Effects of lithium source and electrochemical window on the properties of Li1.2Fe0.16Ni0.24Mn0.4O2 cathode material prepared by oxalate co-precipitation method
Due to the limitation of the theoretical specific capacity of traditional cathode materials, the key to improve the energy density of lithium-ion batteries (LIBs) is to develop high-performance cathode materials. As a promising cathode material for LIBs, Fe-containing lithium-rich manganese-based ma...
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| Veröffentlicht in: | Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology 2021-02, Vol.23 (2), Article 43 |
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| creator | Zhao, Taolin Shen, Jiangang Si, Huayan Zhang, Yuxia |
| description | Due to the limitation of the theoretical specific capacity of traditional cathode materials, the key to improve the energy density of lithium-ion batteries (LIBs) is to develop high-performance cathode materials. As a promising cathode material for LIBs, Fe-containing lithium-rich manganese-based materials possess high specific capacity and high working voltage. At present, the research on the synthesis and electrochemical reaction mechanism of this kind of material is still imperfect. Here, a facile oxalate co-precipitation method is employed to prepare Li
1.2
Fe
0.16
Ni
0.24
Mn
0.4
O
2
using different lithium sources. The effects of lithium source and electrochemical window on the specific capacity and cyclic stability of the materials are also systematically investigated. When applied in LIBs, the prepared material using LiNO
3
as lithium source presents a micro-nano hierarchical structure and exhibits a high first discharge specific capacity of 337.7 mAh g
−1
and a high reversible capacity of 208.4 mAh g
−1
after 60 cycles at 0.1 C in the voltage range of 1.5 − 4.8 V. The results of this study can provide more selectivity for the lithium source of the electrode material during the preparation process, and select a suitable voltage test range for cathode materials to achieve specific properties. The outstanding performances make this oxalate co-precipitation process a prospective method to prepare high-capacity cathode materials for LIBs.
Graphical abstract |
| doi_str_mv | 10.1007/s11051-021-05159-8 |
| format | Article |
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1.2
Fe
0.16
Ni
0.24
Mn
0.4
O
2
using different lithium sources. The effects of lithium source and electrochemical window on the specific capacity and cyclic stability of the materials are also systematically investigated. When applied in LIBs, the prepared material using LiNO
3
as lithium source presents a micro-nano hierarchical structure and exhibits a high first discharge specific capacity of 337.7 mAh g
−1
and a high reversible capacity of 208.4 mAh g
−1
after 60 cycles at 0.1 C in the voltage range of 1.5 − 4.8 V. The results of this study can provide more selectivity for the lithium source of the electrode material during the preparation process, and select a suitable voltage test range for cathode materials to achieve specific properties. The outstanding performances make this oxalate co-precipitation process a prospective method to prepare high-capacity cathode materials for LIBs.
Graphical abstract</description><identifier>ISSN: 1388-0764</identifier><identifier>EISSN: 1572-896X</identifier><identifier>DOI: 10.1007/s11051-021-05159-8</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Cathodes ; Characterization and Evaluation of Materials ; Chemical precipitation ; Chemical synthesis ; Chemistry and Materials Science ; Coprecipitation ; Electric potential ; Electrochemistry ; Electrode materials ; Flux density ; Inorganic Chemistry ; Iron ; Lasers ; Lithium ; Lithium-ion batteries ; Manganese ; Materials Science ; Nanoparticles ; Nanotechnology ; Optical Devices ; Optics ; Oxalic acid ; Photonics ; Physical Chemistry ; Reaction mechanisms ; Rechargeable batteries ; Research Paper ; Selectivity ; Specific capacity ; Structural hierarchy ; Voltage</subject><ispartof>Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology, 2021-02, Vol.23 (2), Article 43</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. part of Springer Nature 2021.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-a339c536f167d91464e8461fd3c823a87438b79c72841adf29710d0ac5dff2dc3</citedby><cites>FETCH-LOGICAL-c386t-a339c536f167d91464e8461fd3c823a87438b79c72841adf29710d0ac5dff2dc3</cites><orcidid>0000-0003-0799-3386</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11051-021-05159-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11051-021-05159-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Zhao, Taolin</creatorcontrib><creatorcontrib>Shen, Jiangang</creatorcontrib><creatorcontrib>Si, Huayan</creatorcontrib><creatorcontrib>Zhang, Yuxia</creatorcontrib><title>Effects of lithium source and electrochemical window on the properties of Li1.2Fe0.16Ni0.24Mn0.4O2 cathode material prepared by oxalate co-precipitation method</title><title>Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology</title><addtitle>J Nanopart Res</addtitle><description>Due to the limitation of the theoretical specific capacity of traditional cathode materials, the key to improve the energy density of lithium-ion batteries (LIBs) is to develop high-performance cathode materials. As a promising cathode material for LIBs, Fe-containing lithium-rich manganese-based materials possess high specific capacity and high working voltage. At present, the research on the synthesis and electrochemical reaction mechanism of this kind of material is still imperfect. Here, a facile oxalate co-precipitation method is employed to prepare Li
1.2
Fe
0.16
Ni
0.24
Mn
0.4
O
2
using different lithium sources. The effects of lithium source and electrochemical window on the specific capacity and cyclic stability of the materials are also systematically investigated. When applied in LIBs, the prepared material using LiNO
3
as lithium source presents a micro-nano hierarchical structure and exhibits a high first discharge specific capacity of 337.7 mAh g
−1
and a high reversible capacity of 208.4 mAh g
−1
after 60 cycles at 0.1 C in the voltage range of 1.5 − 4.8 V. The results of this study can provide more selectivity for the lithium source of the electrode material during the preparation process, and select a suitable voltage test range for cathode materials to achieve specific properties. The outstanding performances make this oxalate co-precipitation process a prospective method to prepare high-capacity cathode materials for LIBs.
