Effect of Anionic Amphiphiles on the Morphology of Hexagonal Plate-like ZnO Particles
Zinc oxide (ZnO) particles were synthesized in the presence of anionic surfactants (ASs). The effect of ASs on the morphology of the ZnO particles was investigated by using ASs with various alkyl chain lengths and changing the molar ratio of AS/ZnSO4. Hexagonal plate-like ZnO particles were formed i...
Gespeichert in:
| Veröffentlicht in: | Journal of Oleo Science 2021, Vol.70(7), pp.919-925 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 925 |
|---|---|
| container_issue | 7 |
| container_start_page | 919 |
| container_title | Journal of Oleo Science |
| container_volume | 70 |
| creator | Shibata, Hirobumi Iizuka, Yoshinobu Amano, Masato Takayanagi, Erika Ogura, Taku Hashimoto, Kazuaki |
| description | Zinc oxide (ZnO) particles were synthesized in the presence of anionic surfactants (ASs). The effect of ASs on the morphology of the ZnO particles was investigated by using ASs with various alkyl chain lengths and changing the molar ratio of AS/ZnSO4. Hexagonal plate-like ZnO particles were formed in the presence of ASs. Adsorption of the AS on the c face of the ZnO crystals inhibited (promoted) crystal growth along the c-axis (ab-axis) direction. Increasing the molar ratio of AS/ZnSO4 decreased the particle thickness, owing to the resulting increase in the coverage of the c face with AS. The particle diameter of the hexagonal plate-like ZnO particles (the diagonal length of the hexagonal plate) increased with increasing alkyl chain length of AS as a result of the van der Waals interactions between the alkyl chains. The data indicate that the particle diameter and thickness can be controlled by fine-tuning the van der Waals interactions between the alkyl chains and the coverage of the c face of the ZnO particles with AS. |
| doi_str_mv | 10.5650/jos.ess21062 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2547624092</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2547624092</sourcerecordid><originalsourceid>FETCH-LOGICAL-c607t-dec982f70cfc7b6d5c3ab52b410526378ab50d5c1c3ff154f16fa6f3ca82be303</originalsourceid><addsrcrecordid>eNpFUE1PwzAMrRBIjI8bPyASVwpO0jTtcUxjIA2NA1y4RFnmbC1ZM5Iiwb8nYwwky3ac956tl2UXFK5FKeCm9fEaY2QUSnaQDSgvZM65YIc_vcirWsjj7CTGFiDNhRxkL2Nr0fTEWzLsGt81hgzXm1WTwmEkviP9CsmjD5uVd375tQXe46de-k478uR0j7lr3pC8djPypEPfmMQ7y46sdhHPf-tp9nI3fh7d59PZ5GE0nOamBNnnCzR1xawEY42clwthuJ4LNi8oCFZyWaUXpCk13FoqCktLq0vLja7YHDnw0-xyp7sJ_v0DY69a_xHSZVExUciSFVCzhLraoUzwMQa0ahOatQ5fioLaGpdYUe2NS_DJDr7GRWO0851rOvxXXrTSO0wMBowqAJkiFaGgpnVKTPAq3cZlUrrdKbWx10v8W_tr089aCUpu037936dZ6aCw49_uwJCk</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2547624092</pqid></control><display><type>article</type><title>Effect of Anionic Amphiphiles on the Morphology of Hexagonal Plate-like ZnO Particles</title><source>J-STAGE日本語サイト (Free Access)</source><source>EZB-FREE-00999 freely available EZB journals</source><source>Directory of Open Access Journals</source><source>Free Full-Text Journals in Chemistry</source><creator>Shibata, Hirobumi ; Iizuka, Yoshinobu ; Amano, Masato ; Takayanagi, Erika ; Ogura, Taku ; Hashimoto, Kazuaki</creator><creatorcontrib>Shibata, Hirobumi ; Iizuka, Yoshinobu ; Amano, Masato ; Takayanagi, Erika ; Ogura, Taku ; Hashimoto, Kazuaki ; Department of Applied Chemistry ; Tokyo University of Science ; NIKKOL GROUP Cosmos Technical Center ; Chiba Institute of Technology ; Research Institute for Science and Technology</creatorcontrib><description>Zinc oxide (ZnO) particles were synthesized in the presence of anionic surfactants (ASs). The effect of ASs on the morphology of the ZnO particles was investigated by using ASs with various alkyl chain lengths and changing the molar ratio of AS/ZnSO4. Hexagonal plate-like ZnO particles were formed in the presence of ASs. Adsorption of the AS on the c face of the ZnO crystals inhibited (promoted) crystal growth along the c-axis (ab-axis) direction. Increasing the molar ratio of AS/ZnSO4 decreased the particle thickness, owing to the resulting increase in the coverage of the c face with AS. The particle diameter of the hexagonal plate-like ZnO particles (the diagonal length of the hexagonal plate) increased with increasing alkyl chain length of AS as a result of the van der Waals interactions between the alkyl chains. The data indicate that the particle diameter and thickness can be controlled by fine-tuning the van der Waals interactions between the alkyl chains and the coverage of the c face of the ZnO particles with AS.