Lattice vibrational characteristics, crystal structure, and dielectric properties of single-phase Sr(Mg1/2Mo1/2)O3 microwave dielectric ceramic

Sr(Mg 1/2 Mo 1/2 )O 3 (SMM) microwave dielectric ceramic was prepared by a solid-state sintering method. X-ray diffraction shows that the sample is a single-phase SMM with a tetragonal double perovskite structure (Fm-3m). Raman scattering and FTIR spectroscopy analyze the vibration characteristics o...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2021-07, Vol.32 (13), p.17191-17199
Hauptverfasser: Yu, Wenhao, Lv, Jiqing, Shi, Feng, Song, Kaixin, Lei, Wen, Zhou, Huanfu, Qi, Ze-Ming, Wang, Jing
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container_issue 13
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container_title Journal of materials science. Materials in electronics
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creator Yu, Wenhao
Lv, Jiqing
Shi, Feng
Song, Kaixin
Lei, Wen
Zhou, Huanfu
Qi, Ze-Ming
Wang, Jing
description Sr(Mg 1/2 Mo 1/2 )O 3 (SMM) microwave dielectric ceramic was prepared by a solid-state sintering method. X-ray diffraction shows that the sample is a single-phase SMM with a tetragonal double perovskite structure (Fm-3m). Raman scattering and FTIR spectroscopy analyze the vibration characteristics of lattice. The far-infrared spectra of SMM ceramics fitted by a FPSQ model are obtained, ε r = 7.39 and tan δ  = 8.19 × 10 –4 . The theoretical properties calculated by the C-M and damping equations are of ε r  = 7.03 and tan δ  = 6.19 × 10 –4 , which agrees well with the experimental values ( ε r  = 7.84 and tan δ  = 6.59 × 10 –4 ). The results show that the stretching vibration of Mg/MoO 6 has the greatest influence on the dielectric properties of the SMM sample.
doi_str_mv 10.1007/s10854-021-06182-0
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X-ray diffraction shows that the sample is a single-phase SMM with a tetragonal double perovskite structure (Fm-3m). Raman scattering and FTIR spectroscopy analyze the vibration characteristics of lattice. The far-infrared spectra of SMM ceramics fitted by a FPSQ model are obtained, ε r = 7.39 and tan δ  = 8.19 × 10 –4 . The theoretical properties calculated by the C-M and damping equations are of ε r  = 7.03 and tan δ  = 6.19 × 10 –4 , which agrees well with the experimental values ( ε r  = 7.84 and tan δ  = 6.59 × 10 –4 ). 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subjects Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Crystal lattices
Crystal structure
Damping
Dielectric properties
Far infrared radiation
Infrared analysis
Infrared spectra
Materials Science
Optical and Electronic Materials
Perovskite structure
Perovskites
Raman spectra
Spectrum analysis
Strontium
Vibration analysis
title Lattice vibrational characteristics, crystal structure, and dielectric properties of single-phase Sr(Mg1/2Mo1/2)O3 microwave dielectric ceramic
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