Water-Soluble Chemical Vapor Detection Enabled by Doctor-Blade-Coated Macroporous Photonic Crystals
Water-soluble chemicals, involving a wide range of toxic chemicals in aqueous solutions, remain essential in both daily living or industrial uses. However, most toxicants are evaporated with water through their use and thus cause deleterious effects on the domestic environment and health in humans....
Gespeichert in:
| Veröffentlicht in: | Sensors (Basel, Switzerland) Switzerland), 2020-09, Vol.20 (19), p.5503, Article 5503 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 19 |
| container_start_page | 5503 |
| container_title | Sensors (Basel, Switzerland) |
| container_volume | 20 |
| creator | Wu, Min-Fang Tsai, Hui-Ping Hsieh, Chia-Hua Lu, Yi-Cheng Pan, Liang-Cheng Yang, Hongta |
| description | Water-soluble chemicals, involving a wide range of toxic chemicals in aqueous solutions, remain essential in both daily living or industrial uses. However, most toxicants are evaporated with water through their use and thus cause deleterious effects on the domestic environment and health in humans. Unfortunately, most current low-dose chemical vapor detection technologies are restricted by the use of sophisticated instruments and unable to promptly detect the quantity of diverse toxicants in a single analysis. To address these issues, this study reports the development of simple and fast chemical vapor detection using doctor-blade-coated macroporous poly(2-hydroxyethyl methacrylate)/poly(ethoxylated trimethylolpropane triacrylate) photonic crystals, in which the poly(2-hydroxyethyl methacrylate) has strong affinity to insecticide vapor owing to a favorable Gibbs free energy change for their mixing. The condensation of water-soluble chemical vapor therefore results in a significant reflection peak shift and an obvious color change. The visual colorimetric readout can be further improved by increasing the lattice spacing of the macroporous photonic crystals. Furthermore, the dependence of the reflection peak position on vapor pressure under actual conditions and the reproducibility of vapor detecting are also evaluated in this study. |
| doi_str_mv | 10.3390/s20195503 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_doaj_</sourceid><recordid>TN_cdi_proquest_journals_2550379309</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><doaj_id>oai_doaj_org_article_d705189f873b4271882369506632ce90</doaj_id><sourcerecordid>2550379309</sourcerecordid><originalsourceid>FETCH-LOGICAL-c446t-b0eca273bcc94e01b07eaac9863c5523b5604922e4e66ed74eda0d7c32cf45323</originalsourceid><addsrcrecordid>eNqNkk1v1DAQhiMEoqVw4B9E4gJCgYk_YvuCBGmBSkUg8XW0HHvS9SobL7YD2n-Pl61WlBOnGXmeeT16Z6rqcQsvKFXwMhFoFedA71SnLSOskYTA3b_yk-pBSmsAQimV96sTSpQiUsjTyn43GWPzOUzLMGHdr3DjrZnqb2YbYn2OGW32Ya4vZlPqrh529XmwOcTmzWQcNn0o_a7-YGwMpSMsqf60CjnM3tZ93KVspvSwujeWgI9u4ln19e3Fl_59c_Xx3WX_-qqxjHW5GQCtIYIO1iqG0A4g0BirZEct54QOvAOmCEGGXYdOMHQGnLCU2JFxSuhZdXnQdcGs9Tb6jYk7HYzXfx5CvNYmZm8n1E4Ab6UaZfmOEdFKSWinOHRdUUMFRevVQWu7DBt0FucczXRL9HZl9it9HX5qwYvhfD_M0xuBGH4smLLe-GRxmsyMxSVNGBOctUrSgj75B12HJc7FKk32WxWKgirUswNVnE4p4ngcpgW9PwN9PIPCygP7C4cwJutxtnjkAYBLQUCqkkHb-2z2O-7DMufS-vz_W-lvb7nCxw</addsrcrecordid><sourcetype>Open Website</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2550379309</pqid></control><display><type>article</type><title>Water-Soluble Chemical Vapor Detection Enabled by Doctor-Blade-Coated Macroporous Photonic Crystals</title><source>DOAJ Directory of Open Access Journals</source><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><creator>Wu, Min-Fang ; Tsai, Hui-Ping ; Hsieh, Chia-Hua ; Lu, Yi-Cheng ; Pan, Liang-Cheng ; Yang, Hongta</creator><creatorcontrib>Wu, Min-Fang ; Tsai, Hui-Ping ; Hsieh, Chia-Hua ; Lu, Yi-Cheng ; Pan, Liang-Cheng ; Yang, Hongta</creatorcontrib><description>Water-soluble chemicals, involving a wide range of toxic chemicals in aqueous solutions, remain essential in both daily living or industrial uses. However, most toxicants are evaporated with water through their use and thus cause deleterious effects on the domestic environment and health in humans. Unfortunately, most current low-dose chemical vapor detection technologies are