Metal(II) Ion Dependence of the Structures and Properties of Square-Grid Coordination Polymers of Tetrabromobenzenedicarboxylate and Pyrazine as Bridging Ligands

In this study, we report the synthesis and crystal structures of coordination polymers employing tetrabromobenzenedicarboxylate (Br4bdc2−) and pyrazine (pyz). Uncoordinated pyz molecules are stabilized between the layers by both hydrogen H-bonding and π–π stacking interactions in [M(Br4bdc)(pyz)(H2O...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2021-05, Vol.94 (5), p.1571-1578
Hauptverfasser:	Kumagai, Hitoshi, Setoyama, Norihiko, Kawata, Satoshi, Sakamoto, Yoshiyuki
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical synthesis Cobalt Coordination polymers Crystal structure Crystallinity Dehydration Heating Jahn-Teller effect Proton conduction Relative humidity Stacking Water chemistry Zinc
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