S-doped NiFe-based catalyst for fast degradation of methylene blue by heterogeneous photo-Fenton reaction
S-doped NiFe-based particles were prepared by a solvothermal method and used to degrade methylene blue (MB) aqueous solutions with visible light in a heterogeneous Fenton reaction. The obtained solid samples were characterized by XRD, SEM, TEM, and XPS. It was found that 0.2 g L −1 NiFe 2 S 4 can de...
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Veröffentlicht in: | Environmental science and pollution research international 2021-07, Vol.28 (27), p.36112-36121 |
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creator | Guo, Xiaojun Meng, Qian Wang, Dianguo Zha, Fei Tang, Xiaohua Tian, Haifeng |
description | S-doped NiFe-based particles were prepared by a solvothermal method and used to degrade methylene blue (MB) aqueous solutions with visible light in a heterogeneous Fenton reaction. The obtained solid samples were characterized by XRD, SEM, TEM, and XPS. It was found that 0.2 g L
−1
NiFe
2
S
4
can degrade 99.8% MB solution within 6 min in the presence of 5 mM H
2
O
2
and natural pH. The recycle experiments results indicate that the NiFe
2
S
4
catalyst possessed better stability than NiFe
2
O
4
. Furthermore, NiFe
2
S
4
particles can be easily separated from contaminant solution by using a magnet due to their excellent ferromagnetism. COD analysis experiments indicated that the COD removal rate of NiFe
2
S
4
is 73.1% in 30 min. A possible mechanism was proposed, and the degradation products were measured by LC-MS. |
doi_str_mv | 10.1007/s11356-021-13212-1 |
format | Article |
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−1
NiFe
2
S
4
can degrade 99.8% MB solution within 6 min in the presence of 5 mM H
2
O
2
and natural pH. The recycle experiments results indicate that the NiFe
2
S
4
catalyst possessed better stability than NiFe
2
O
4
. Furthermore, NiFe
2
S
4
particles can be easily separated from contaminant solution by using a magnet due to their excellent ferromagnetism. COD analysis experiments indicated that the COD removal rate of NiFe
2
S
4
is 73.1% in 30 min. A possible mechanism was proposed, and the degradation products were measured by LC-MS.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-021-13212-1</identifier><identifier>PMID: 33682058</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aquatic Pollution ; Aqueous solutions ; Atmospheric Protection/Air Quality Control/Air Pollution ; Catalysis ; Catalysts ; Contaminants ; Degradation ; Degradation products ; Earth and Environmental Science ; Ecotoxicology ; Efficiency ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental science ; Experiments ; Ferromagnetism ; Hydrogen Peroxide ; Intermetallic compounds ; Iron ; Iron compounds ; Light ; Methylene Blue ; Nickel compounds ; Nickel ferrites ; Oxidation ; Research Article ; Waste Water Technology ; Water Management ; Water Pollution Control ; Water treatment ; X ray photoelectron spectroscopy</subject><ispartof>Environmental science and pollution research international, 2021-07, Vol.28 (27), p.36112-36121</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c375t-7f63c2fe4d5e61bc975616eff1ab9a8e787595876100e1030604f79916afe4d83</citedby><cites>FETCH-LOGICAL-c375t-7f63c2fe4d5e61bc975616eff1ab9a8e787595876100e1030604f79916afe4d83</cites><orcidid>0000-0001-6988-616X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-021-13212-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-021-13212-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33682058$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Guo, Xiaojun</creatorcontrib><creatorcontrib>Meng, Qian</creatorcontrib><creatorcontrib>Wang, Dianguo</creatorcontrib><creatorcontrib>Zha, Fei</creatorcontrib><creatorcontrib>Tang, Xiaohua</creatorcontrib><creatorcontrib>Tian, Haifeng</creatorcontrib><title>S-doped NiFe-based catalyst for fast degradation of methylene blue by heterogeneous photo-Fenton reaction</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>S-doped NiFe-based particles were prepared by a solvothermal method and used to degrade methylene blue (MB) aqueous solutions with visible light in a heterogeneous Fenton reaction. The obtained solid samples were characterized by XRD, SEM, TEM, and XPS. It was found that 0.2 g L
−1
NiFe
2
S
4
can degrade 99.8% MB solution within 6 min in the presence of 5 mM H
2
O
2
and natural pH. The recycle experiments results indicate that the NiFe
2
S
4
catalyst possessed better stability than NiFe
2
O
4
. Furthermore, NiFe
2
S
4
particles can be easily separated from contaminant solution by using a magnet due to their excellent ferromagnetism. COD analysis experiments indicated that the COD removal rate of NiFe
2
S
4
