Heterogeneous Catalyst Based on Phosphine-Containing Organic Polymer for Hydroformylation of Octene-1

A phosphine-containing porous polymer (TPDB), and a rhodium catalyst based on it, were synthesized. Proceeding from the relevant TEM, NMR, IR spectroscopy, and XPS data obtained, it was assumed that both the Rh(I) complexes and the Rh(0) nanoparticles that are stabilized in the polymer pores act as...

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Veröffentlicht in:	Petroleum chemistry 2021-06, Vol.61 (6), p.688-696
Hauptverfasser:	Gorbunov, D. N., Nenasheva, M. V., Matsukevich, R. P., Terenina, M. V., Kardasheva, Yu. S., Karakhanov, E. A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Catalysts Chemical synthesis Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Infrared spectroscopy Nanoparticles NMR Nuclear magnetic resonance Nuclear magnetic resonance spectroscopy Octenes Phosphines Polymer industry Polymers Rhodium X ray photoelectron spectroscopy
Online-Zugang:	Volltext
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