Expanding Family of Litharge-Derived Sulfate Minerals and Synthetic Compounds: Preparation and Crystal Structures of [Bi2CuO3]SO4 and [Ln2O2]SO4 (Ln = Dy and Ho)
During the last decades, layered structures have attracted particular and increasing interest due to the multitude of outstanding properties exhibited by their representatives. Particularly common among their archetypes, with a significant number of mineral and synthetic species structural derivativ...
Gespeichert in:
| Veröffentlicht in: | Minerals (Basel) 2020-10, Vol.10 (10), p.887 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 10 |
| container_start_page | 887 |
| container_title | Minerals (Basel) |
| container_volume | 10 |
| creator | Siidra, Oleg Charkin, Dmitri Plokhikh, Igor Nazarchuk, Evgeny Holzheid, Astrid Akimov, Georgy |
| description | During the last decades, layered structures have attracted particular and increasing interest due to the multitude of outstanding properties exhibited by their representatives. Particularly common among their archetypes, with a significant number of mineral and synthetic species structural derivatives, is that of litharge. In the current paper, we report the structural studies of two later rare-earth oxysulfates, [Ln2O2]SO4 (Ln = Dy, Ho), which belong indeed to the grandreefite family, and a novel compound [Bi2CuO3]SO4, which belongs to a new structure type and demonstrates the second example of Cu2+ incorporation into litharge-type slabs. Crystals of [Bi2CuO3]SO4 were obtained under high-pressure/high-temperature (HP/HT) conditions, whereas polycrystalline samples of [Ln2O2]SO4 (Ln = Dy, Ho) compounds were prepared via an exchange solid-state reaction. The crystal structure of [Bi2CuO3]SO4 is based on alternation of continuous [Bi2CuO3]2+ layers of edge-sharing OBi2Cu2 and OBi3Cu tetrahedra and sheets of sulfate groups. Cu2+ cations are in cis position in O5Bi2Cu2 and O6Bi2Cu2 oxocentered tetrahedra in litharge slab. The crystal structure of [Ln2O2]SO4 (Ln = Dy, Ho) is completely analogous to those of grandreefite and oxysulfates of La, Sm, Eu, and Bi. |
| doi_str_mv | 10.3390/min10100887 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2549047275</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2549047275</sourcerecordid><originalsourceid>FETCH-LOGICAL-c298t-39cf0c3e6d404937de4b925e0897d8ed78f38ff2b6711b9195e7735f9c58afd3</originalsourceid><addsrcrecordid>eNpNkU9LwzAYxosoOOZOfoGAF0Wq-dMuieBBu80JlQnbQRhSsjbZMra0JqnYj-M3tds87L28f_i9z3N4guASwTtCOLzfaoMggpAxehJ0MKRxiPrk4_RoPg96zq1hWxwRFuNO8Dv8qYQptFmCkdjqTQNKBVLtV8IuZTiQVn_LAkzrjRJegjdtpBUbB9oXMG2MX0mvc5CU26qsTeEewLuVlbDC69LsocQ2zosNmHpb57620u0M5s8aJ_WEfE4n0R6bpwZP8H69Tg14BINmfx-XNxfBmWotZe-_d4PZaDhLxmE6eXlNntIwx5z5kPBcwZzIfhHBiBNayGjBcSwh47RgsqBMEaYUXvQpQguOeCwpJbHiecyEKkg3uDrIVrb8qqXz2bqsrWkdMxxHHEYU07ilbg9UbkvnrFRZZfVW2CZDMNulkB2lQP4AxOF5oQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2549047275</pqid></control><display><type>article</type><title>Expanding Family of Litharge-Derived Sulfate Minerals and Synthetic Compounds: Preparation and Crystal Structures of [Bi2CuO3]SO4 and [Ln2O2]SO4 (Ln = Dy and Ho)</title><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>EZB-FREE-00999 freely available EZB journals</source><source>Alma/SFX Local Collection</source><creator>Siidra, Oleg ; Charkin, Dmitri ; Plokhikh, Igor ; Nazarchuk, Evgeny ; Holzheid, Astrid ; Akimov, Georgy</creator><creatorcontrib>Siidra, Oleg ; Charkin, Dmitri ; Plokhikh, Igor ; Nazarchuk, Evgeny ; Holzheid, Astrid ; Akimov, Georgy</creatorcontrib><description>During the last decades, layered structures have attracted particular and increasing interest due to the multitude of outstanding properties exhibited