 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Aliphatic amines Amines Chemistry Chemistry and Materials Science Chemistry/Food Science Oxazole Oxazoles Substitutes |
| title | New Heterocyclization Reactions of N′-Substituted N-(2,2-Dichloro-1-cyanoethenyl)ureas with Aliphatic Amines |
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