Geochemistry and Pb isotopic proof for sources of heavy metal(loid)s in Late Cretaceous sandstones from Eastern Pontides (NE Turkey)
Upper Cretaceous sedimentary rocks are widely exposed around Trabzon, Giresun and Gümüşhane in the eastern Pontides. The sedimentary rocks are mainly composed of sandstones and marls, and the thicknesses of these rocks range from 170 to 400 m. This paper focused on Late Cretaceous sandstones of Trab...
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description | Upper Cretaceous sedimentary rocks are widely exposed around Trabzon, Giresun and Gümüşhane in the eastern Pontides. The sedimentary rocks are mainly composed of sandstones and marls, and the thicknesses of these rocks range from 170 to 400 m. This paper focused on Late Cretaceous sandstones of Trabzon, Giresun and Gümüşhane regions to identify the concentrations, sources, deposition environment and conditions of certain heavy metal(loid)s (Zn, Pb, Cu, Ni, As, Co, Mo and V). Enrichment factor (EF), geo-accumulation index (
Igeo
), Pollution index (Pi), Pollution load index (Pl
n
), Pb isotope and multivariate statistical analysis were performed to elucidate the pollution levels and sources. In general, the evaluation indices exhibited that the sandstones were moderately polluted by As in the Trabzon area, and strongly polluted by Ni and As, moderately polluted by Co and V in the Giresun and Gümüşhane areas. The results of multivariate statistical analyses indicated that As and partly Pb might be originated from anthropogenic sources, whereas other metals were derived from geogenic origin. Lead isotopic analysis demonstrated two characterized signatures of the pollution sources in the sandstones, one related to geogenic origin and the other to coal, gasoline and pesticides. The sandstones were deposited in transition—marine environment under oxic—weak oxic conditions and paleoclimatic conditions ranged from arid to moist during Late Cretaceous period. |
doi_str_mv | 10.1007/s12665-021-09772-7 |
format | Article |
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Igeo
), Pollution index (Pi), Pollution load index (Pl
n
), Pb isotope and multivariate statistical analysis were performed to elucidate the pollution levels and sources. In general, the evaluation indices exhibited that the sandstones were moderately polluted by As in the Trabzon area, and strongly polluted by Ni and As, moderately polluted by Co and V in the Giresun and Gümüşhane areas. The results of multivariate statistical analyses indicated that As and partly Pb might be originated from anthropogenic sources, whereas other metals were derived from geogenic origin. Lead isotopic analysis demonstrated two characterized signatures of the pollution sources in the sandstones, one related to geogenic origin and the other to coal, gasoline and pesticides. The sandstones were deposited in transition—marine environment under oxic—weak oxic conditions and paleoclimatic conditions ranged from arid to moist during Late Cretaceous period.</description><identifier>ISSN: 1866-6280</identifier><identifier>EISSN: 1866-6299</identifier><identifier>DOI: 10.1007/s12665-021-09772-7</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Anthropogenic factors ; Aridity ; Biogeosciences ; Copper ; Cretaceous ; Earth and Environmental Science ; Earth Sciences ; Environmental Science and Engineering ; Gasoline ; Geochemistry ; Geology ; Heavy metals ; Hydrology/Water Resources ; Isotopes ; Lead ; Marine environment ; Molybdenum ; Multivariate analysis ; Multivariate statistical analysis ; Nickel ; Original Article ; Oxic conditions ; Pesticides ; Pollutant load ; Pollution ; Pollution index ; Pollution levels ; Pollution load ; Pollution sources ; Sandstone ; Sedimentary rocks ; Statistical analysis ; Statistical methods ; Statistics ; Terrestrial Pollution ; Zinc</subject><ispartof>Environmental earth sciences, 2021-08, Vol.80 (15), Article 477</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a386t-768ce84256e8d48c1d9fe6fd931e0ebef0f4850f32812cfad30e5ef89e3e204a3</citedby><cites>FETCH-LOGICAL-a386t-768ce84256e8d48c1d9fe6fd931e0ebef0f4850f32812cfad30e5ef89e3e204a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12665-021-09772-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12665-021-09772-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Saydam, Eker Çiğdem</creatorcontrib><title>Geochemistry and Pb isotopic proof for sources of heavy metal(loid)s in Late Cretaceous sandstones from Eastern Pontides (NE Turkey)</title><title>Environmental earth sciences</title><addtitle>Environ Earth Sci</addtitle><description>Upper Cretaceous sedimentary rocks are widely exposed around Trabzon, Giresun and Gümüşhane in the eastern Pontides. The sedimentary rocks are mainly composed of sandstones and marls, and the thicknesses of these rocks range from 170 to 400 m. This paper focused on Late Cretaceous sandstones of Trabzon, Giresun and Gümüşhane regions to identify the concentrations, sources, deposition environment and conditions of certain heavy metal(loid)s (Zn, Pb, Cu, Ni, As, Co, Mo and V). Enrichment factor (EF), geo-accumulation index (
Igeo
), Pollution index (Pi), Pollution load index (Pl
n
