Periodic Properties Illustrated by CH3NH3Pb(I1–x Br x )3 Solid Solution Perovskite Semiconductors
For solid solutions with the same arrangement of atoms, the size of a unit cell depends on the size of the atoms in the unit cell. The distance between nuclei also helps determine how strongly electrons are held, which changes the band gap energy. Samples of semiconductor CH3NH3Pb(I1–x Br x )3 soli...
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Veröffentlicht in: | Journal of chemical education 2021-07, Vol.98 (7), p.2392-2397 |
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description | For solid solutions with the same arrangement of atoms, the size of a unit cell depends on the size of the atoms in the unit cell. The distance between nuclei also helps determine how strongly electrons are held, which changes the band gap energy. Samples of semiconductor CH3NH3Pb(I1–x Br x )3 solid solutions were prepared; the unit cell size was measured by powder X-ray diffraction, and the band gap energy was measured by visible absorption spectroscopy. This use of a material with significant research and technological implications for solar cells illustrates the periodic properties relationship between composition, atomic size, and electron energy levels. |
doi_str_mv | 10.1021/acs.jchemed.1c00435 |
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This use of a material with significant research and technological implications for solar cells illustrates the periodic properties relationship between composition, atomic size, and electron energy levels.</description><identifier>ISSN: 0021-9584</identifier><identifier>EISSN: 1938-1328</identifier><identifier>DOI: 10.1021/acs.jchemed.1c00435</identifier><language>eng</language><publisher>Easton: American Chemical Society and Division of Chemical Education, Inc</publisher><subject>Absorption spectroscopy ; Band gap ; Electron energy ; Electronics industry ; Electrons ; Energy gap ; Energy levels ; Perovskite ; Perovskites ; Photovoltaic cells ; Semiconductors ; Solar cells ; Solid solutions ; Spectrum analysis ; Unit cell ; X ray powder diffraction ; X-ray diffraction</subject><ispartof>Journal of chemical education, 2021-07, Vol.98 (7), p.2392-2397</ispartof><rights>2021 American Chemical Society and Division of Chemical Education, Inc.</rights><rights>Copyright American Chemical Society Jun 13, 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-1000-406X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.jchemed.1c00435$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.jchemed.1c00435$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,27076,27924,27925,56738,56788</link.rule.ids></links><search><creatorcontrib>Lisensky, George C</creatorcontrib><creatorcontrib>Dauzvardis, Fabian</creatorcontrib><creatorcontrib>Young, Megan M. 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This use of a material with significant research and technological implications for solar cells illustrates the periodic properties relationship between composition, atomic size, and electron energy levels.</description><subject>Absorption spectroscopy</subject><subject>Band gap</subject><subject>Electron energy</subject><subject>Electronics industry</subject><subject>Electrons</subject><subject>Energy gap</subject><subject>Energy levels</subject><subject>Perovskite</subject><subject>Perovskites</subject><subject>Photovoltaic cells</subject><subject>Semiconductors</subject><subject>Solar cells</subject><subject>Solid solutions</subject><subject>Spectrum analysis</subject><subject>Unit cell</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><issn>0021-9584</issn><issn>1938-1328</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpFkMFKAzEQhoMoWKtP4CXgRQ_bJpnNmhy1qC0ULbT3ZTeZxa3bpiZZqTffwTf0SdzaggzMwPDxD_MRcsnZgDPBh4UJg6V5xRXaATeMpSCPSI9rUAkHoY5Jj3VYoqVKT8lZCEvGuJBa9YiZoa-drQ2debdBH2sMdNI0bYi-iGhp-UlHY3gew6y8nvCfr-8tvfd0S2-Azl1T211vY-3WtEtyH-GtjkjnuKqNW9vWROfDOTmpiibgxWH2yeLxYTEaJ9OXp8nobpoUmWKJFFpLi1JXWKYKeFaaCjQrLGMKja5uleKVBJ3qTNoMUEPWPZVay3UlBBTQJ1f72I137y2GmC9d69fdxVxICUoC66pPhnuqc_YPcJbvROZ_y73I_CASfgHQYWim</recordid><startdate>20210713</startdate><enddate>20210713</enddate><creator>Lisensky, George C</creator><creator>Dauzvardis, Fabian</creator><creator>Young, Megan M. 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K</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a680-52995de59feb48316bcf390ad008ec9f7881f5394965d63e9360024dd19f223a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Absorption spectroscopy</topic><topic>Band gap</topic><topic>Electron energy</topic><topic>Electronics industry</topic><topic>Electrons</topic><topic>Energy gap</topic><topic>Energy levels</topic><topic>Perovskite</topic><topic>Perovskites</topic><topic>Photovoltaic cells</topic><topic>Semiconductors</topic><topic>Solar cells</topic><topic>Solid solutions</topic><topic>Spectrum analysis</topic><topic>Unit cell</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lisensky, George C</creatorcontrib><creatorcontrib>Dauzvardis, Fabian</creatorcontrib><creatorcontrib>Young, Megan M. 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subjects | Absorption spectroscopy Band gap Electron energy Electronics industry Electrons Energy gap Energy levels Perovskite Perovskites Photovoltaic cells Semiconductors Solar cells Solid solutions Spectrum analysis Unit cell X ray powder diffraction X-ray diffraction |
title | Periodic Properties Illustrated by CH3NH3Pb(I1–x Br x )3 Solid Solution Perovskite Semiconductors |
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