Graphical abstract</description><subject>Cathodes</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical precipitation</subject><subject>Chemical synthesis</subject><subject>Chemistry and Materials Science</subject><subject>Coprecipitation</subject><subject>Electric potential</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Flux density</subject><subject>Inorganic Chemistry</subject><subject>Iron</subject><subject>Lasers</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Manganese</subject><subject>Materials Science</subject><subject>Nanoparticles</subject><subject>Nanotechnology</subject><subject>Optical Devices</subject><subject>Optics</subject><subject>Oxalic acid</subject><subject>Photonics</subject><subject>Physical Chemistry</subject><subject>Reaction mechanisms</subject><subject>Rechargeable batteries</subject><subject>Research Paper</subject><subject>Selectivity</subject><subject>Specific capacity</subject><subject>Structural 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of lithium source and electrochemical window on the properties of Li1.2Fe0.16Ni0.24Mn0.4O2 cathode material prepared by oxalate co-precipitation method</title><author>Zhao, Taolin ; Shen, Jiangang ; Si, Huayan ; Zhang, Yuxia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-a339c536f167d91464e8461fd3c823a87438b79c72841adf29710d0ac5dff2dc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Cathodes</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical precipitation</topic><topic>Chemical synthesis</topic><topic>Chemistry and Materials Science</topic><topic>Coprecipitation</topic><topic>Electric potential</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Flux density</topic><topic>Inorganic Chemistry</topic><topic>Iron</topic><topic>Lasers</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Manganese</topic><topic>Materials Science</topic><topic>Nanoparticles</topic><topic>Nanotechnology</topic><topic>Optical Devices</topic><topic>Optics</topic><topic>Oxalic acid</topic><topic>Photonics</topic><topic>Physical Chemistry</topic><topic>Reaction mechanisms</topic><topic>Rechargeable batteries</topic><topic>Research Paper</topic><topic>Selectivity</topic><topic>Specific capacity</topic><topic>Structural hierarchy</topic><topic>Voltage</topic><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Taolin</creatorcontrib><creatorcontrib>Shen, Jiangang</creatorcontrib><creatorcontrib>Si, Huayan</creatorcontrib><creatorcontrib>Zhang, Yuxia</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Biotechnology Research Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and 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Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Taolin</au><au>Shen, Jiangang</au><au>Si, Huayan</au><au>Zhang, Yuxia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of lithium source and electrochemical window on the properties of Li1.2Fe0.16Ni0.24Mn0.4O2 cathode material prepared by oxalate co-precipitation method</atitle><jtitle>Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology</jtitle><stitle>J Nanopart Res</stitle><date>2021-02-01</date><risdate>2021</risdate><volume>23</volume><issue>2</issue><artnum>43</artnum><issn>1388-0764</issn><eissn>1572-896X</eissn><abstract>Due to the limitation of the theoretical specific capacity of traditional cathode materials, the key to improve the energy density of lithium-ion batteries (LIBs) is to develop high-performance cathode materials. As a promising cathode material for LIBs, Fe-containing lithium-rich manganese-based materials possess high specific capacity and high working voltage. At present, the research on the synthesis and electrochemical reaction mechanism of this kind of material is still imperfect. Here, a facile oxalate co-precipitation method is employed to prepare Li
1.2
Fe
0.16
Ni
0.24
Mn
0.4
O
2
using different lithium sources. The effects of lithium source and electrochemical window on the specific capacity and cyclic stability of the materials are also systematically investigated. When applied in LIBs, the prepared material using LiNO
3
as lithium source presents a micro-nano hierarchical structure and exhibits a high first discharge specific capacity of 337.7 mAh g
−1
and a high reversible capacity of 208.4 mAh g
−1
after 60 cycles at 0.1 C in the voltage range of 1.5 − 4.8 V. The results of this study can provide more selectivity for the lithium source of the electrode material during the preparation process, and select a suitable voltage test range for cathode materials to achieve specific properties. The outstanding performances make this oxalate co-precipitation process a prospective method to prepare high-capacity cathode materials for LIBs.
Graphical abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11051-021-05159-8</doi><orcidid>https://orcid.org/0000-0003-0799-3386</orcidid></addata></record> |
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| subjects | Cathodes Characterization and Evaluation of Materials Chemical precipitation Chemical synthesis Chemistry and Materials Science Coprecipitation Electric potential Electrochemistry Electrode materials Flux density Inorganic Chemistry Iron Lasers Lithium Lithium-ion batteries Manganese Materials Science Nanoparticles Nanotechnology Optical Devices Optics Oxalic acid Photonics Physical Chemistry Reaction mechanisms Rechargeable batteries Research Paper Selectivity Specific capacity Structural hierarchy Voltage |
| title | Effects of lithium source and electrochemical window on the properties of Li1.2Fe0.16Ni0.24Mn0.4O2 cathode material prepared by oxalate co-precipitation method |
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