), Pb isotope and multivariate statistical analysis were performed to elucidate the pollution levels and sources. In general, the evaluation indices exhibited that the sandstones were moderately polluted by As in the Trabzon area, and strongly polluted by Ni and As, moderately polluted by Co and V in the Giresun and Gümüşhane areas. The results of multivariate statistical analyses indicated that As and partly Pb might be originated from anthropogenic sources, whereas other metals were derived from geogenic origin. Lead isotopic analysis demonstrated two characterized signatures of the pollution sources in the sandstones, one related to geogenic origin and the other to coal, gasoline and pesticides. The sandstones were deposited in transition—marine environment under oxic—weak oxic conditions and paleoclimatic conditions ranged from arid to moist during Late Cretaceous period.</description><subject>Anthropogenic factors</subject><subject>Aridity</subject><subject>Biogeosciences</subject><subject>Copper</subject><subject>Cretaceous</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>Environmental Science and Engineering</subject><subject>Gasoline</subject><subject>Geochemistry</subject><subject>Geology</subject><subject>Heavy metals</subject><subject>Hydrology/Water Resources</subject><subject>Isotopes</subject><subject>Lead</subject><subject>Marine environment</subject><subject>Molybdenum</subject><subject>Multivariate analysis</subject><subject>Multivariate statistical analysis</subject><subject>Nickel</subject><subject>Original Article</subject><subject>Oxic conditions</subject><subject>Pesticides</subject><subject>Pollutant load</subject><subject>Pollution</subject><subject>Pollution index</subject><subject>Pollution levels</subject><subject>Pollution load</subject><subject>Pollution sources</subject><subject>Sandstone</subject><subject>Sedimentary rocks</subject><subject>Statistical analysis</subject><subject>Statistical methods</subject><subject>Statistics</subject><subject>Terrestrial 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Çiğdem</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a386t-768ce84256e8d48c1d9fe6fd931e0ebef0f4850f32812cfad30e5ef89e3e204a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Anthropogenic factors</topic><topic>Aridity</topic><topic>Biogeosciences</topic><topic>Copper</topic><topic>Cretaceous</topic><topic>Earth and Environmental Science</topic><topic>Earth Sciences</topic><topic>Environmental Science and Engineering</topic><topic>Gasoline</topic><topic>Geochemistry</topic><topic>Geology</topic><topic>Heavy metals</topic><topic>Hydrology/Water Resources</topic><topic>Isotopes</topic><topic>Lead</topic><topic>Marine environment</topic><topic>Molybdenum</topic><topic>Multivariate analysis</topic><topic>Multivariate statistical analysis</topic><topic>Nickel</topic><topic>Original Article</topic><topic>Oxic conditions</topic><topic>Pesticides</topic><topic>Pollutant 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sciences</jtitle><stitle>Environ Earth Sci</stitle><date>2021-08-01</date><risdate>2021</risdate><volume>80</volume><issue>15</issue><artnum>477</artnum><issn>1866-6280</issn><eissn>1866-6299</eissn><abstract>Upper Cretaceous sedimentary rocks are widely exposed around Trabzon, Giresun and Gümüşhane in the eastern Pontides. The sedimentary rocks are mainly composed of sandstones and marls, and the thicknesses of these rocks range from 170 to 400 m. This paper focused on Late Cretaceous sandstones of Trabzon, Giresun and Gümüşhane regions to identify the concentrations, sources, deposition environment and conditions of certain heavy metal(loid)s (Zn, Pb, Cu, Ni, As, Co, Mo and V). Enrichment factor (EF), geo-accumulation index (
Igeo
), Pollution index (Pi), Pollution load index (Pl
n
), Pb isotope and multivariate statistical analysis were performed to elucidate the pollution levels and sources. In general, the evaluation indices exhibited that the sandstones were moderately polluted by As in the Trabzon area, and strongly polluted by Ni and As, moderately polluted by Co and V in the Giresun and Gümüşhane areas. The results of multivariate statistical analyses indicated that As and partly Pb might be originated from anthropogenic sources, whereas other metals were derived from geogenic origin. Lead isotopic analysis demonstrated two characterized signatures of the pollution sources in the sandstones, one related to geogenic origin and the other to coal, gasoline and pesticides. The sandstones were deposited in transition—marine environment under oxic—weak oxic conditions and paleoclimatic conditions ranged from arid to moist during Late Cretaceous period.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s12665-021-09772-7</doi><oa>free_for_read</oa></addata></record> |
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subjects | Anthropogenic factors Aridity Biogeosciences Copper Cretaceous Earth and Environmental Science Earth Sciences Environmental Science and Engineering Gasoline Geochemistry Geology Heavy metals Hydrology/Water Resources Isotopes Lead Marine environment Molybdenum Multivariate analysis Multivariate statistical analysis Nickel Original Article Oxic conditions Pesticides Pollutant load Pollution Pollution index Pollution levels Pollution load Pollution sources Sandstone Sedimentary rocks Statistical analysis Statistical methods Statistics Terrestrial Pollution Zinc |
title | Geochemistry and Pb isotopic proof for sources of heavy metal(loid)s in Late Cretaceous sandstones from Eastern Pontides (NE Turkey) |
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