The synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN based coatings
More and more attention has been paid to AlCrN coatings with self-lubricating property and high temperature oxidation resistance. In this study, the synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN coatings is investigated in detail. With V is gradually repla...
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| Veröffentlicht in: | Surface & coatings technology 2021-04, Vol.412, p.127082, Article 127082 |
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| creator | Chen, Yu Zhang, Zhijian Yuan, Tiechui Mei, Fangsheng Lin, Xiaoliang Gao, Jiangxiong Chen, Weifei Xu, Yunbao |
| description | More and more attention has been paid to AlCrN coatings with self-lubricating property and high temperature oxidation resistance. In this study, the synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN coatings is investigated in detail. With V is gradually replaced by Si, coatings' microstructures are transformed from compact columnar to coarse columnar, and a dense fine-grained structure, and finally to a featureless dense structure. When the V content is 10 at.%, the coating is consisted of c-VN and c-Al(Cr)N solid solution phases. As decreasing the ratio of V to Si, there is only a cubic Al-Cr-V-N solid solution phase in Al0.58Cr0.31V0.08Si0.03N coating and the coexistence of c-Al(Cr)N and h-Al(Cr)N phases in Al0.58Cr0.31V0.04Si0.07N coating. The addition of Si can promote the transition from c-Al(Cr)N solid solution to h-Al(Cr)N solid solution, and finally forming a nanocomposite structure composed of h-Al(Cr)N nanocrystalline and α-Si3N4 for Al0.58Cr0.32Si0.1N coating. The performance test results indicate that the Al0.58Cr0.31V0.04Si0.07N coating has the best resistance to plastic deformation, the lowest wear rate of 2.72 × 10−16 m3·N−1·m−1 and the oxidation resistance temperature of 1000 °C attributing to the synergistic effect of V and Si.
•The synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN coatings is investigated.•Al0.58Cr0.31V0.04Si0.07N coating has the best resistance to plastic deformation.•Al0.58Cr0.31V0.04Si0.07N coating's wear rate is the lowest, 2.72 × 10−16 m3·N−1·m−1.•The oxidation resistance temperature of the Al0.58Cr0.31V0.04Si0.07N coating reaches 1000 °C. |
| doi_str_mv | 10.1016/j.surfcoat.2021.127082 |
| format | Article |
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•The synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN coatings is investigated.•Al0.58Cr0.31V0.04Si0.07N coating has the best resistance to plastic deformation.•Al0.58Cr0.31V0.04Si0.07N coating's wear rate is the lowest, 2.72 × 10−16 m3·N−1·m−1.•The oxidation resistance temperature of the Al0.58Cr0.31V0.04Si0.07N coating reaches 1000 °C.</description><identifier>ISSN: 0257-8972</identifier><identifier>EISSN: 1879-3347</identifier><identifier>DOI: 10.1016/j.surfcoat.2021.127082</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>AlCrVSiN ; Aluminum ; Coatings ; Columnar structure ; Deformation wear ; High temperature ; Microstructure ; Nanocomposites ; Oxidation ; Oxidation resistance ; Performance tests ; Plastic deformation ; Self lubrication ; Silicon ; Solid solutions ; Synergistic effect ; Synergy ; Tribological property ; Tribology ; Wear rate</subject><ispartof>Surface & coatings technology, 2021-04, Vol.412, p.127082, Article 127082</ispartof><rights>2021 Elsevier B.V.