N-Methylmorpholine-N-oxide (NMMO): hazards in practice and pitfalls in theory
The hazards of handling N -methylmorpholine- N -oxide (NMMO) cannot be described often enough, although it is a rather common (co-)solvent for cellulose. Inaccuracies in the literature regarding the chemistry of NMMO, such as its role in solvent systems and in redox systems involving transition meta...
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| Veröffentlicht in: | Cellulose (London) 2021-07, Vol.28 (10), p.5985-5990 |
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| container_title | Cellulose (London) |
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| creator | Rosenau, Thomas French, Alfred D. |
| description | The hazards of handling
N
-methylmorpholine-
N
-oxide (NMMO) cannot be described often enough, although it is a rather common (co-)solvent for cellulose. Inaccuracies in the literature regarding the chemistry of NMMO, such as its role in solvent systems and in redox systems involving transition metal ions, increase the risk of dangerous failure of the intended reactions which might result in uncontrolled exothermicities, damage of laboratory equipment or even accidents and work safety issues. Therefore, suitable cautionary and mitigation strategy statements regarding the hazards of handling NMMO are encouraged for future publications regarding NMMO and cellulose. |
| doi_str_mv | 10.1007/s10570-021-03860-4 |
| format | Article |
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N
-methylmorpholine-
N
-oxide (NMMO) cannot be described often enough, although it is a rather common (co-)solvent for cellulose. Inaccuracies in the literature regarding the chemistry of NMMO, such as its role in solvent systems and in redox systems involving transition metal ions, increase the risk of dangerous failure of the intended reactions which might result in uncontrolled exothermicities, damage of laboratory equipment or even accidents and work safety issues. Therefore, suitable cautionary and mitigation strategy statements regarding the hazards of handling NMMO are encouraged for future publications regarding NMMO and cellulose.</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-021-03860-4</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Bioorganic Chemistry ; Cellulose ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Communication ; Composites ; Exothermic reactions ; Glass ; Hazard mitigation ; Natural Materials ; Organic Chemistry ; Physical Chemistry ; Polymer Sciences ; Solvents ; Sustainable Development ; Transition metals</subject><ispartof>Cellulose (London), 2021-07, Vol.28 (10), p.5985-5990</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c385t-7c1e43be64e99c980ffd5615a6cd472b2823ff2f8fe4d6f42c94cf11768081a13</citedby><cites>FETCH-LOGICAL-c385t-7c1e43be64e99c980ffd5615a6cd472b2823ff2f8fe4d6f42c94cf11768081a13</cites><orcidid>0000-0002-6636-9260</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-021-03860-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-021-03860-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Rosenau, Thomas</creatorcontrib><creatorcontrib>French, Alfred D.</creatorcontrib><title>N-Methylmorpholine-N-oxide (NMMO): hazards in practice and pitfalls in theory</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><description>The hazards of handling
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-methylmorpholine-
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Therefore, suitable cautionary and mitigation strategy statements regarding the hazards of handling NMMO are encouraged for future publications regarding NMMO and cellulose.</description><subject>Bioorganic Chemistry</subject><subject>Cellulose</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Communication</subject><subject>Composites</subject><subject>Exothermic reactions</subject><subject>Glass</subject><subject>Hazard mitigation</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Solvents</subject><subject>Sustainable Development</subject><subject>Transition metals</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE1LwzAYx4MoOKdfwFPBix6iT9I0L95k-AbrdlHwFrI0sR1dW5MOnJ_eugrePD3wf3vgh9A5gWsCIG4igUwABkowpJIDZgdoQjJBsZT07RBNQHE12Kk6RicxrgFACUomKF_g3PXlrt60oSvbumocXuD2sypccrnI8-XVbVKaLxOKmFRN0gVj-8q6xDRF0lW9N3W9N_rStWF3io4GJbqz3ztFrw_3L7MnPF8-Ps_u5timMuuxsMSxdOU4c0pZJcH7IuMkM9wWTNAVlTT1nnrpHSu4Z9QqZj0hgkuQxJB0ii7G3S60H1sXe71ut6EZXmqaMUkVZ4oPKTqmbGhjDM7rLlQbE3aagP7BpkdsesCm99g0G0rpWIpDuHl34W_6n9Y3hpNu7A</recordid><startdate>20210701</startdate><enddate>20210701</enddate><creator>Rosenau, Thomas</creator><creator>French, Alfred D.</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0002-6636-9260</orcidid></search><sort><creationdate>20210701</creationdate><title>N-Methylmorpholine-N-oxide (NMMO): hazards in practice and pitfalls in theory</title><author>Rosenau, Thomas ; French, Alfred D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c385t-7c1e43be64e99c980ffd5615a6cd472b2823ff2f8fe4d6f42c94cf11768081a13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Bioorganic Chemistry</topic><topic>Cellulose</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Communication</topic><topic>Composites</topic><topic>Exothermic reactions</topic><topic>Glass</topic><topic>Hazard mitigation</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Solvents</topic><topic>Sustainable Development</topic><topic>Transition metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rosenau, Thomas</creatorcontrib><creatorcontrib>French, Alfred D.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rosenau, Thomas</au><au>French, Alfred D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>N-Methylmorpholine-N-oxide (NMMO): hazards in practice and pitfalls in theory</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><date>2021-07-01</date><risdate>2021</risdate><volume>28</volume><issue>10</issue><spage>5985</spage><epage>5990</epage><pages>5985-5990</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>The hazards of handling
N
-methylmorpholine-
N
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| subjects | Bioorganic Chemistry Cellulose Ceramics Chemistry Chemistry and Materials Science Communication Composites Exothermic reactions Glass Hazard mitigation Natural Materials Organic Chemistry Physical Chemistry Polymer Sciences Solvents Sustainable Development Transition metals |
| title | N-Methylmorpholine-N-oxide (NMMO): hazards in practice and pitfalls in theory |
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