Crystal Structures and Spin Crossover of Iron(III) Cocrystal Formed via Halogen Bonding
Spin crossover iron(III) compounds containing the tridentate Schiff base ligand and its cocrystal, [Fe(acpa)2]I (1) and [Fe(acpa)2][1,3,5-TITFB(I−)] (2) (Hacpa = N-(1-acetyl-2-propylidene)(2-pyridylmethyl) amine, 1,3,5-TITFB = 1,3,5-triiodotrifluorobenzene), were synthesized and their crystal struct...
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| Veröffentlicht in: | Chemistry letters 2021-06, Vol.50 (6), p.1259-1262 |
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| container_title | Chemistry letters |
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| creator | Zenno, Hikaru Akiyoshi, Ryohei Nakamura, Masaaki Sekine, Yoshihiro Hayami, Shinya |
| description | Spin crossover iron(III) compounds containing the tridentate Schiff base ligand and its cocrystal, [Fe(acpa)2]I (1) and [Fe(acpa)2][1,3,5-TITFB(I−)] (2) (Hacpa = N-(1-acetyl-2-propylidene)(2-pyridylmethyl) amine, 1,3,5-TITFB = 1,3,5-triiodotrifluorobenzene), were synthesized and their crystal structures and magnetic properties characterized in detail. 1 exhibits abrupt spin crossover (SCO) behavior (T1/2 = 182 K) with thermal hysteresis loop being 23 K while showing gradual SCO behavior for 2 without thermal hysteresis loop. |
| doi_str_mv | 10.1246/cl.210101 |
| format | Article |
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| language | eng |
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| source | Oxford University Press Journals All Titles (1996-Current) |
| subjects | Crossovers Crystal structure Crystals Hysteresis loops Imines Iron Magnetic properties |
| title | Crystal Structures and Spin Crossover of Iron(III) Cocrystal Formed via Halogen Bonding |
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