</rights><rights>Copyright Elsevier BV Apr 25, 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c340t-bee79a946c8879797d36ae6d5b007634f48e31ac1b28de05ee378f4cbeecb3123</citedby><cites>FETCH-LOGICAL-c340t-bee79a946c8879797d36ae6d5b007634f48e31ac1b28de05ee378f4cbeecb3123</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0257897221002565$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids></links><search><creatorcontrib>Chen, Yu</creatorcontrib><creatorcontrib>Zhang, Zhijian</creatorcontrib><creatorcontrib>Yuan, Tiechui</creatorcontrib><creatorcontrib>Mei, Fangsheng</creatorcontrib><creatorcontrib>Lin, Xiaoliang</creatorcontrib><creatorcontrib>Gao, Jiangxiong</creatorcontrib><creatorcontrib>Chen, Weifei</creatorcontrib><creatorcontrib>Xu, Yunbao</creatorcontrib><title>The synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN based coatings</title><title>Surface & coatings technology</title><description>More and more attention has been paid to AlCrN coatings with self-lubricating property and high temperature oxidation resistance. In this study, the synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN coatings is investigated in detail. With V is gradually replaced by Si, coatings' microstructures are transformed from compact columnar to coarse columnar, and a dense fine-grained structure, and finally to a featureless dense structure. When the V content is 10 at.%, the coating is consisted of c-VN and c-Al(Cr)N solid solution phases. As decreasing the ratio of V to Si, there is only a cubic Al-Cr-V-N solid solution phase in Al0.58Cr0.31V0.08Si0.03N coating and the coexistence of c-Al(Cr)N and h-Al(Cr)N phases in Al0.58Cr0.31V0.04Si0.07N coating. The addition of Si can promote the transition from c-Al(Cr)N solid solution to h-Al(Cr)N solid solution, and finally forming a nanocomposite structure composed of h-Al(Cr)N nanocrystalline and α-Si3N4 for Al0.58Cr0.32Si0.1N coating. The performance test results indicate that the Al0.58Cr0.31V0.04Si0.07N coating has the best resistance to plastic deformation, the lowest wear rate of 2.72 × 10−16 m3·N−1·m−1 and the oxidation resistance temperature of 1000 °C attributing to the synergistic effect of V and Si.
•The synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN coatings is investigated.•Al0.58Cr0.31V0.04Si0.07N coating has the best resistance to plastic deformation.•Al0.58Cr0.31V0.04Si0.07N coating's wear rate is the lowest, 2.72 × 10−16 m3·N−1·m−1.•The oxidation resistance temperature of the Al0.58Cr0.31V0.04Si0.07N coating reaches 1000 °C.</description><subject>AlCrVSiN</subject><subject>Aluminum</subject><subject>Coatings</subject><subject>Columnar structure</subject><subject>Deformation wear</subject><subject>High temperature</subject><subject>Microstructure</subject><subject>Nanocomposites</subject><subject>Oxidation</subject><subject>Oxidation resistance</subject><subject>Performance tests</subject><subject>Plastic deformation</subject><subject>Self lubrication</subject><subject>Silicon</subject><subject>Solid solutions</subject><subject>Synergistic effect</subject><subject>Synergy</subject><subject>Tribological property</subject><subject>Tribology</subject><subject>Wear rate</subject><issn>0257-8972</issn><issn>1879-3347</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFUMtOwzAQtBBIlMIvIEtcSfErcXKjqnhJCA4UrpbjbIqrNC62g-jf41A4oz3sYWdmZwahc0pmlNDiaj0Lg2-N03HGCKMzyiQp2QGa0FJWGedCHqIJYbnMykqyY3QSwpoQQmUlJqhbvgMOux78aoddi9-w7hv8YrHrcUynjTXehegHEwcPlzh6W7vOrazR3Q_UfdlGR5vgW--24KOFMArNu4V_wrUO0ODRm-1X4RQdtboLcPa7p-j19ma5uM8en-8eFvPHzHBBYlYDyEpXojBlSpCm4YWGoslrQmTBRStK4FQbWrOyAZIDcFm2wiSeqTllfIou9rrJ0scAIaq1G3yfXiqW50IQwohIqGKPGhMGD63aervRfqcoUWOzaq3-mlVjs2rfbCJe74mQMnxa8CoYC72BxnowUTXO_ifxDZPThnU</recordid><startdate>20210425</startdate><enddate>20210425</enddate><creator>Chen, Yu</creator><creator>Zhang, Zhijian</creator><creator>Yuan, Tiechui</creator><creator>Mei, Fangsheng</creator><creator>Lin, Xiaoliang</creator><creator>Gao, Jiangxiong</creator><creator>Chen, Weifei</creator><creator>Xu, Yunbao</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20210425</creationdate><title>The synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN based coatings</title><author>Chen, Yu ; Zhang, Zhijian ; Yuan, Tiechui ; Mei, Fangsheng ; Lin, Xiaoliang ; Gao, Jiangxiong ; Chen, Weifei ; Xu, Yunbao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c340t-bee79a946c8879797d36ae6d5b007634f48e31ac1b28de05ee378f4cbeecb3123</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>AlCrVSiN</topic><topic>Aluminum</topic><topic>Coatings</topic><topic>Columnar structure</topic><topic>Deformation wear</topic><topic>High temperature</topic><topic>Microstructure</topic><topic>Nanocomposites</topic><topic>Oxidation</topic><topic>Oxidation resistance</topic><topic>Performance tests</topic><topic>Plastic deformation</topic><topic>Self lubrication</topic><topic>Silicon</topic><topic>Solid solutions</topic><topic>Synergistic effect</topic><topic>Synergy</topic><topic>Tribological property</topic><topic>Tribology</topic><topic>Wear rate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Yu</creatorcontrib><creatorcontrib>Zhang, Zhijian</creatorcontrib><creatorcontrib>Yuan, Tiechui</creatorcontrib><creatorcontrib>Mei, Fangsheng</creatorcontrib><creatorcontrib>Lin, Xiaoliang</creatorcontrib><creatorcontrib>Gao, Jiangxiong</creatorcontrib><creatorcontrib>Chen, Weifei</creatorcontrib><creatorcontrib>Xu, Yunbao</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Surface & coatings technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Yu</au><au>Zhang, Zhijian</au><au>Yuan, Tiechui</au><au>Mei, Fangsheng</au><au>Lin, Xiaoliang</au><au>Gao, Jiangxiong</au><au>Chen, Weifei</au><au>Xu, Yunbao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN based coatings</atitle><jtitle>Surface & coatings technology</jtitle><date>2021-04-25</date><risdate>2021</risdate><volume>412</volume><spage>127082</spage><pages>127082-</pages><artnum>127082</artnum><issn>0257-8972</issn><eissn>1879-3347</eissn><abstract>More and more attention has been paid to AlCrN coatings with self-lubricating property and high temperature oxidation resistance. In this study, the synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN coatings is investigated in detail. With V is gradually replaced by Si, coatings' microstructures are transformed from compact columnar to coarse columnar, and a dense fine-grained structure, and finally to a featureless dense structure. When the V content is 10 at.%, the coating is consisted of c-VN and c-Al(Cr)N solid solution phases. As decreasing the ratio of V to Si, there is only a cubic Al-Cr-V-N solid solution phase in Al0.58Cr0.31V0.08Si0.03N coating and the coexistence of c-Al(Cr)N and h-Al(Cr)N phases in Al0.58Cr0.31V0.04Si0.07N coating. The addition of Si can promote the transition from c-Al(Cr)N solid solution to h-Al(Cr)N solid solution, and finally forming a nanocomposite structure composed of h-Al(Cr)N nanocrystalline and α-Si3N4 for Al0.58Cr0.32Si0.1N coating. The performance test results indicate that the Al0.58Cr0.31V0.04Si0.07N coating has the best resistance to plastic deformation, the lowest wear rate of 2.72 × 10−16 m3·N−1·m−1 and the oxidation resistance temperature of 1000 °C attributing to the synergistic effect of V and Si.
•The synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN coatings is investigated.•Al0.58Cr0.31V0.04Si0.07N coating has the best resistance to plastic deformation.•Al0.58Cr0.31V0.04Si0.07N coating's wear rate is the lowest, 2.72 × 10−16 m3·N−1·m−1.•The oxidation resistance temperature of the Al0.58Cr0.31V0.04Si0.07N coating reaches 1000 °C.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.surfcoat.2021.127082</doi></addata></record> |
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| subjects | AlCrVSiN Aluminum Coatings Columnar structure Deformation wear High temperature Microstructure Nanocomposites Oxidation Oxidation resistance Performance tests Plastic deformation Self lubrication Silicon Solid solutions Synergistic effect Synergy Tribological property Tribology Wear rate |
| title | The synergy of V and Si on the microstructure, tribological and oxidation properties of AlCrN based coatings |
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