Copper-catalyzed P-H insertion reactions of sulfoxonium ylides

A copper-catalyzed P-H insertion reaction between sulfoxonium ylides and H-phosphorus oxides has been demonstrated, furnishing α-phosphonyl carboxylate derivatives in 41-93% yields. This methodology utilizing bench-stable and thermodynamically stable sulfoxonium ylides as carbene precursors in the p...

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Veröffentlicht in:	Organic & biomolecular chemistry 2021-07, Vol.19 (26), p.5767-5771
Hauptverfasser:	Zhang, Xinzhi, Zhang, Yangyang, Liang, Cuijian, Jiang, Jun
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysts Chemical reactions Copper Functional groups Insertion Phosphorus Phosphorus oxides
Online-Zugang:	Volltext
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