Periodic Properties Illustrated by CH3NH3Pb(I1–x Br x )3 Solid Solution Perovskite Semiconductors

For solid solutions with the same arrangement of atoms, the size of a unit cell depends on the size of the atoms in the unit cell. The distance between nuclei also helps determine how strongly electrons are held, which changes the band gap energy. Samples of semiconductor CH3NH3Pb­(I1–x Br x )3 soli...

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Veröffentlicht in:Journal of chemical education 2021-07, Vol.98 (7), p.2392-2397
Hauptverfasser: Lisensky, George C, Dauzvardis, Fabian, Young, Megan M. K
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Young, Megan M. K
description For solid solutions with the same arrangement of atoms, the size of a unit cell depends on the size of the atoms in the unit cell. The distance between nuclei also helps determine how strongly electrons are held, which changes the band gap energy. Samples of semiconductor CH3NH3Pb­(I1–x Br x )3 solid solutions were prepared; the unit cell size was measured by powder X-ray diffraction, and the band gap energy was measured by visible absorption spectroscopy. This use of a material with significant research and technological implications for solar cells illustrates the periodic properties relationship between composition, atomic size, and electron energy levels.
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source American Chemical Society Journals
subjects Absorption spectroscopy
Band gap
Electron energy
Electronics industry
Electrons
Energy gap
Energy levels
Perovskite
Perovskites
Photovoltaic cells
Semiconductors
Solar cells
Solid solutions
Spectrum analysis
Unit cell
X ray powder diffraction
X-ray diffraction
title Periodic Properties Illustrated by CH3NH3Pb(I1–x Br x )3 Solid Solution Perovskite Semiconductors
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