Unexpected coordination behavior of ruthenium to a polymeric α-diimine containing the poly[bis(arylimino)acenaphthene] fragment

[Display omitted] •Mixtures of Ar-BIAN oligomers can be easily accessed from cheap reagents.•Cross-linking of oligomers with terephthaloyl monomers yields an insoluble polymeric ligand.•Ruthenium(II) coordinates to the amido moiety instead than to the imine in the polymeric ligand.•Different coordin...

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Veröffentlicht in:	Inorganica Chimica Acta 2021-04, Vol.518, p.120257, Article 120257
Hauptverfasser:	Ferretti, Francesco, Rota, Luca, Ragaini, Fabio
Format:	Artikel
Sprache:	eng
Schlagworte:	Aniline Carbon monoxide Coordination compounds Heterogenized catalysts Ligands N-ligands Nitrobenzene Oligomers Polyamide resins Polymeric ligands Polymers Recovery Ruthenium Ruthenium compounds Schiff bases
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