Removal of Rhodamine B by g-C3N4/Co3O4/MWCNT composite stabilized in hydrogel via the synergy of adsorption and photocatalysis under visible light
Hydrogel nanocomposite as a novel porous macromolecular provides potential applications in many different fields. In this paper, Co 3 O 4 /g-C 3 N 4 /multi wall carbon nanotube (MWCNT) nanocomposites were stabilized in resorcinol formaldehyde hydrogel for a highly efficient removal of Rhodamine B fr...
Gespeichert in:
| Veröffentlicht in: | Journal of materials science. Materials in electronics 2019-07, Vol.30 (13), p.12475-12486 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 12486 |
|---|---|
| container_issue | 13 |
| container_start_page | 12475 |
| container_title | Journal of materials science. Materials in electronics |
| container_volume | 30 |
| creator | Shafiee, Mohammad Reza Mohammad Parhizkar, Janan Radfar, Sasan |
| description | Hydrogel nanocomposite as a novel porous macromolecular provides potential applications in many different fields. In this paper, Co
3
O
4
/g-C
3
N
4
/multi wall carbon nanotube (MWCNT) nanocomposites were stabilized in resorcinol formaldehyde hydrogel for a highly efficient removal of Rhodamine B from aqueous solution. Hydrogel, Co
3
O
4
in hydrogel, g-C
3
N
4
in hydrogel, Co
3
O
4
/g-C
3
N
4
in hydrogel and Co
3
O
4
/g-C
3
N
4
/MWCNT in hydrogel were synthesized and characterized by Fourier-transform infrared spectroscopy (FTIR), UV–Vis diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD), BET, BJH, Scanning Electron Microscope (SEM) and energy dispersive X ray (EDX). BET results showed that the presence of nanomaterials in synthesis steps of hydrogel, increase specific surface area about 22.5-30 times. DRS results confirmed that the stabilization of g-C
3
N
4
and Co
3
O
4
nanoparticles in hydrogel effectively shifted absorption edge to longer wavelength (red shift). The aim of this study is to eliminate Rhodamine B from solution by semiconducting materials which stabilized in hydrogel. Adsorption and synergistic performance of each sample in removal of 3 ppm solution of Rhodamine B were evaluated by UV–Vis spectrophotometry in dark and under visible light irradiation, respectively. The best removal performance (87%) was obtained by Co
3
O
4
/g-C
3
N
4
/MWCNT nanocomposites stabilized in hydrogel in 120 min under visible light irradiation. All of the samples follow first order kinetic model in removal of Rhodamine B. This study provides new insights into the stabilization of catalysts in hydrogel as a porous material and facilitates their application in the synergistic removal of dye in the field of water treatment. |
| doi_str_mv | 10.1007/s10854-019-01607-3 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2553402774</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2553402774</sourcerecordid><originalsourceid>FETCH-LOGICAL-c386t-a6ad7ec777b1d1bafbfa4fceba4578bfab0b52727294fb688c6c01281d667ff23</originalsourceid><addsrcrecordid>eNp9kc2KFTEQhYMoeB19AVcB1-3Nf3KX2vgH4wwMI7oLSSfpztC30ya5A-1j-MRmvIK7oSiKos53anEAeI3RW4yQ3BeMFGcdwofWAsmOPgE7zCXtmCI_noIdOnDZMU7Ic_CilDuEkGBU7cDvG39M92aGKcCbKTlzjIuH76Hd4Nj19Irt-0Sv2f7r9_7qFg7puKYSq4elGhvn-Ms7GBc4bS6n0c_wPhpYp3beFp_H7cHVuJLyWmNaoFkcXKdU02CqmbcSCzwtzueGlWhnD-c4TvUleBbMXPyrf_MCfPv44bb_3F1ef_rSv7vsBqpE7YwwTvpBSmmxw9YEGwwLg7eGcanaYpHlRLY6sGCFUoMYECYKOyFkCIRegDdn3zWnnydfqr5Lp7y0l5pwThkiUrJHVYSSgxKUo6YiZ9WQUynZB73meDR50xjph4T0OSHdEtJ_E9K0QfQMlSZeRp__Wz9C_QFXnpTx</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2232986350</pqid></control><display><type>article</type><title>Removal of Rhodamine B by g-C3N4/Co3O4/MWCNT composite stabilized in hydrogel via the synergy of adsorption and photocatalysis under visible light</title><source>Springer Nature - Complete Springer Journals</source><creator>Shafiee, Mohammad Reza Mohammad ; Parhizkar, Janan ; Radfar, Sasan</creator><creatorcontrib>Shafiee, Mohammad Reza Mohammad ; Parhizkar, Janan ; Radfar, Sasan</creatorcontrib><description>Hydrogel nanocomposite as a novel porous macromolecular provides potential applications in many different fields. In this paper, Co
