Mn Ion Influence on the Structural and Magnetic Response of CaTi1−xMnxO3
This paper describes the CaTi 1− x Mn x O 3 ( x = 0.0, 0.4, 0.6, 0.8 and 1.0) system synthesis using the solid-state reaction (SSR) method. The structural, morphological, and magnetic properties of Mn ion were evaluated in the CaTiO 3 system through X-ray diffraction patterns (XRD), scanning electr...
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Veröffentlicht in: | Journal of low temperature physics 2021-08, Vol.204 (3-4), p.85-94 |
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creator | Saavedra Gaona, I. M. Anzola, E. W. Caro Moreno, M. A. Mendoza Sáenz, C. L. Sánchez Canaria, C. Turatti, A. M. Pimentel, J. L. Mesquita, F. Parra Vargas, C. A. |
description | This paper describes the CaTi
1−
x
Mn
x
O
3
(
x
= 0.0, 0.4, 0.6, 0.8 and 1.0) system synthesis using the solid-state reaction (SSR) method. The structural, morphological, and magnetic properties of Mn ion were evaluated in the CaTiO
3
system through X-ray diffraction patterns (XRD), scanning electron microscopy + electron-dispersive spectroscopy (SEM + EDS), and vibrating sample magnetometry. Rietveld analysis of the XRDs at room temperature evidenced that the samples crystallized in the
Pnma
(62) space group. Likewise, the XRDs showed that lattice parameters decreased when increasing Mn content. The SEM + EDS results exhibited typical features of samples obtained by SSR at high temperatures. The zero-field cooling and field cooling curves of magnetization in temperatures ranging from 50 to 300 K showed paramagnetic behavior in the applied field for each Mn-doped sample with a possible weak ferromagnetic-like ordering. Conversely, the CaMnO
3
sample exhibited antiferromagnetic ordering with
T
N
near 113.26 K. |
doi_str_mv | 10.1007/s10909-021-02600-z |
format | Article |
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1−
x
Mn
x
O
3
(
x
= 0.0, 0.4, 0.6, 0.8 and 1.0) system synthesis using the solid-state reaction (SSR) method. The structural, morphological, and magnetic properties of Mn ion were evaluated in the CaTiO
3
system through X-ray diffraction patterns (XRD), scanning electron microscopy + electron-dispersive spectroscopy (SEM + EDS), and vibrating sample magnetometry. Rietveld analysis of the XRDs at room temperature evidenced that the samples crystallized in the
Pnma
(62) space group. Likewise, the XRDs showed that lattice parameters decreased when increasing Mn content. The SEM + EDS results exhibited typical features of samples obtained by SSR at high temperatures. The zero-field cooling and field cooling curves of magnetization in temperatures ranging from 50 to 300 K showed paramagnetic behavior in the applied field for each Mn-doped sample with a possible weak ferromagnetic-like ordering. Conversely, the CaMnO
3
sample exhibited antiferromagnetic ordering with
T
N
near 113.26 K.</description><identifier>ISSN: 0022-2291</identifier><identifier>EISSN: 1573-7357</identifier><identifier>DOI: 10.1007/s10909-021-02600-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Antiferromagnetism ; Characterization and Evaluation of Materials ; Chemical synthesis ; Condensed Matter Physics ; Cooling curves ; Crystallization ; Diffraction patterns ; Ferromagnetism ; High temperature ; Lattice parameters ; Low temperature physics ; Magnetic Materials ; Magnetic measurement ; Magnetic properties ; Magnetism ; Manganese ; Physics ; Physics and Astronomy ; Room temperature ; Scanning electron microscopy</subject><ispartof>Journal of low temperature physics, 2021-08, Vol.204 (3-4), p.85-94</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c293t-cfd7697959cd419db019b35b0981d9aa7a46d5764312fc53d1f55e1fc84d4c7a3</citedby><cites>FETCH-LOGICAL-c293t-cfd7697959cd419db019b35b0981d9aa7a46d5764312fc53d1f55e1fc84d4c7a3</cites><orcidid>0000-0002-8354-1886</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10909-021-02600-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10909-021-02600-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Saavedra Gaona, I. M.