Bi- and Tetranuclear Antimony(III) Bromide Complexes with Alkanediyl-bis(3-methylpyridinium) Cations
Polynuclear bromoantimonates(III) with alkanediyl-bis(3-methylpyridinium) cations (3-MePy )—(3-MePyC 2 ) 3 [Sb 2 Br 9 ] 2 ( 1 ), (3-MePyC 3 ) 2 [β-Sb 4 Br 16 ] ( 2 ), and (3-MePyC 4 ) 2 [α-Sb 4 Br 16 ] ( 3 )—and bromobismuthate(III) (3-MePyC 3 ) 3 [Bi 2 Br 9 ] 2 ( 4 ) have been synthesized by reacti...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2021-06, Vol.66 (6), p.827-833 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Polynuclear bromoantimonates(III) with alkanediyl-bis(3-methylpyridinium) cations (3-MePy
)—(3-MePyC
2
)
3
[Sb
2
Br
9
]
2
(
1
), (3-MePyC
3
)
2
[β-Sb
4
Br
16
] (
2
), and (3-MePyC
4
)
2
[α-Sb
4
Br
16
] (
3
)—and bromobismuthate(III) (3-MePyC
3
)
3
[Bi
2
Br
9
]
2
(
4
) have been synthesized by reacting solutions of Sb
2
O
3
(Bi
2
O
3
) in HBr with bromides of the corresponding organic cations. Differences in the structure between compounds
1
–
3
and bromobismuthates with analogous cations (
4
and previously studied compounds) have been considered. |
|---|---|
| ISSN: | 0036-0236 1531-8613 |
| DOI: | 10.1134/S003602362106019X |