3
O
4
/g-C
3
N
4
/multi wall carbon nanotube (MWCNT) nanocomposites were stabilized in resorcinol formaldehyde hydrogel for a highly efficient removal of Rhodamine B from aqueous solution. Hydrogel, Co
3
O
4
in hydrogel, g-C
3
N
4
in hydrogel, Co
3
O
4
/g-C
3
N
4
in hydrogel and Co
3
O
4
/g-C
3
N
4
/MWCNT in hydrogel were synthesized and characterized by Fourier-transform infrared spectroscopy (FTIR), UV–Vis diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD), BET, BJH, Scanning Electron Microscope (SEM) and energy dispersive X ray (EDX). BET results showed that the presence of nanomaterials in synthesis steps of hydrogel, increase specific surface area about 22.5-30 times. DRS results confirmed that the stabilization of g-C
3
N
4
and Co
3
O
4
nanoparticles in hydrogel effectively shifted absorption edge to longer wavelength (red shift). The aim of this study is to eliminate Rhodamine B from solution by semiconducting materials which stabilized in hydrogel. Adsorption and synergistic performance of each sample in removal of 3 ppm solution of Rhodamine B were evaluated by UV–Vis spectrophotometry in dark and under visible light irradiation, respectively. The best removal performance (87%) was obtained by Co
3
O
4
/g-C
3
N
4
/MWCNT nanocomposites stabilized in hydrogel in 120 min under visible light irradiation. All of the samples follow first order kinetic model in removal of Rhodamine B. This study provides new insights into the stabilization of catalysts in hydrogel as a porous material and facilitates their application in the synergistic removal of dye in the field of water treatment.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-019-01607-3</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorption ; Aqueous solutions ; Carbon nitride ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Cobalt oxides ; Diffuse reflectance spectroscopy ; Doppler effect ; Fourier transforms ; Hydrogels ; Infrared spectroscopy ; Light irradiation ; Materials Science ; Multi wall carbon nanotubes ; Nanocomposites ; Nanomaterials ; Nanoparticles ; Optical and Electronic Materials ; Porous materials ; Red shift ; Rhodamine ; Spectrophotometry ; Spectrum analysis ; Stabilization ; Water treatment ; X-ray diffraction</subject><ispartof>Journal of materials science. Materials in electronics, 2019-07, Vol.30 (13), p.12475-12486</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>Journal of Materials Science: Materials in Electronics is a copyright of Springer, (2019). All Rights Reserved.</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-a6ad7ec777b1d1bafbfa4fceba4578bfab0b52727294fb688c6c01281d667ff23</citedby><cites>FETCH-LOGICAL-c386t-a6ad7ec777b1d1bafbfa4fceba4578bfab0b52727294fb688c6c01281d667ff23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-019-01607-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-019-01607-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27911,27912,41475,42544,51306</link.rule.ids></links><search><creatorcontrib>Shafiee, Mohammad Reza Mohammad</creatorcontrib><creatorcontrib>Parhizkar, Janan</creatorcontrib><creatorcontrib>Radfar, Sasan</creatorcontrib><title>Removal of Rhodamine B by g-C3N4/Co3O4/MWCNT composite stabilized in hydrogel via the synergy of adsorption and photocatalysis under visible light</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>Hydrogel nanocomposite as a novel porous macromolecular provides potential applications in many different fields. In this paper, Co
3
O
4
/g-C
3
N
4
/multi wall carbon nanotube (MWCNT) nanocomposites were stabilized in resorcinol formaldehyde hydrogel for a highly efficient removal of Rhodamine B from aqueous solution. Hydrogel, Co
3
O
4
in hydrogel, g-C
3
N
4
in hydrogel, Co
3
O
4
/g-C
3
N
4
in hydrogel and Co
3
O
4
/g-C
3
N
4
/MWCNT in hydrogel were synthesized and characterized by Fourier-transform infrared spectroscopy (FTIR), UV–Vis diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD), BET, BJH, Scanning Electron Microscope (SEM) and energy dispersive X ray (EDX). BET results showed that the presence of nanomaterials in synthesis steps of hydrogel, increase specific surface area about 22.5-30 times. DRS results confirmed that the stabilization of g-C
