Enantiopure Polyradical Tetrahedral Pd12L6 Cages

The synthesis of cages with a polyradical framework remains a challenging task. Herein is reported an enantiomeric pair of quinoid‐bridged polyradical tetrahedral palladium(II) cages that are stabilized by an unusual dianionic diradical form (dhbq..2−). These cages have been characterized by electro...

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Veröffentlicht in:	Chemistry : a European journal 2021-07, Vol.27 (39), p.10012-10015
Hauptverfasser:	Rajasekar, Prabhakaran, Swain, Abinash, Rajaraman, Gopalan, Boomishankar, Ramamoorthy
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Cages Chemistry chirality Crystal structure Electron paramagnetic resonance Electron spin resonance Ferromagnetism Magnetic measurement Mass spectrometry Mass spectroscopy Palladium P−N ligands radicals Superconducting quantum interference devices
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