restricted by the use of sophisticated instruments and unable to promptly detect the quantity of diverse toxicants in a single analysis. To address these issues, this study reports the development of simple and fast chemical vapor detection using doctor-blade-coated macroporous poly(2-hydroxyethyl methacrylate)/poly(ethoxylated trimethylolpropane triacrylate) photonic crystals, in which the poly(2-hydroxyethyl methacrylate) has strong affinity to insecticide vapor owing to a favorable Gibbs free energy change for their mixing. The condensation of water-soluble chemical vapor therefore results in a significant reflection peak shift and an obvious color change. The visual colorimetric readout can be further improved by increasing the lattice spacing of the macroporous photonic crystals. Furthermore, the dependence of the reflection peak position on vapor pressure under actual conditions and the reproducibility of vapor detecting are also evaluated in this study.</description><identifier>ISSN: 1424-8220</identifier><identifier>EISSN: 1424-8220</identifier><identifier>DOI: 10.3390/s20195503</identifier><identifier>PMID: 32992878</identifier><language>eng</language><publisher>BASEL: Mdpi</publisher><subject>Acids ; Aqueous solutions ; Chemicals ; Chemistry ; Chemistry, Analytical ; Chromatography ; Colorimetry ; Contaminants ; Crystal lattices ; detecting ; doctor-blade coating ; Engineering ; Engineering, Electrical & Electronic ; Enzymes ; Ethanol ; Gibbs free energy ; Glass substrates ; Industrial applications ; Insecticides ; Instruments & Instrumentation ; Laboratories ; Letter ; Optics ; Photonic crystals ; Physical Sciences ; Polyhydroxyethyl methacrylate ; Science & Technology ; Technology ; Vapor pressure ; visual colorimetric readout ; Water chemistry ; water-soluble chemicals</subject><ispartof>Sensors (Basel, Switzerland), 2020-09, Vol.20 (19), p.5503, Article 5503</ispartof><rights>2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2020 by the authors. 2020</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>2</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000587208900001</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c446t-b0eca273bcc94e01b07eaac9863c5523b5604922e4e66ed74eda0d7c32cf45323</citedby><cites>FETCH-LOGICAL-c446t-b0eca273bcc94e01b07eaac9863c5523b5604922e4e66ed74eda0d7c32cf45323</cites><orcidid>0000-0002-4915-1075</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7582252/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7582252/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,315,728,781,785,865,886,2103,2115,27928,27929,53795,53797</link.rule.ids></links><search><creatorcontrib>Wu, Min-Fang</creatorcontrib><creatorcontrib>Tsai, Hui-Ping</creatorcontrib><creatorcontrib>Hsieh, Chia-Hua</creatorcontrib><creatorcontrib>Lu, Yi-Cheng</creatorcontrib><creatorcontrib>Pan, Liang-Cheng</creatorcontrib><creatorcontrib>Yang, Hongta</creatorcontrib><title>Water-Soluble Chemical Vapor Detection Enabled by Doctor-Blade-Coated Macroporous Photonic Crystals</title><title>Sensors (Basel, Switzerland)</title><addtitle>SENSORS-BASEL</addtitle><description>Water-soluble chemicals, involving a wide range of toxic chemicals in aqueous solutions, remain essential in both daily living or industrial uses. However, most toxicants are evaporated with water through their use and thus cause deleterious effects on the domestic environment and health in humans. Unfortunately, most current low-dose chemical vapor detection technologies are restricted by the use of sophisticated instruments and unable to promptly detect the quantity of diverse toxicants in a single analysis. To address these issues, this study reports the development of simple and fast chemical vapor detection using doctor-blade-coated macroporous poly(2-hydroxyethyl methacrylate)/poly(ethoxylated trimethylolpropane triacrylate) photonic crystals, in which the poly(2-hydroxyethyl methacrylate) has strong affinity to insecticide vapor owing to a favorable Gibbs free energy change for their mixing. The condensation of water-soluble chemical vapor therefore results in a significant reflection peak shift and an obvious color change. The visual colorimetric readout can be further improved by increasing the lattice spacing of the macroporous photonic crystals. Furthermore, the dependence of the reflection peak position on vapor pressure under actual conditions and the reproducibility of vapor detecting are also evaluated in this study.