Aerogel based on nanoporous aluminium ferrocenyl diphosphinate metal-organic framework
[Display omitted] •Novel PCP-aerogel was prepared from ferrocenediyl-bis(H-phosphinic acid) and Al(NO3)3.•The as-prepared aerogel possessed high specific surface area.•N2 amount adsorbed in the pores of PCP reaches 1400 cm3g−1.•The ferrocene fragment provides the redox activity of the obtained polym...
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| Veröffentlicht in: | Inorganica Chimica Acta 2021-04, Vol.518, p.120240, Article 120240 |
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| creator | Khrizanforova, Vera V. Shekurov, Ruslan P. Nizameev, Irek R. Gerasimova, Tatiana P. Khrizanforov, Mikhail N. Bezkishko, Il'ya A. Miluykov, Vasiliy A. Budnikova, Yulia H. |
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•Novel PCP-aerogel was prepared from ferrocenediyl-bis(H-phosphinic acid) and Al(NO3)3.•The as-prepared aerogel possessed high specific surface area.•N2 amount adsorbed in the pores of PCP reaches 1400 cm3g−1.•The ferrocene fragment provides the redox activity of the obtained polymer.
New porous coordination polymer (PCP) has been synthesized using ferrocene-based ligand bearing phosphinic groups (H2fcdHp = 1,1′-ferrocenediyl-bis(H-phosphinic acid)) and aluminum salt. Al-fcdHp was obtained according to a sol–gel approach followed by supercritical CO2 drying. The N2 adsorption properties of aerogel were investigated and N2 amount adsorbed in the pores of PCP reaches 1400 cm3g−1. The aerogel exhibits high surface area of approximately 671 m2/g and redox activity due to ferrocenyl fragment. |
| doi_str_mv | 10.1016/j.ica.2020.120240 |
| format | Article |
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•Novel PCP-aerogel was prepared from ferrocenediyl-bis(H-phosphinic acid) and Al(NO3)3.•The as-prepared aerogel possessed high specific surface area.•N2 amount adsorbed in the pores of PCP reaches 1400 cm3g−1.•The ferrocene fragment provides the redox activity of the obtained polymer.
New porous coordination polymer (PCP) has been synthesized using ferrocene-based ligand bearing phosphinic groups (H2fcdHp = 1,1′-ferrocenediyl-bis(H-phosphinic acid)) and aluminum salt. Al-fcdHp was obtained according to a sol–gel approach followed by supercritical CO2 drying. The N2 adsorption properties of aerogel were investigated and N2 amount adsorbed in the pores of PCP reaches 1400 cm3g−1. The aerogel exhibits high surface area of approximately 671 m2/g and redox activity due to ferrocenyl fragment.</description><identifier>ISSN: 0020-1693</identifier><identifier>EISSN: 1873-3255</identifier><identifier>DOI: 10.1016/j.ica.2020.120240</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Aerogel ; Aerogels ; Aluminium ; Aluminum ; Coordination polymers ; Ferrocenyl diphosphinate ; Metal-organic frameworks ; Metal–organic framework ; Sol-gel processes</subject><ispartof>Inorganica Chimica Acta, 2021-04, Vol.518, p.120240, Article 120240</ispartof><rights>2020</rights><rights>Copyright Elsevier Science Ltd. Apr 1, 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c325t-2caa1799e1593b0b802c93dc321800fe5face28e63a20ad7b1f0ed937b069cd03</citedby><cites>FETCH-LOGICAL-c325t-2caa1799e1593b0b802c93dc321800fe5face28e63a20ad7b1f0ed937b069cd03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.ica.2020.120240$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Khrizanforova, Vera V.</creatorcontrib><creatorcontrib>Shekurov, Ruslan P.</creatorcontrib><creatorcontrib>Nizameev, Irek R.</creatorcontrib><creatorcontrib>Gerasimova, Tatiana P.</creatorcontrib><creatorcontrib>Khrizanforov, Mikhail N.</creatorcontrib><creatorcontrib>Bezkishko, Il'ya A.</creatorcontrib><creatorcontrib>Miluykov, Vasiliy A.</creatorcontrib><creatorcontrib>Budnikova, Yulia H.</creatorcontrib><title>Aerogel based on nanoporous aluminium ferrocenyl diphosphinate metal-organic framework</title><title>Inorganica Chimica Acta</title><description>[Display omitted]
•Novel PCP-aerogel was prepared from ferrocenediyl-bis(H-phosphinic acid) and Al(NO3)3.•The as-prepared aerogel possessed high specific surface area.•N2 amount adsorbed in the pores of PCP reaches 1400 cm3g−1.•The ferrocene fragment provides the redox activity of the obtained polymer.