is 73.1% in 30 min. A possible mechanism was proposed, and the degradation products were measured by LC-MS.</description><subject>Aquatic Pollution</subject><subject>Aqueous solutions</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Contaminants</subject><subject>Degradation</subject><subject>Degradation products</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Efficiency</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental science</subject><subject>Experiments</subject><subject>Ferromagnetism</subject><subject>Hydrogen Peroxide</subject><subject>Intermetallic compounds</subject><subject>Iron</subject><subject>Iron compounds</subject><subject>Light</subject><subject>Methylene Blue</subject><subject>Nickel compounds</subject><subject>Nickel ferrites</subject><subject>Oxidation</subject><subject>Research Article</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><subject>Water treatment</subject><subject>X ray photoelectron 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NiFe-based catalyst for fast degradation of methylene blue by heterogeneous photo-Fenton reaction</title><author>Guo, Xiaojun ; Meng, Qian ; Wang, Dianguo ; Zha, Fei ; Tang, Xiaohua ; Tian, Haifeng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c375t-7f63c2fe4d5e61bc975616eff1ab9a8e787595876100e1030604f79916afe4d83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aquatic Pollution</topic><topic>Aqueous solutions</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Contaminants</topic><topic>Degradation</topic><topic>Degradation products</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Efficiency</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Environmental science</topic><topic>Experiments</topic><topic>Ferromagnetism</topic><topic>Hydrogen Peroxide</topic><topic>Intermetallic compounds</topic><topic>Iron</topic><topic>Iron compounds</topic><topic>Light</topic><topic>Methylene Blue</topic><topic>Nickel compounds</topic><topic>Nickel ferrites</topic><topic>Oxidation</topic><topic>Research Article</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><topic>Water treatment</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guo, Xiaojun</creatorcontrib><creatorcontrib>Meng, Qian</creatorcontrib><creatorcontrib>Wang, Dianguo</creatorcontrib><creatorcontrib>Zha, Fei</creatorcontrib><creatorcontrib>Tang, Xiaohua</creatorcontrib><creatorcontrib>Tian, Haifeng</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE 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(Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guo, Xiaojun</au><au>Meng, Qian</au><au>Wang, Dianguo</au><au>Zha, Fei</au><au>Tang, Xiaohua</au><au>Tian, Haifeng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>S-doped NiFe-based catalyst for fast degradation of methylene blue by heterogeneous photo-Fenton reaction</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2021-07-01</date><risdate>2021</risdate><volume>28</volume><issue>27</issue><spage>36112</spage><epage>36121</epage><pages>36112-36121</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>S-doped NiFe-based particles were prepared by a solvothermal method and used to degrade methylene blue (MB) aqueous solutions with visible light in a heterogeneous Fenton reaction. The obtained solid samples were characterized by XRD, SEM, TEM, and XPS. It was found that 0.2 g L
−1
NiFe
2
S
4
can degrade 99.8% MB solution within 6 min in the presence of 5 mM H
2
O
2
and natural pH. The recycle experiments results indicate that the NiFe
2
S
4
catalyst possessed better stability than NiFe
2
O
4
. Furthermore, NiFe
2
S
4
particles can be easily separated from contaminant solution by using a magnet due to their excellent ferromagnetism. COD analysis experiments indicated that the COD removal rate of NiFe
2
S
4
is 73.1% in 30 min. A possible mechanism was proposed, and the degradation products were measured by LC-MS.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>33682058</pmid><doi>10.1007/s11356-021-13212-1</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0001-6988-616X</orcidid></addata></record> |
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language | eng |
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source | MEDLINE; SpringerLink Journals - AutoHoldings |
subjects | Aquatic Pollution Aqueous solutions Atmospheric Protection/Air Quality Control/Air Pollution Catalysis Catalysts Contaminants Degradation Degradation products Earth and Environmental Science Ecotoxicology Efficiency Environment Environmental Chemistry Environmental Health Environmental science Experiments Ferromagnetism Hydrogen Peroxide Intermetallic compounds Iron Iron compounds Light Methylene Blue Nickel compounds Nickel ferrites Oxidation Research Article Waste Water Technology Water Management Water Pollution Control Water treatment X ray photoelectron spectroscopy |
title | S-doped NiFe-based catalyst for fast degradation of methylene blue by heterogeneous photo-Fenton reaction |
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