</description><identifier>ISSN: 1345-8957</identifier><identifier>EISSN: 1347-3352</identifier><identifier>DOI: 10.5650/jos.ess21062</identifier><language>eng</language><publisher>Tokyo: Japan Oil Chemists' Society</publisher><subject>anionic amphiphiles ; Chains ; Crystal growth ; crystal-growth-directing agent ; Diameters ; Morphology ; Particle size ; Thickness ; van der Waals interaction ; Zinc oxide ; Zinc oxides ; Zinc plating</subject><ispartof>Journal of Oleo Science, 2021, Vol.70(7), pp.919-925</ispartof><rights>2021 by Japan Oil Chemists' Society</rights><rights>2021. This work is published under https://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c607t-dec982f70cfc7b6d5c3ab52b410526378ab50d5c1c3ff154f16fa6f3ca82be303</citedby><cites>FETCH-LOGICAL-c607t-dec982f70cfc7b6d5c3ab52b410526378ab50d5c1c3ff154f16fa6f3ca82be303</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,864,1883,27924,27925</link.rule.ids></links><search><creatorcontrib>Shibata, Hirobumi</creatorcontrib><creatorcontrib>Iizuka, Yoshinobu</creatorcontrib><creatorcontrib>Amano, Masato</creatorcontrib><creatorcontrib>Takayanagi, Erika</creatorcontrib><creatorcontrib>Ogura, Taku</creatorcontrib><creatorcontrib>Hashimoto, Kazuaki</creatorcontrib><creatorcontrib>Department of Applied Chemistry</creatorcontrib><creatorcontrib>Tokyo University of Science</creatorcontrib><creatorcontrib>NIKKOL GROUP Cosmos Technical Center</creatorcontrib><creatorcontrib>Chiba Institute of Technology</creatorcontrib><creatorcontrib>Research Institute for Science and Technology</creatorcontrib><title>Effect of Anionic Amphiphiles on the Morphology of Hexagonal Plate-like ZnO Particles</title><title>Journal of Oleo Science</title><description>Zinc oxide (ZnO) particles were synthesized in the presence of anionic surfactants (ASs). The effect of ASs on the morphology of the ZnO particles was investigated by using ASs with various alkyl chain lengths and changing the molar ratio of AS/ZnSO4. Hexagonal plate-like ZnO particles were formed in the presence of ASs. Adsorption of the AS on the c face of the ZnO crystals inhibited (promoted) crystal growth along the c-axis (ab-axis) direction. Increasing the molar ratio of AS/ZnSO4 decreased the particle thickness, owing to the resulting increase in the coverage of the c face with AS. The particle diameter of the hexagonal plate-like ZnO particles (the diagonal length of the hexagonal plate) increased with increasing alkyl chain length of AS as a result of the van der Waals interactions between the alkyl chains. The data indicate that the particle diameter and thickness can be controlled by fine-tuning the van der Waals interactions between the alkyl chains and the coverage of the c face of the ZnO particles with AS.</description><subject>anionic amphiphiles</subject><subject>Chains</subject><subject>Crystal growth</subject><subject>crystal-growth-directing agent</subject><subject>Diameters</subject><subject>Morphology</subject><subject>Particle size</subject><subject>Thickness</subject><subject>van der Waals interaction</subject><subject>Zinc oxide</subject><subject>Zinc oxides</subject><subject>Zinc plating</subject><issn>1345-8957</issn><issn>1347-3352</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpFUE1PwzAMrRBIjI8bPyASVwpO0jTtcUxjIA2NA1y4RFnmbC1ZM5Iiwb8nYwwky3ac956tl2UXFK5FKeCm9fEaY2QUSnaQDSgvZM65YIc_vcirWsjj7CTGFiDNhRxkL2Nr0fTEWzLsGt81hgzXm1WTwmEkviP9CsmjD5uVd375tQXe46de-k478uR0j7lr3pC8djPypEPfmMQ7y46sdhHPf-tp9nI3fh7d59PZ5GE0nOamBNnnCzR1xawEY42clwthuJ4LNi8oCFZyWaUXpCk13FoqCktLq0vLja7YHDnw0-xyp7sJ_v0DY69a_xHSZVExUciSFVCzhLraoUzwMQa0ahOatQ5fioLaGpdYUe2NS_DJDr7GRWO0851rOvxXXrTSO0wMBowqAJkiFaGgpnVKTPAq3cZlUrrdKbWx10v8W_tr089aCUpu037936dZ6aCw49_uwJCk</recordid><startdate>20210101</startdate><enddate>20210101</enddate><creator>Shibata, Hirobumi</creator><creator>Iizuka, Yoshinobu</creator><creator>Amano, Masato</creator><creator>Takayanagi, Erika</creator><creator>Ogura, Taku</creator><creator>Hashimoto, Kazuaki</creator><general>Japan Oil Chemists' Society</general><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>20210101</creationdate><title>Effect of Anionic Amphiphiles on the Morphology of Hexagonal Plate-like ZnO Particles</title><author>Shibata, Hirobumi ; Iizuka, Yoshinobu ; Amano, Masato ; Takayanagi, Erika ; Ogura, Taku ; Hashimoto, Kazuaki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c607t-dec982f70cfc7b6d5c3ab52b410526378ab50d5c1c3ff154f16fa6f3ca82be303</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>anionic