3
N
4
and Co
3
O
4
nanoparticles in hydrogel effectively shifted absorption edge to longer wavelength (red shift). The aim of this study is to eliminate Rhodamine B from solution by semiconducting materials which stabilized in hydrogel. Adsorption and synergistic performance of each sample in removal of 3 ppm solution of Rhodamine B were evaluated by UV–Vis spectrophotometry in dark and under visible light irradiation, respectively. The best removal performance (87%) was obtained by Co
3
O
4
/g-C
3
N
4
/MWCNT nanocomposites stabilized in hydrogel in 120 min under visible light irradiation. All of the samples follow first order kinetic model in removal of Rhodamine B. This study provides new insights into the stabilization of catalysts in hydrogel as a porous material and facilitates their application in the synergistic removal of dye in the field of water treatment.</description><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Carbon nitride</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt oxides</subject><subject>Diffuse reflectance spectroscopy</subject><subject>Doppler effect</subject><subject>Fourier transforms</subject><subject>Hydrogels</subject><subject>Infrared spectroscopy</subject><subject>Light irradiation</subject><subject>Materials Science</subject><subject>Multi wall carbon nanotubes</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanoparticles</subject><subject>Optical and Electronic Materials</subject><subject>Porous materials</subject><subject>Red shift</subject><subject>Rhodamine</subject><subject>Spectrophotometry</subject><subject>Spectrum analysis</subject><subject>Stabilization</subject><subject>Water treatment</subject><subject>X-ray diffraction</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kc2KFTEQhYMoeB19AVcB1-3Nf3KX2vgH4wwMI7oLSSfpztC30ya5A-1j-MRmvIK7oSiKos53anEAeI3RW4yQ3BeMFGcdwofWAsmOPgE7zCXtmCI_noIdOnDZMU7Ic_CilDuEkGBU7cDvG39M92aGKcCbKTlzjIuH76Hd4Nj19Irt-0Sv2f7r9_7qFg7puKYSq4elGhvn-Ms7GBc4bS6n0c_wPhpYp3beFp_H7cHVuJLyWmNaoFkcXKdU02CqmbcSCzwtzueGlWhnD-c4TvUleBbMXPyrf_MCfPv44bb_3F1ef_rSv7vsBqpE7YwwTvpBSmmxw9YEGwwLg7eGcanaYpHlRLY6sGCFUoMYECYKOyFkCIRegDdn3zWnnydfqr5Lp7y0l5pwThkiUrJHVYSSgxKUo6YiZ9WQUynZB73meDR50xjph4T0OSHdEtJ_E9K0QfQMlSZeRp__Wz9C_QFXnpTx</recordid><startdate>20190701</startdate><enddate>20190701</enddate><creator>Shafiee, Mohammad Reza Mohammad</creator><creator>Parhizkar, Janan</creator><creator>Radfar, Sasan</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>S0W</scope></search><sort><creationdate>20190701</creationdate><title>Removal of Rhodamine B by g-C3N4/Co3O4/MWCNT composite stabilized in hydrogel via the synergy of adsorption and photocatalysis under visible light</title><author>Shafiee, Mohammad Reza Mohammad ; Parhizkar, Janan ; Radfar, Sasan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-a6ad7ec777b1d1bafbfa4fceba4578bfab0b52727294fb688c6c01281d667ff23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Adsorption</topic><topic>Aqueous solutions</topic><topic>Carbon nitride</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt oxides</topic><topic>Diffuse reflectance spectroscopy</topic><topic>Doppler effect</topic><topic>Fourier transforms</topic><topic>Hydrogels</topic><topic>Infrared spectroscopy</topic><topic>Light irradiation</topic><topic>Materials Science</topic><topic>Multi wall carbon nanotubes</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanoparticles</topic><topic>Optical and Electronic Materials</topic><topic>Porous materials</topic><topic>Red shift</topic><topic>Rhodamine</topic><topic>Spectrophotometry</topic><topic>Spectrum analysis</topic><topic>Stabilization</topic><topic>Water treatment</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shafiee, Mohammad Reza Mohammad</creatorcontrib><creatorcontrib>Parhizkar, Janan</creatorcontrib><creatorcontrib>Radfar, Sasan</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shafiee, Mohammad