by their representatives. Particularly common among their archetypes, with a significant number of mineral and synthetic species structural derivatives, is that of litharge. In the current paper, we report the structural studies of two later rare-earth oxysulfates, [Ln2O2]SO4 (Ln = Dy, Ho), which belong indeed to the grandreefite family, and a novel compound [Bi2CuO3]SO4, which belongs to a new structure type and demonstrates the second example of Cu2+ incorporation into litharge-type slabs. Crystals of [Bi2CuO3]SO4 were obtained under high-pressure/high-temperature (HP/HT) conditions, whereas polycrystalline samples of [Ln2O2]SO4 (Ln = Dy, Ho) compounds were prepared via an exchange solid-state reaction. The crystal structure of [Bi2CuO3]SO4 is based on alternation of continuous [Bi2CuO3]2+ layers of edge-sharing OBi2Cu2 and OBi3Cu tetrahedra and sheets of sulfate groups. Cu2+ cations are in cis position in O5Bi2Cu2 and O6Bi2Cu2 oxocentered tetrahedra in litharge slab. The crystal structure of [Ln2O2]SO4 (Ln = Dy, Ho) is completely analogous to those of grandreefite and oxysulfates of La, Sm, Eu, and Bi.</description><identifier>ISSN: 2075-163X</identifier><identifier>EISSN: 2075-163X</identifier><identifier>DOI: 10.3390/min10100887</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Cations ; Cooling ; Copper ; Crystal structure ; Crystals ; Dysprosium ; High temperature ; Investigations ; Minerals ; Rare earth elements ; Slabs ; Sulfates ; Sulphates ; Tetrahedra</subject><ispartof>Minerals (Basel), 2020-10, Vol.10 (10), p.887</ispartof><rights>2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c298t-39cf0c3e6d404937de4b925e0897d8ed78f38ff2b6711b9195e7735f9c58afd3</citedby><cites>FETCH-LOGICAL-c298t-39cf0c3e6d404937de4b925e0897d8ed78f38ff2b6711b9195e7735f9c58afd3</cites><orcidid>0009-0008-6440-6209 ; 0000-0001-5154-9886 ; 0000-0003-1908-3152</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Siidra, Oleg</creatorcontrib><creatorcontrib>Charkin, Dmitri</creatorcontrib><creatorcontrib>Plokhikh, Igor</creatorcontrib><creatorcontrib>Nazarchuk, Evgeny</creatorcontrib><creatorcontrib>Holzheid, Astrid</creatorcontrib><creatorcontrib>Akimov, Georgy</creatorcontrib><title>Expanding Family of Litharge-Derived Sulfate Minerals and Synthetic Compounds: Preparation and Crystal Structures of [Bi2CuO3]SO4 and [Ln2O2]SO4 (Ln = Dy and Ho)</title><title>Minerals (Basel)</title><description>During the last decades, layered structures have attracted particular and increasing interest due to the multitude of outstanding properties exhibited by their representatives. Particularly common among their archetypes, with a significant number of mineral and synthetic species structural derivatives, is that of litharge. In the current paper, we report the structural studies of two later rare-earth oxysulfates, [Ln2O2]SO4 (Ln = Dy, Ho), which belong indeed to the grandreefite family, and a novel compound [Bi2CuO3]SO4, which belongs to a new structure type and demonstrates the second example of Cu2+ incorporation into litharge-type slabs. Crystals of [Bi2CuO3]SO4 were obtained under high-pressure/high-temperature (HP/HT) conditions, whereas polycrystalline samples of [Ln2O2]SO4 (Ln = Dy, Ho) compounds were prepared via an exchange solid-state reaction. The crystal structure of [Bi2CuO3]SO4 is based on alternation of continuous [Bi2CuO3]2+ layers of edge-sharing OBi2Cu2 and OBi3Cu tetrahedra and sheets of sulfate groups. Cu2+ cations are in cis position in O5Bi2Cu2 and O6Bi2Cu2 oxocentered tetrahedra in litharge slab. The crystal structure of [Ln2O2]SO4 (Ln = Dy, Ho) is completely analogous to those of grandreefite and oxysulfates of La, Sm, Eu, and Bi.