amphiphiles</topic><topic>Chains</topic><topic>Crystal growth</topic><topic>crystal-growth-directing agent</topic><topic>Diameters</topic><topic>Morphology</topic><topic>Particle size</topic><topic>Thickness</topic><topic>van der Waals interaction</topic><topic>Zinc oxide</topic><topic>Zinc oxides</topic><topic>Zinc plating</topic><toplevel>online_resources</toplevel><creatorcontrib>Shibata, Hirobumi</creatorcontrib><creatorcontrib>Iizuka, Yoshinobu</creatorcontrib><creatorcontrib>Amano, Masato</creatorcontrib><creatorcontrib>Takayanagi, Erika</creatorcontrib><creatorcontrib>Ogura, Taku</creatorcontrib><creatorcontrib>Hashimoto, Kazuaki</creatorcontrib><creatorcontrib>Department of Applied Chemistry</creatorcontrib><creatorcontrib>Tokyo University of Science</creatorcontrib><creatorcontrib>NIKKOL GROUP Cosmos Technical Center</creatorcontrib><creatorcontrib>Chiba Institute of Technology</creatorcontrib><creatorcontrib>Research Institute for Science and Technology</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><jtitle>Journal of Oleo Science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shibata, Hirobumi</au><au>Iizuka, Yoshinobu</au><au>Amano, Masato</au><au>Takayanagi, Erika</au><au>Ogura, Taku</au><au>Hashimoto, Kazuaki</au><aucorp>Department of Applied Chemistry</aucorp><aucorp>Tokyo University of Science</aucorp><aucorp>NIKKOL GROUP Cosmos Technical Center</aucorp><aucorp>Chiba Institute of Technology</aucorp><aucorp>Research Institute for Science and Technology</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Anionic Amphiphiles on the Morphology of Hexagonal Plate-like ZnO Particles</atitle><jtitle>Journal of Oleo Science</jtitle><date>2021-01-01</date><risdate>2021</risdate><volume>70</volume><issue>7</issue><spage>919</spage><epage>925</epage><pages>919-925</pages><artnum>ess21062</artnum><issn>1345-8957</issn><eissn>1347-3352</eissn><abstract>Zinc oxide (ZnO) particles were synthesized in the presence of anionic surfactants (ASs). The effect of ASs on the morphology of the ZnO particles was investigated by using ASs with various alkyl chain lengths and changing the molar ratio of AS/ZnSO4. Hexagonal plate-like ZnO particles were formed in the presence of ASs. Adsorption of the AS on the c face of the ZnO crystals inhibited (promoted) crystal growth along the c-axis (ab-axis) direction. Increasing the molar ratio of AS/ZnSO4 decreased the particle thickness, owing to the resulting increase in the coverage of the c face with AS. The particle diameter of the hexagonal plate-like ZnO particles (the diagonal length of the hexagonal plate) increased with increasing alkyl chain length of AS as a result of the van der Waals interactions between the alkyl chains. The data indicate that the particle diameter and thickness can be controlled by fine-tuning the van der Waals interactions between the alkyl chains and the coverage of the c face of the ZnO particles with AS.</abstract><cop>Tokyo</cop><pub>Japan Oil Chemists' Society</pub><doi>10.5650/jos.ess21062</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1345-8957 |
| ispartof | Journal of Oleo Science, 2021, Vol.70(7), pp.919-925 |
| issn | 1345-8957 1347-3352 |
| language | eng |
| recordid | cdi_proquest_journals_2547624092 |
| source | J-STAGE日本語サイト (Free Access); EZB-FREE-00999 freely available EZB journals; Directory of Open Access Journals; Free Full-Text Journals in Chemistry |
| subjects | anionic amphiphiles Chains Crystal growth crystal-growth-directing agent Diameters Morphology Particle size Thickness van der Waals interaction Zinc oxide Zinc oxides Zinc plating |
| title | Effect of Anionic Amphiphiles on the Morphology of Hexagonal Plate-like ZnO Particles |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T08%3A04%3A58IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Effect%20of%20Anionic%20Amphiphiles%20on%20the%20Morphology%20of%20Hexagonal%20Plate-like%20ZnO%20Particles&rft.jtitle=Journal%20of%20Oleo%20Science&rft.au=Shibata,%20Hirobumi&rft.aucorp=Department%20of%20Applied%20Chemistry&rft.date=2021-01-01&rft.volume=70&rft.issue=7&rft.spage=919&rft.epage=925&rft.pages=919-925&rft.artnum=ess21062&rft.issn=1345-8957&rft.eissn=1347-3352&rft_id=info:doi/10.5650/jos.ess21062&rft_dat=%3Cproquest_cross%3E2547624092%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2547624092&rft_id=info:pmid/&rfr_iscdi=true |