Textile waste as precursors in nanocrystalline cellulose synthesis
High solid waste generation is one of the biggest environmental issues today. The rapid cycle of fashion in the textile industry has contributed intensely to the extremely high levels of material consumption and waste generation. This paper presents a proposal for obtaining cellulose nanocrystals fr...
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Veröffentlicht in: | Cellulose (London) 2021-07, Vol.28 (11), p.6967-6981 |
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description | High solid waste generation is one of the biggest environmental issues today. The rapid cycle of fashion in the textile industry has contributed intensely to the extremely high levels of material consumption and waste generation. This paper presents a proposal for obtaining cellulose nanocrystals from recovered textile waste. For this, cotton cloth waste and cotton and polyester fabric blend waste were used. Spherical cellulose nanocrystals were obtained from the milling of fabrics in liquid medium and oxidative treatment. The results obtained by transmission electron microscopy, zeta potential, X-ray diffraction and thermogravimetry showed that both fabric samples promoted the formation of spherical cellulose nanocrystals with high crystallinity index. The oxidative treatment promoted the increase of the crystallinity percentage of the samples, as well as the decrease of the crystallite size. With this, the potential of the textile industry waste to obtain cellulose nanocrystals becomes evident.
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doi_str_mv | 10.1007/s10570-021-03982-9 |
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Graphic abstract</description><subject>Bioorganic Chemistry</subject><subject>Cellulose</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cloth</subject><subject>Composites</subject><subject>Cotton</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Crystallites</subject><subject>Glass</subject><subject>Industrial wastes</subject><subject>Nanocrystals</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Sustainable Development</subject><subject>Textile industry</subject><subject>Thermogravimetry</subject><subject>Zeta potential</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kE1LxDAQhoMouK7-AU8Fz9XJpGmSoy5-geBlBW8hm061S23XTIvuv7e6gjdPc5j3eYd5hDiVcC4BzAVL0AZyQJmDchZztydmUhvMrcXnfTEDV7pprdyhOGJeA4AzKGfiakmfQ9NS9hF4oCxwtkkUx8R94qzpsi50fUxbHkLbNh1lkdp2bHumjLfd8Erc8LE4qEPLdPI75-Lp5nq5uMsfHm_vF5cPeVTSDXnlNLpVZVEaZUNVIlLp0GAsSl0WxiiqV-iiMXVdWYoKgQqoQqmL6TOlCzUXZ7veTerfR-LBr_sxddNJj1pLCwVKO6Vwl4qpZ05U-01q3kLaegn-25XfufKTK__jyrsJUjuIp3D3Qumv-h_qC6fbbCg</recordid><startdate>20210701</startdate><enddate>20210701</enddate><creator>Vanzetto, Andrielen Braz</creator><creator>Beltrami, Lilian Vanessa Rossa</creator><creator>Zattera, Ademir José</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0001-5430-2598</orcidid></search><sort><creationdate>20210701</creationdate><title>Textile waste as precursors in nanocrystalline cellulose synthesis</title><author>Vanzetto, Andrielen Braz ; 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The rapid cycle of fashion in the textile industry has contributed intensely to the extremely high levels of material consumption and waste generation. This paper presents a proposal for obtaining cellulose nanocrystals from recovered textile waste. For this, cotton cloth waste and cotton and polyester fabric blend waste were used. Spherical cellulose nanocrystals were obtained from the milling of fabrics in liquid medium and oxidative treatment. The results obtained by transmission electron microscopy, zeta potential, X-ray diffraction and thermogravimetry showed that both fabric samples promoted the formation of spherical cellulose nanocrystals with high crystallinity index. The oxidative treatment promoted the increase of the crystallinity percentage of the samples, as well as the decrease of the crystallite size. With this, the potential of the textile industry waste to obtain cellulose nanocrystals becomes evident.
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subjects | Bioorganic Chemistry Cellulose Ceramics Chemistry Chemistry and Materials Science Cloth Composites Cotton Crystal structure Crystallinity Crystallites Glass Industrial wastes Nanocrystals Natural Materials Organic Chemistry Original Research Physical Chemistry Polymer Sciences Sustainable Development Textile industry Thermogravimetry Zeta potential |
title | Textile waste as precursors in nanocrystalline cellulose synthesis |
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