S-doped NiFe-based catalyst for fast degradation of methylene blue by heterogeneous photo-Fenton reaction

S-doped NiFe-based particles were prepared by a solvothermal method and used to degrade methylene blue (MB) aqueous solutions with visible light in a heterogeneous Fenton reaction. The obtained solid samples were characterized by XRD, SEM, TEM, and XPS. It was found that 0.2 g L −1 NiFe 2 S 4 can de...

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Veröffentlicht in:Environmental science and pollution research international 2021-07, Vol.28 (27), p.36112-36121
Hauptverfasser: Guo, Xiaojun, Meng, Qian, Wang, Dianguo, Zha, Fei, Tang, Xiaohua, Tian, Haifeng
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container_end_page 36121
container_issue 27
container_start_page 36112
container_title Environmental science and pollution research international
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creator Guo, Xiaojun
Meng, Qian
Wang, Dianguo
Zha, Fei
Tang, Xiaohua
Tian, Haifeng
description S-doped NiFe-based particles were prepared by a solvothermal method and used to degrade methylene blue (MB) aqueous solutions with visible light in a heterogeneous Fenton reaction. The obtained solid samples were characterized by XRD, SEM, TEM, and XPS. It was found that 0.2 g L −1 NiFe 2 S 4 can degrade 99.8% MB solution within 6 min in the presence of 5 mM H 2 O 2 and natural pH. The recycle experiments results indicate that the NiFe 2 S 4 catalyst possessed better stability than NiFe 2 O 4 . Furthermore, NiFe 2 S 4 particles can be easily separated from contaminant solution by using a magnet due to their excellent ferromagnetism. COD analysis experiments indicated that the COD removal rate of NiFe 2 S 4 is 73.1% in 30 min. A possible mechanism was proposed, and the degradation products were measured by LC-MS.
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subjects Aquatic Pollution
Aqueous solutions
Atmospheric Protection/Air Quality Control/Air Pollution
Catalysis
Catalysts
Contaminants
Degradation
Degradation products
Earth and Environmental Science
Ecotoxicology
Efficiency
Environment
Environmental Chemistry
Environmental Health
Environmental science
Experiments
Ferromagnetism
Hydrogen Peroxide
Intermetallic compounds
Iron
Iron compounds
Light
Methylene Blue
Nickel compounds
Nickel ferrites
Oxidation
Research Article
Waste Water Technology
Water Management
Water Pollution Control
Water treatment
X ray photoelectron spectroscopy
title S-doped NiFe-based catalyst for fast degradation of methylene blue by heterogeneous photo-Fenton reaction
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