Reza Mohammad</au><au>Parhizkar, Janan</au><au>Radfar, Sasan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Removal of Rhodamine B by g-C3N4/Co3O4/MWCNT composite stabilized in hydrogel via the synergy of adsorption and photocatalysis under visible light</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2019-07-01</date><risdate>2019</risdate><volume>30</volume><issue>13</issue><spage>12475</spage><epage>12486</epage><pages>12475-12486</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>Hydrogel nanocomposite as a novel porous macromolecular provides potential applications in many different fields. In this paper, Co
3
O
4
/g-C
3
N
4
/multi wall carbon nanotube (MWCNT) nanocomposites were stabilized in resorcinol formaldehyde hydrogel for a highly efficient removal of Rhodamine B from aqueous solution. Hydrogel, Co
3
O
4
in hydrogel, g-C
3
N
4
in hydrogel, Co
3
O
4
/g-C
3
N
4
in hydrogel and Co
3
O
4
/g-C
3
N
4
/MWCNT in hydrogel were synthesized and characterized by Fourier-transform infrared spectroscopy (FTIR), UV–Vis diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD), BET, BJH, Scanning Electron Microscope (SEM) and energy dispersive X ray (EDX). BET results showed that the presence of nanomaterials in synthesis steps of hydrogel, increase specific surface area about 22.5-30 times. DRS results confirmed that the stabilization of g-C
3
N
4
and Co
3
O
4
nanoparticles in hydrogel effectively shifted absorption edge to longer wavelength (red shift). The aim of this study is to eliminate Rhodamine B from solution by semiconducting materials which stabilized in hydrogel. Adsorption and synergistic performance of each sample in removal of 3 ppm solution of Rhodamine B were evaluated by UV–Vis spectrophotometry in dark and under visible light irradiation, respectively. The best removal performance (87%) was obtained by Co
3
O
4
/g-C
3
N
4
/MWCNT nanocomposites stabilized in hydrogel in 120 min under visible light irradiation. All of the samples follow first order kinetic model in removal of Rhodamine B. This study provides new insights into the stabilization of catalysts in hydrogel as a porous material and facilitates their application in the synergistic removal of dye in the field of water treatment.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-019-01607-3</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0957-4522 |
| ispartof | Journal of materials science. Materials in electronics, 2019-07, Vol.30 (13), p.12475-12486 |
| issn | 0957-4522 1573-482X |
| language | eng |
| recordid | cdi_proquest_journals_2553402774 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Adsorption Aqueous solutions Carbon nitride Characterization and Evaluation of Materials Chemistry and Materials Science Cobalt oxides Diffuse reflectance spectroscopy Doppler effect Fourier transforms Hydrogels Infrared spectroscopy Light irradiation Materials Science Multi wall carbon nanotubes Nanocomposites Nanomaterials Nanoparticles Optical and Electronic Materials Porous materials Red shift Rhodamine Spectrophotometry Spectrum analysis Stabilization Water treatment X-ray diffraction |
| title | Removal of Rhodamine B by g-C3N4/Co3O4/MWCNT composite stabilized in hydrogel via the synergy of adsorption and photocatalysis under visible light |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T03%3A11%3A14IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Removal%20of%20Rhodamine%20B%20by%20g-C3N4/Co3O4/MWCNT%20composite%20stabilized%20in%20hydrogel%20via%20the%20synergy%20of%20adsorption%20and%20photocatalysis%20under%20visible%20light&rft.jtitle=Journal%20of%20materials%20science.%20Materials%20in%20electronics&rft.au=Shafiee,%20Mohammad%20Reza%20Mohammad&rft.date=2019-07-01&rft.volume=30&rft.issue=13&rft.spage=12475&rft.epage=12486&rft.pages=12475-12486&rft.issn=0957-4522&rft.eissn=1573-482X&rft_id=info:doi/10.1007/s10854-019-01607-3&rft_dat=%3Cproquest_cross%3E2553402774%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2232986350&rft_id=info:pmid/&rfr_iscdi=true |