</creatorcontrib><creatorcontrib>Anzola, E. W. Caro</creatorcontrib><creatorcontrib>Moreno, M. A. Mendoza</creatorcontrib><creatorcontrib>Sáenz, C. L. Sánchez</creatorcontrib><creatorcontrib>Canaria, C.</creatorcontrib><creatorcontrib>Turatti, A. M.</creatorcontrib><creatorcontrib>Pimentel, J. L.</creatorcontrib><creatorcontrib>Mesquita, F.</creatorcontrib><creatorcontrib>Parra Vargas, C. A.</creatorcontrib><title>Mn Ion Influence on the Structural and Magnetic Response of CaTi1−xMnxO3</title><title>Journal of low temperature physics</title><addtitle>J Low Temp Phys</addtitle><description>This paper describes the CaTi
1−
x
Mn
x
O
3
(
x
= 0.0, 0.4, 0.6, 0.8 and 1.0) system synthesis using the solid-state reaction (SSR) method. The structural, morphological, and magnetic properties of Mn ion were evaluated in the CaTiO
3
system through X-ray diffraction patterns (XRD), scanning electron microscopy + electron-dispersive spectroscopy (SEM + EDS), and vibrating sample magnetometry. Rietveld analysis of the XRDs at room temperature evidenced that the samples crystallized in the
Pnma
(62) space group. Likewise, the XRDs showed that lattice parameters decreased when increasing Mn content. The SEM + EDS results exhibited typical features of samples obtained by SSR at high temperatures. The zero-field cooling and field cooling curves of magnetization in temperatures ranging from 50 to 300 K showed paramagnetic behavior in the applied field for each Mn-doped sample with a possible weak ferromagnetic-like ordering. Conversely, the CaMnO
3
sample exhibited antiferromagnetic ordering with
T
N
near 113.26 K.</description><subject>Antiferromagnetism</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical synthesis</subject><subject>Condensed Matter Physics</subject><subject>Cooling curves</subject><subject>Crystallization</subject><subject>Diffraction patterns</subject><subject>Ferromagnetism</subject><subject>High temperature</subject><subject>Lattice parameters</subject><subject>Low temperature physics</subject><subject>Magnetic Materials</subject><subject>Magnetic measurement</subject><subject>Magnetic properties</subject><subject>Magnetism</subject><subject>Manganese</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Room temperature</subject><subject>Scanning electron microscopy</subject><issn>0022-2291</issn><issn>1573-7357</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KAzEUhYMoWKsv4CrgevQmmUyapRS1lZaC1nVI81NbaqYmM1D7BK59RJ_E6AjuXBwuF75z7uUgdE7gkgCIq0RAgiyAkqwKoNgfoB7hghWCcXGIegCUFpRKcoxOUloDgBxUrIfupwGP66zgN60LxuG8NM8OPzaxNU0b9QbrYPFUL4NrVgY_uLStQ8qcx0M9X5HP94_dNOxm7BQdeb1J7ux39tHT7c18OComs7vx8HpSGCpZUxhvRSWF5NLYkki7ACIXjC_yQ8RKrYUuK8tFVTJCveHMEs-5I94MSlsaoVkfXXS521i_ti41al23MeSTinLOOKuAikzRjjKxTik6r7Zx9aLjmyKgvjtTXWcqd6Z-OlP7bGKdKWU4LF38i_7H9QWyoW72</recordid><startdate>20210801</startdate><enddate>20210801</enddate><creator>Saavedra Gaona, I. M.</creator><creator>Anzola, E. W. Caro</creator><creator>Moreno, M. A. Mendoza</creator><creator>Sáenz, C. L. Sánchez</creator><creator>Canaria, C.</creator><creator>Turatti, A. M.</creator><creator>Pimentel, J. L.</creator><creator>Mesquita, F.</creator><creator>Parra Vargas, C. A.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-8354-1886</orcidid></search><sort><creationdate>20210801</creationdate><title>Mn Ion Influence on the Structural and Magnetic Response of CaTi1−xMnxO3</title><author>Saavedra Gaona, I. M. ; Anzola, E. W. Caro ; Moreno, M. A. Mendoza ; Sáenz, C. L. Sánchez ; Canaria, C. ; Turatti, A. M. ; Pimentel, J. L. ; Mesquita, F. ; Parra Vargas, C. