Chloro- and BF2bdk-substituted dithienylethene: Synthesis, photophysical properties, and optical switching behavior
A novel chloro- and BF2bdk-substituted dithienylethene derivative, in which a chlorine atom and a difluoroboron β-diketonate (BF2bdk) group are appended at the termini of the dithienylethene core, is developed. The structure was confirmed by 1H NMR, 13C NMR, and high-resolution mass spectrometry (el...
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| Veröffentlicht in: | Journal of chemical research 2021-05, Vol.45 (5-6), p.411-416 |
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| container_issue | 5-6 |
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| container_title | Journal of chemical research |
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| creator | Lu, Zhiqiang Yang, Wenbo Bai, Yanhui Wang, Mo Li, Zixu Yang, Yang Feng, Xueling Zhu, Yuanxiao Yang, Xujia Li, Ziyong |
| description | A novel chloro- and BF2bdk-substituted dithienylethene derivative, in which a chlorine atom and a difluoroboron β-diketonate (BF2bdk) group are appended at the termini of the dithienylethene core, is developed. The structure was confirmed by 1H NMR, 13C NMR, and high-resolution mass spectrometry (electrospray ionization). It displayed solvent-dependent photophysical properties, and blue/red light-triggered optical switching behavior in nonpolar or less polar solvents. |
| doi_str_mv | 10.1177/1747519820951410 |
| format | Article |
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The structure was confirmed by 1H NMR, 13C NMR, and high-resolution mass spectrometry (electrospray ionization). 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It displayed solvent-dependent photophysical properties, and blue/red light-triggered optical switching behavior in nonpolar or less polar solvents.</description><subject>Chlorine</subject><subject>Ions</subject><subject>Mass spectrometry</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Optical properties</subject><subject>Optical switching</subject><subject>Solvents</subject><subject>Substitutes</subject><issn>1747-5198</issn><issn>2047-6507</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>AFRWT</sourceid><recordid>eNpdUMFKxDAUDKLgunr3GPBqNEmbpPGmi6vCggf1XJL2dZu1NLVJlf69rSsInt5jZpg3bxA6Z_SKMaWumUqVYDrjVAuWMnqAFpymikhB1SFazDSZ-WN0EsKO0lRIzRYorOrG955g05b4bs1t-U7CYEN0cYhQ4tLF2kE7NhBraOEGv4zttAUXLnFX--i7egyuMA3uet9BHx1MzGzmu_iDhy8Xi9q1W2yhNp_O96foqDJNgLPfuURv6_vX1SPZPD88rW43pOMyiUQWAEaXmVDc2lJXtrAJTcBOmDRFkomyoIIro2UFCa2Y0FqnkmZSV4Vg3CZLdLH3naJ9DBBivvND304ncy7S6X2tKZtUZK8KZgt_Ckbzudf8f6_JN4DdbIs</recordid><startdate>202105</startdate><enddate>202105</enddate><creator>Lu, Zhiqiang</creator><creator>Yang, Wenbo</creator><creator>Bai, Yanhui</creator><creator>Wang, Mo</creator><creator>Li, Zixu</creator><creator>Yang, Yang</creator><creator>Feng, Xueling</creator><creator>Zhu, Yuanxiao</creator><creator>Yang, Xujia</creator><creator>Li, Ziyong</creator><general>SAGE Publications</general><general>Sage Publications Ltd</general><scope>AFRWT</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-2658-2286</orcidid></search><sort><creationdate>202105</creationdate><title>Chloro- and BF2bdk-substituted dithienylethene: Synthesis, photophysical properties, and optical switching behavior</title><author>Lu, Zhiqiang ; Yang, Wenbo ; Bai, Yanhui ; Wang, Mo ; Li, Zixu ; Yang, Yang ; Feng, Xueling ; Zhu, Yuanxiao ; Yang, Xujia ; Li, Ziyong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p263t-6ceea9d8572bbd9fbcb303eba9d6ac385dc0527a96fe30f15999460869fc512b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chlorine</topic><topic>Ions</topic><topic>Mass spectrometry</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Optical properties</topic><topic>Optical switching</topic><topic>Solvents</topic><topic>Substitutes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lu, Zhiqiang</creatorcontrib><creatorcontrib>Yang, Wenbo</creatorcontrib><creatorcontrib>Bai, Yanhui</creatorcontrib><creatorcontrib>Wang, Mo</creatorcontrib><creatorcontrib>Li, Zixu</creatorcontrib><creatorcontrib>Yang, Yang</creatorcontrib><creatorcontrib>Feng, Xueling</creatorcontrib><creatorcontrib>Zhu, Yuanxiao</creatorcontrib><creatorcontrib>Yang, Xujia</creatorcontrib><creatorcontrib>Li, Ziyong</creatorcontrib><collection>Sage Journals GOLD Open Access 2024</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of chemical research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lu, Zhiqiang</au><au>Yang, Wenbo</au><au>Bai, Yanhui</au><au>Wang, Mo</au><au>Li, Zixu</au><au>Yang, Yang</au><au>Feng, Xueling</au><au>Zhu, Yuanxiao</au><au>Yang, Xujia</au><au>Li, Ziyong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chloro- and BF2bdk-substituted dithienylethene: Synthesis, photophysical properties, and optical switching behavior</atitle><jtitle>Journal of chemical research</jtitle><date>2021-05</date><risdate>2021</risdate><volume>45</volume><issue>5-6</issue><spage>411</spage><epage>416</epage><pages>411-416</pages><issn>1747-5198</issn><eissn>2047-6507</eissn><abstract>A novel chloro- and BF2bdk-substituted dithienylethene derivative, in which a chlorine atom and a difluoroboron β-diketonate (BF2bdk) group are appended at the termini of the dithienylethene core, is developed. 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| subjects | Chlorine Ions Mass spectrometry NMR Nuclear magnetic resonance Optical properties Optical switching Solvents Substitutes |
| title | Chloro- and BF2bdk-substituted dithienylethene: Synthesis, photophysical properties, and optical switching behavior |
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