</description><subject>Cations</subject><subject>Cooling</subject><subject>Copper</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Dysprosium</subject><subject>High temperature</subject><subject>Investigations</subject><subject>Minerals</subject><subject>Rare earth elements</subject><subject>Slabs</subject><subject>Sulfates</subject><subject>Sulphates</subject><subject>Tetrahedra</subject><issn>2075-163X</issn><issn>2075-163X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpNkU9LwzAYxosoOOZOfoGAF0Wq-dMuieBBu80JlQnbQRhSsjbZMra0JqnYj-M3tds87L28f_i9z3N4guASwTtCOLzfaoMggpAxehJ0MKRxiPrk4_RoPg96zq1hWxwRFuNO8Dv8qYQptFmCkdjqTQNKBVLtV8IuZTiQVn_LAkzrjRJegjdtpBUbB9oXMG2MX0mvc5CU26qsTeEewLuVlbDC69LsocQ2zosNmHpb57620u0M5s8aJ_WEfE4n0R6bpwZP8H69Tg14BINmfx-XNxfBmWotZe-_d4PZaDhLxmE6eXlNntIwx5z5kPBcwZzIfhHBiBNayGjBcSwh47RgsqBMEaYUXvQpQguOeCwpJbHiecyEKkg3uDrIVrb8qqXz2bqsrWkdMxxHHEYU07ilbg9UbkvnrFRZZfVW2CZDMNulkB2lQP4AxOF5oQ</recordid><startdate>20201001</startdate><enddate>20201001</enddate><creator>Siidra, Oleg</creator><creator>Charkin, Dmitri</creator><creator>Plokhikh, Igor</creator><creator>Nazarchuk, Evgeny</creator><creator>Holzheid, Astrid</creator><creator>Akimov, Georgy</creator><general>MDPI AG</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7TN</scope><scope>7UA</scope><scope>7WY</scope><scope>7WZ</scope><scope>7XB</scope><scope>87Z</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8FL</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>C1K</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F1W</scope><scope>FR3</scope><scope>FRNLG</scope><scope>F~G</scope><scope>H96</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K60</scope><scope>K6~</scope><scope>KB.</scope><scope>KR7</scope><scope>L.-</scope><scope>L.G</scope><scope>M0C</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><orcidid>https://orcid.org/0009-0008-6440-6209</orcidid><orcidid>https://orcid.org/0000-0001-5154-9886</orcidid><orcidid>https://orcid.org/0000-0003-1908-3152</orcidid></search><sort><creationdate>20201001</creationdate><title>Expanding Family of Litharge-Derived Sulfate Minerals and Synthetic Compounds: Preparation and Crystal Structures of [Bi2CuO3]SO4 and [Ln2O2]SO4 (Ln = Dy and Ho)</title><author>Siidra, Oleg ; Charkin, Dmitri ; Plokhikh, Igor ; Nazarchuk, Evgeny ; Holzheid, Astrid ; Akimov, Georgy</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c298t-39cf0c3e6d404937de4b925e0897d8ed78f38ff2b6711b9195e7735f9c58afd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Cations</topic><topic>Cooling</topic><topic>Copper</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Dysprosium</topic><topic>High temperature</topic><topic>Investigations</topic><topic>Minerals</topic><topic>Rare earth elements</topic><topic>Slabs</topic><topic>Sulfates</topic><topic>Sulphates</topic><topic>Tetrahedra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Siidra, Oleg</creatorcontrib><creatorcontrib>Charkin, Dmitri</creatorcontrib><creatorcontrib>Plokhikh, Igor</creatorcontrib><creatorcontrib>Nazarchuk, Evgeny</creatorcontrib><creatorcontrib>Holzheid, Astrid</creatorcontrib><creatorcontrib>Akimov, Georgy</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Oceanic Abstracts</collection><collection>Water Resources Abstracts</collection><collection>ABI/INFORM Collection</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Global (Alumni Edition)</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Engineering Research Database</collection><collection>Business Premium Collection (Alumni)</collection><collection>ABI/INFORM Global (Corporate)</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>Materials Science Database</collection><collection>Civil Engineering