</description><subject>Acids</subject><subject>Aqueous solutions</subject><subject>Chemicals</subject><subject>Chemistry</subject><subject>Chemistry, Analytical</subject><subject>Chromatography</subject><subject>Colorimetry</subject><subject>Contaminants</subject><subject>Crystal lattices</subject><subject>detecting</subject><subject>doctor-blade coating</subject><subject>Engineering</subject><subject>Engineering, Electrical & Electronic</subject><subject>Enzymes</subject><subject>Ethanol</subject><subject>Gibbs free energy</subject><subject>Glass substrates</subject><subject>Industrial applications</subject><subject>Insecticides</subject><subject>Instruments & Instrumentation</subject><subject>Laboratories</subject><subject>Letter</subject><subject>Optics</subject><subject>Photonic crystals</subject><subject>Physical Sciences</subject><subject>Polyhydroxyethyl methacrylate</subject><subject>Science & Technology</subject><subject>Technology</subject><subject>Vapor pressure</subject><subject>visual colorimetric readout</subject><subject>Water chemistry</subject><subject>water-soluble chemicals</subject><issn>1424-8220</issn><issn>1424-8220</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>DOA</sourceid><recordid>eNqNkk1v1DAQhiMEoqVw4B9E4gJCgYk_YvuCBGmBSkUg8XW0HHvS9SobL7YD2n-Pl61WlBOnGXmeeT16Z6rqcQsvKFXwMhFoFedA71SnLSOskYTA3b_yk-pBSmsAQimV96sTSpQiUsjTyn43GWPzOUzLMGHdr3DjrZnqb2YbYn2OGW32Ya4vZlPqrh529XmwOcTmzWQcNn0o_a7-YGwMpSMsqf60CjnM3tZ93KVspvSwujeWgI9u4ln19e3Fl_59c_Xx3WX_-qqxjHW5GQCtIYIO1iqG0A4g0BirZEct54QOvAOmCEGGXYdOMHQGnLCU2JFxSuhZdXnQdcGs9Tb6jYk7HYzXfx5CvNYmZm8n1E4Ab6UaZfmOEdFKSWinOHRdUUMFRevVQWu7DBt0FucczXRL9HZl9it9HX5qwYvhfD_M0xuBGH4smLLe-GRxmsyMxSVNGBOctUrSgj75B12HJc7FKk32WxWKgirUswNVnE4p4ngcpgW9PwN9PIPCygP7C4cwJutxtnjkAYBLQUCqkkHb-2z2O-7DMufS-vz_W-lvb7nCxw</recordid><startdate>20200925</startdate><enddate>20200925</enddate><creator>Wu, Min-Fang</creator><creator>Tsai, Hui-Ping</creator><creator>Hsieh, Chia-Hua</creator><creator>Lu, Yi-Cheng</creator><creator>Pan, Liang-Cheng</creator><creator>Yang, Hongta</creator><general>Mdpi</general><general>MDPI AG</general><general>MDPI</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>7X8</scope><scope>5PM</scope><scope>DOA</scope><orcidid>https://orcid.org/0000-0002-4915-1075</orcidid></search><sort><creationdate>20200925</creationdate><title>Water-Soluble Chemical Vapor Detection Enabled by Doctor-Blade-Coated Macroporous Photonic Crystals</title><author>Wu, Min-Fang ; Tsai, Hui-Ping ; Hsieh, Chia-Hua ; Lu, Yi-Cheng ; Pan, Liang-Cheng ; Yang, Hongta</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c446t-b0eca273bcc94e01b07eaac9863c5523b5604922e4e66ed74eda0d7c32cf45323</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Acids</topic><topic>Aqueous solutions</topic><topic>Chemicals</topic><topic>Chemistry</topic><topic>Chemistry, Analytical</topic><topic>Chromatography</topic><topic>Colorimetry</topic><topic>Contaminants</topic><topic>Crystal lattices</topic><topic>detecting</topic><topic>doctor-blade coating</topic><topic>Engineering</topic><topic>Engineering, Electrical & Electronic</topic><topic>Enzymes</topic><topic>Ethanol</topic><topic>Gibbs free energy</topic><topic>Glass substrates</topic><topic>Industrial applications</topic><topic>Insecticides</topic><topic>Instruments & Instrumentation</topic><topic>Laboratories</topic><topic>Letter</topic><topic>Optics</topic><topic>Photonic crystals</topic><topic>Physical Sciences</topic><topic>Polyhydroxyethyl methacrylate</topic><topic>Science & Technology</topic><topic>Technology</topic><topic>Vapor pressure</topic><topic>visual colorimetric readout</topic><topic>Water chemistry</topic><topic>water-soluble chemicals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Min-Fang</creatorcontrib><creatorcontrib>Tsai, Hui-Ping</creatorcontrib><creatorcontrib>Hsieh, Chia-Hua</creatorcontrib><creatorcontrib>Lu, Yi-Cheng</creatorcontrib><creatorcontrib>Pan, Liang-Cheng</creatorcontrib><creatorcontrib>Yang, Hongta</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Access