Geochemistry and Pb isotopic proof for sources of heavy metal(loid)s in Late Cretaceous sandstones from Eastern Pontides (NE Turkey)

Upper Cretaceous sedimentary rocks are widely exposed around Trabzon, Giresun and Gümüşhane in the eastern Pontides. The sedimentary rocks are mainly composed of sandstones and marls, and the thicknesses of these rocks range from 170 to 400 m. This paper focused on Late Cretaceous sandstones of Trab...

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description Upper Cretaceous sedimentary rocks are widely exposed around Trabzon, Giresun and Gümüşhane in the eastern Pontides. The sedimentary rocks are mainly composed of sandstones and marls, and the thicknesses of these rocks range from 170 to 400 m. This paper focused on Late Cretaceous sandstones of Trabzon, Giresun and Gümüşhane regions to identify the concentrations, sources, deposition environment and conditions of certain heavy metal(loid)s (Zn, Pb, Cu, Ni, As, Co, Mo and V). Enrichment factor (EF), geo-accumulation index ( Igeo ), Pollution index (Pi), Pollution load index (Pl n ), Pb isotope and multivariate statistical analysis were performed to elucidate the pollution levels and sources. In general, the evaluation indices exhibited that the sandstones were moderately polluted by As in the Trabzon area, and strongly polluted by Ni and As, moderately polluted by Co and V in the Giresun and Gümüşhane areas. The results of multivariate statistical analyses indicated that As and partly Pb might be originated from anthropogenic sources, whereas other metals were derived from geogenic origin. Lead isotopic analysis demonstrated two characterized signatures of the pollution sources in the sandstones, one related to geogenic origin and the other to coal, gasoline and pesticides. The sandstones were deposited in transition—marine environment under oxic—weak oxic conditions and paleoclimatic conditions ranged from arid to moist during Late Cretaceous period.
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The sedimentary rocks are mainly composed of sandstones and marls, and the thicknesses of these rocks range from 170 to 400 m. This paper focused on Late Cretaceous sandstones of Trabzon, Giresun and Gümüşhane regions to identify the concentrations, sources, deposition environment and conditions of certain heavy metal(loid)s (Zn, Pb, Cu, Ni, As, Co, Mo and V). Enrichment factor (EF), geo-accumulation index ( Igeo ), Pollution index (Pi), Pollution load index (Pl n ), Pb isotope and multivariate statistical analysis were performed to elucidate the pollution levels and sources. In general, the evaluation indices exhibited that the sandstones were moderately polluted by As in the Trabzon area, and strongly polluted by Ni and As, moderately polluted by Co and V in the Giresun and Gümüşhane areas. The results of multivariate statistical analyses indicated that As and partly Pb might be originated from anthropogenic sources, whereas other metals were derived from geogenic origin. Lead isotopic analysis demonstrated two characterized signatures of the pollution sources in the sandstones, one related to geogenic origin and the other to coal, gasoline and pesticides. 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Lead isotopic analysis demonstrated two characterized signatures of the pollution sources in the sandstones, one related to geogenic origin and the other to coal, gasoline and pesticides. 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subjects Anthropogenic factors
Aridity
Biogeosciences
Copper
Cretaceous
Earth and Environmental Science
Earth Sciences
Environmental Science and Engineering
Gasoline
Geochemistry
Geology
Heavy metals
Hydrology/Water Resources
Isotopes
Lead
Marine environment
Molybdenum
Multivariate analysis
Multivariate statistical analysis
Nickel
Original Article
Oxic conditions
Pesticides
Pollutant load
Pollution
Pollution index
Pollution levels
Pollution load
Pollution sources
Sandstone
Sedimentary rocks
Statistical analysis
Statistical methods
Statistics
Terrestrial Pollution
Zinc
title Geochemistry and Pb isotopic proof for sources of heavy metal(loid)s in Late Cretaceous sandstones from Eastern Pontides (NE Turkey)
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