Abstracts</collection><collection>ABI/INFORM Professional Advanced</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>ABI/INFORM Global</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Business</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Minerals (Basel)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Siidra, Oleg</au><au>Charkin, Dmitri</au><au>Plokhikh, Igor</au><au>Nazarchuk, Evgeny</au><au>Holzheid, Astrid</au><au>Akimov, Georgy</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Expanding Family of Litharge-Derived Sulfate Minerals and Synthetic Compounds: Preparation and Crystal Structures of [Bi2CuO3]SO4 and [Ln2O2]SO4 (Ln = Dy and Ho)</atitle><jtitle>Minerals (Basel)</jtitle><date>2020-10-01</date><risdate>2020</risdate><volume>10</volume><issue>10</issue><spage>887</spage><pages>887-</pages><issn>2075-163X</issn><eissn>2075-163X</eissn><abstract>During the last decades, layered structures have attracted particular and increasing interest due to the multitude of outstanding properties exhibited by their representatives. Particularly common among their archetypes, with a significant number of mineral and synthetic species structural derivatives, is that of litharge. In the current paper, we report the structural studies of two later rare-earth oxysulfates, [Ln2O2]SO4 (Ln = Dy, Ho), which belong indeed to the grandreefite family, and a novel compound [Bi2CuO3]SO4, which belongs to a new structure type and demonstrates the second example of Cu2+ incorporation into litharge-type slabs. Crystals of [Bi2CuO3]SO4 were obtained under high-pressure/high-temperature (HP/HT) conditions, whereas polycrystalline samples of [Ln2O2]SO4 (Ln = Dy, Ho) compounds were prepared via an exchange solid-state reaction. The crystal structure of [Bi2CuO3]SO4 is based on alternation of continuous [Bi2CuO3]2+ layers of edge-sharing OBi2Cu2 and OBi3Cu tetrahedra and sheets of sulfate groups. Cu2+ cations are in cis position in O5Bi2Cu2 and O6Bi2Cu2 oxocentered tetrahedra in litharge slab. The crystal structure of [Ln2O2]SO4 (Ln = Dy, Ho) is completely analogous to those of grandreefite and oxysulfates of La, Sm, Eu, and Bi.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/min10100887</doi><orcidid>https://orcid.org/0009-0008-6440-6209</orcidid><orcidid>https://orcid.org/0000-0001-5154-9886</orcidid><orcidid>https://orcid.org/0000-0003-1908-3152</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2075-163X |
| ispartof | Minerals (Basel), 2020-10, Vol.10 (10), p.887 |
| issn | 2075-163X 2075-163X |
| language | eng |
| recordid | cdi_proquest_journals_2549047275 |
| source | MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; Alma/SFX Local Collection |
| subjects | Cations Cooling Copper Crystal structure Crystals Dysprosium High temperature Investigations Minerals Rare earth elements Slabs Sulfates Sulphates Tetrahedra |
| title | Expanding Family of Litharge-Derived Sulfate Minerals and Synthetic Compounds: Preparation and Crystal Structures of [Bi2CuO3]SO4 and [Ln2O2]SO4 (Ln = Dy and Ho) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-12T05%3A15%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Expanding%20Family%20of%20Litharge-Derived%20Sulfate%20Minerals%20and%20Synthetic%20Compounds:%20Preparation%20and%20Crystal%20Structures%20of%20%5BBi2CuO3%5DSO4%20and%20%5BLn2O2%5DSO4%20(Ln%20=%20Dy%20and%20Ho)&rft.jtitle=Minerals%20(Basel)&rft.au=Siidra,%20Oleg&rft.date=2020-10-01&rft.volume=10&rft.issue=10&rft.spage=887&rft.pages=887-&rft.issn=2075-163X&rft.eissn=2075-163X&rft_id=info:doi/10.3390/min10100887&rft_dat=%3Cproquest_cross%3E2549047275%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2549047275&rft_id=info:pmid/&rfr_iscdi=true |