A liquid phase anion-exchange approach to high-quality all-inorganic halide perovskite micro- and nanowires

All-inorganic halide perovskite nanowires (NWs) are promising materials due to they have broad application prospects in the field of optoelectronics, with mixed-halide perovskite nanowires can change the optoelectronic properties by adjusting the halide ratio. Here, we experimentally investigated th...

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Veröffentlicht in:Journal of materials science 2021-10, Vol.56 (28), p.16059-16067
Hauptverfasser: Li, Huafeng, Li, Jing, Bao, Yanan, Li, Jianliang, He, Chengyu, Wang, Hengshan, Zhang, Yajing, Tang, Huayi, Xu, Jiao, Fang, Yurui, Liang, Shuang, Yang, Yiming
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container_issue 28
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container_title Journal of materials science
container_volume 56
creator Li, Huafeng
Li, Jing
Bao, Yanan
Li, Jianliang
He, Chengyu
Wang, Hengshan
Zhang, Yajing
Tang, Huayi
Xu, Jiao
Fang, Yurui
Liang, Shuang
Yang, Yiming
description All-inorganic halide perovskite nanowires (NWs) are promising materials due to they have broad application prospects in the field of optoelectronics, with mixed-halide perovskite nanowires can change the optoelectronic properties by adjusting the halide ratio. Here, we experimentally investigated the two-process governed anion-exchange reaction in single-crystalline CsPbX 3 micro- and nanowires. The critical parameters affecting the outcome of the reaction are identified as the reaction temperature, reaction time, and precursor concentrations. Upon examining the photoluminescence and morphology of the NWs, high-quality NWs were obtained by optimizing these critical parameters. The bandgap of the NWs can be tuned over the entire visible spectra (430–700 nm). In addition, photodetectors incorporating single NWs were fabricated, which demonstrated excellent responsivity under illumination. Our results expand the validity of liquid-phase anion exchange to the microscale, and lay the basis for liquid-processed optoelectronics and displays.
doi_str_mv 10.1007/s10853-021-06316-z
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subjects Anion exchanging
Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Crystallography and Scattering Methods
Energy Materials
Liquid phases
Materials Science
Morphology
Nanowires
Optoelectronics
Parameter identification
Perovskite
Perovskites
Photoluminescence
Polymer Sciences
Reaction time
Single crystals
Solid Mechanics
title A liquid phase anion-exchange approach to high-quality all-inorganic halide perovskite micro- and nanowires
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