via ProQuest (Open Access)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Sensors (Basel, Switzerland)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Min-Fang</au><au>Tsai, Hui-Ping</au><au>Hsieh, Chia-Hua</au><au>Lu, Yi-Cheng</au><au>Pan, Liang-Cheng</au><au>Yang, Hongta</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Water-Soluble Chemical Vapor Detection Enabled by Doctor-Blade-Coated Macroporous Photonic Crystals</atitle><jtitle>Sensors (Basel, Switzerland)</jtitle><stitle>SENSORS-BASEL</stitle><date>2020-09-25</date><risdate>2020</risdate><volume>20</volume><issue>19</issue><spage>5503</spage><pages>5503-</pages><artnum>5503</artnum><issn>1424-8220</issn><eissn>1424-8220</eissn><abstract>Water-soluble chemicals, involving a wide range of toxic chemicals in aqueous solutions, remain essential in both daily living or industrial uses. However, most toxicants are evaporated with water through their use and thus cause deleterious effects on the domestic environment and health in humans. Unfortunately, most current low-dose chemical vapor detection technologies are restricted by the use of sophisticated instruments and unable to promptly detect the quantity of diverse toxicants in a single analysis. To address these issues, this study reports the development of simple and fast chemical vapor detection using doctor-blade-coated macroporous poly(2-hydroxyethyl methacrylate)/poly(ethoxylated trimethylolpropane triacrylate) photonic crystals, in which the poly(2-hydroxyethyl methacrylate) has strong affinity to insecticide vapor owing to a favorable Gibbs free energy change for their mixing. The condensation of water-soluble chemical vapor therefore results in a significant reflection peak shift and an obvious color change. The visual colorimetric readout can be further improved by increasing the lattice spacing of the macroporous photonic crystals. Furthermore, the dependence of the reflection peak position on vapor pressure under actual conditions and the reproducibility of vapor detecting are also evaluated in this study.</abstract><cop>BASEL</cop><pub>Mdpi</pub><pmid>32992878</pmid><doi>10.3390/s20195503</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0002-4915-1075</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1424-8220 |
| ispartof | Sensors (Basel, Switzerland), 2020-09, Vol.20 (19), p.5503, Article 5503 |
| issn | 1424-8220 1424-8220 |
| language | eng |
| recordid | cdi_proquest_journals_2550379309 |
| source | DOAJ Directory of Open Access Journals; MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central; Free Full-Text Journals in Chemistry |
| subjects | Acids Aqueous solutions Chemicals Chemistry Chemistry, Analytical Chromatography Colorimetry Contaminants Crystal lattices detecting doctor-blade coating Engineering Engineering, Electrical & Electronic Enzymes Ethanol Gibbs free energy Glass substrates Industrial applications Insecticides Instruments & Instrumentation Laboratories Letter Optics Photonic crystals Physical Sciences Polyhydroxyethyl methacrylate Science & Technology Technology Vapor pressure visual colorimetric readout Water chemistry water-soluble chemicals |
| title | Water-Soluble Chemical Vapor Detection Enabled by Doctor-Blade-Coated Macroporous Photonic Crystals |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-17T12%3A00%3A25IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_doaj_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Water-Soluble%20Chemical%20Vapor%20Detection%20Enabled%20by%20Doctor-Blade-Coated%20Macroporous%20Photonic%20Crystals&rft.jtitle=Sensors%20(Basel,%20Switzerland)&rft.au=Wu,%20Min-Fang&rft.date=2020-09-25&rft.volume=20&rft.issue=19&rft.spage=5503&rft.pages=5503-&rft.artnum=5503&rft.issn=1424-8220&rft.eissn=1424-8220&rft_id=info:doi/10.3390/s20195503&rft_dat=%3Cproquest_doaj_%3E2550379309%3C/proquest_doaj_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2550379309&rft_id=info:pmid/32992878&rft_doaj_id=oai_doaj_org_article_d705189f873b4271882369506632ce90&rfr_iscdi=true |