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c293t-cfd7697959cd419db019b35b0981d9aa7a46d5764312fc53d1f55e1fc84d4c7a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Antiferromagnetism</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical synthesis</topic><topic>Condensed Matter Physics</topic><topic>Cooling curves</topic><topic>Crystallization</topic><topic>Diffraction patterns</topic><topic>Ferromagnetism</topic><topic>High temperature</topic><topic>Lattice parameters</topic><topic>Low temperature physics</topic><topic>Magnetic Materials</topic><topic>Magnetic measurement</topic><topic>Magnetic properties</topic><topic>Magnetism</topic><topic>Manganese</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Room temperature</topic><topic>Scanning electron microscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Saavedra Gaona, I. M.</creatorcontrib><creatorcontrib>Anzola, E. W. Caro</creatorcontrib><creatorcontrib>Moreno, M. A. Mendoza</creatorcontrib><creatorcontrib>Sáenz, C. L. Sánchez</creatorcontrib><creatorcontrib>Canaria, C.</creatorcontrib><creatorcontrib>Turatti, A. M.</creatorcontrib><creatorcontrib>Pimentel, J. L.</creatorcontrib><creatorcontrib>Mesquita, F.</creatorcontrib><creatorcontrib>Parra Vargas, C. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of low temperature physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saavedra Gaona, I. M.</au><au>Anzola, E. W. Caro</au><au>Moreno, M. A. Mendoza</au><au>Sáenz, C. L. Sánchez</au><au>Canaria, C.</au><au>Turatti, A. M.</au><au>Pimentel, J. L.</au><au>Mesquita, F.</au><au>Parra Vargas, C. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mn Ion Influence on the Structural and Magnetic Response of CaTi1−xMnxO3</atitle><jtitle>Journal of low temperature physics</jtitle><stitle>J Low Temp Phys</stitle><date>2021-08-01</date><risdate>2021</risdate><volume>204</volume><issue>3-4</issue><spage>85</spage><epage>94</epage><pages>85-94</pages><issn>0022-2291</issn><eissn>1573-7357</eissn><abstract>This paper describes the CaTi
1−
x
Mn
x
O
3
(
x
= 0.0, 0.4, 0.6, 0.8 and 1.0) system synthesis using the solid-state reaction (SSR) method. The structural, morphological, and magnetic properties of Mn ion were evaluated in the CaTiO
3
system through X-ray diffraction patterns (XRD), scanning electron microscopy + electron-dispersive spectroscopy (SEM + EDS), and vibrating sample magnetometry. Rietveld analysis of the XRDs at room temperature evidenced that the samples crystallized in the
Pnma
(62) space group. Likewise, the XRDs showed that lattice parameters decreased when increasing Mn content. The SEM + EDS results exhibited typical features of samples obtained by SSR at high temperatures. The zero-field cooling and field cooling curves of magnetization in temperatures ranging from 50 to 300 K showed paramagnetic behavior in the applied field for each Mn-doped sample with a possible weak ferromagnetic-like ordering. Conversely, the CaMnO
3
sample exhibited antiferromagnetic ordering with
T
N
near 113.26 K.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10909-021-02600-z</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-8354-1886</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Antiferromagnetism Characterization and Evaluation of Materials Chemical synthesis Condensed Matter Physics Cooling curves Crystallization Diffraction patterns Ferromagnetism High temperature Lattice parameters Low temperature physics Magnetic Materials Magnetic measurement Magnetic properties Magnetism Manganese Physics Physics and Astronomy Room temperature Scanning electron microscopy |
title | Mn Ion Influence on the Structural and Magnetic Response of CaTi1−xMnxO3 |
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