New porous coordination polymer (PCP) has been synthesized using ferrocene-based ligand bearing phosphinic groups (H2fcdHp = 1,1′-ferrocenediyl-bis(H-phosphinic acid)) and aluminum salt. Al-fcdHp was obtained according to a sol–gel approach followed by supercritical CO2 drying. The N2 adsorption properties of aerogel were investigated and N2 amount adsorbed in the pores of PCP reaches 1400 cm3g−1. The aerogel exhibits high surface area of approximately 671 m2/g and redox activity due to ferrocenyl fragment.</description><subject>Aerogel</subject><subject>Aerogels</subject><subject>Aluminium</subject><subject>Aluminum</subject><subject>Coordination polymers</subject><subject>Ferrocenyl diphosphinate</subject><subject>Metal-organic frameworks</subject><subject>Metal–organic framework</subject><subject>Sol-gel processes</subject><issn>0020-1693</issn><issn>1873-3255</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9UMtOwzAQtBBIlMIHcLPEOWVtk5c4VRUvqRIX4Go5zqZ1SOxgJ6D-Pa7CmcuuVjOzOzuEXDNYMWDZbbsyWq048DjHegcnZMGKXCSCp-kpWUBEEpaV4pxchNACCMhEuiAfa_Ruhx2tVMCaOkutsm5w3k2Bqm7qjTVTTxv03mm0h47WZti7MOyNVSPSHkfVJc7vlDWaNl71-OP85yU5a1QX8OqvL8n748Pb5jnZvj69bNbbREdfY8K1UiwvS2RpKSqoCuC6FHUEWQHQYNoojbzATCgOqs4r1gDWpcgryEpdg1iSm3nv4N3XhGGUrZu8jSdl_FsUac5ZGllsZmnvQvDYyMGbXvmDZCCP8clWxvjkMT45xxc197MGo_1vg14GbdBqrI1HPcramX_Uv55VeNc</recordid><startdate>20210401</startdate><enddate>20210401</enddate><creator>Khrizanforova, Vera V.</creator><creator>Shekurov, Ruslan P.</creator><creator>Nizameev, Irek R.</creator><creator>Gerasimova, Tatiana P.</creator><creator>Khrizanforov, Mikhail N.</creator><creator>Bezkishko, Il'ya A.</creator><creator>Miluykov, Vasiliy A.</creator><creator>Budnikova, Yulia H.</creator><general>Elsevier B.V</general><general>Elsevier Science Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20210401</creationdate><title>Aerogel based on nanoporous aluminium ferrocenyl diphosphinate metal-organic framework</title><author>Khrizanforova, Vera V. ; Shekurov, Ruslan P. ; Nizameev, Irek R. ; Gerasimova, Tatiana P. ; Khrizanforov, Mikhail N. ; Bezkishko, Il'ya A. ; Miluykov, Vasiliy A. ; Budnikova, Yulia H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c325t-2caa1799e1593b0b802c93dc321800fe5face28e63a20ad7b1f0ed937b069cd03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aerogel</topic><topic>Aerogels</topic><topic>Aluminium</topic><topic>Aluminum</topic><topic>Coordination polymers</topic><topic>Ferrocenyl diphosphinate</topic><topic>Metal-organic frameworks</topic><topic>Metal–organic framework</topic><topic>Sol-gel processes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khrizanforova, Vera V.</creatorcontrib><creatorcontrib>Shekurov, Ruslan P.</creatorcontrib><creatorcontrib>Nizameev, Irek R.</creatorcontrib><creatorcontrib>Gerasimova, Tatiana P.</creatorcontrib><creatorcontrib>Khrizanforov, Mikhail N.</creatorcontrib><creatorcontrib>Bezkishko, Il'ya A.</creatorcontrib><creatorcontrib>Miluykov, Vasiliy A.</creatorcontrib><creatorcontrib>Budnikova, Yulia H.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Inorganica Chimica Acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khrizanforova, Vera V.</au><au>Shekurov, Ruslan P.</au><au>Nizameev, Irek R.</au><au>Gerasimova, Tatiana P.</au><au>Khrizanforov, Mikhail N.</au><au>Bezkishko, Il'ya A.</au><au>Miluykov, Vasiliy A.</au><au>Budnikova, Yulia H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Aerogel based on nanoporous aluminium ferrocenyl diphosphinate metal-organic framework</atitle><jtitle>Inorganica Chimica Acta</jtitle><date>2021-04-01</date><risdate>2021</risdate><volume>518</volume><spage>120240</spage><pages>120240-</pages><artnum>120240</artnum><issn>0020-1693</issn><eissn>1873-3255</eissn><abstract>[Display omitted]
•Novel PCP-aerogel was prepared from ferrocenediyl-bis(H-phosphinic acid) and Al(NO3)3.•The as-prepared aerogel possessed high specific surface area.•N2 amount adsorbed in the pores of PCP reaches 1400 cm3g−1.•The ferrocene fragment provides the redox activity of the obtained polymer.
New porous coordination polymer (PCP) has been synthesized using ferrocene-based ligand bearing phosphinic groups (H2fcdHp = 1,1′-ferrocenediyl-bis(H-phosphinic acid)) and aluminum salt. Al-fcdHp was obtained according to a sol–gel approach followed by supercritical CO2 drying. The N2 adsorption properties of aerogel were investigated and N2 amount adsorbed in the pores of PCP reaches 1400 cm3g−1. The aerogel exhibits high surface area of approximately 671 m2/g and redox activity due to ferrocenyl fragment.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.ica.2020.120240</doi></addata></record> |
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| subjects | Aerogel Aerogels Aluminium Aluminum Coordination polymers Ferrocenyl diphosphinate Metal-organic frameworks Metal–organic framework Sol-gel processes |
| title | Aerogel based on nanoporous aluminium ferrocenyl diphosphinate metal-organic framework |
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