Multi-Response/Multi-Step Optimization of Heterogeneous Fenton Process with Fe3O4 Catalyst for the Treatment of Landfill Leachate
Since conventional biological treatment methods are not sufficient alone to treat landfill leachate, this study investigated the efficacy of the heterogeneous Fenton process as a preliminary treatment technique. With this aim, a two-level factorial design combined with the response surface methodolo...
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| description | Since conventional biological treatment methods are not sufficient alone to treat landfill leachate, this study investigated the efficacy of the heterogeneous Fenton process as a preliminary treatment technique. With this aim, a two-level factorial design combined with the response surface methodology (RSM) was used to optimize the operating parameters for the heterogeneous Fenton process used for treatment of leachate. The surface morphology and elemental analysis of Fe
3
O
4
nanoparticles used in the heterogeneous Fenton process were completed with scanning electron microscope (SEM), energy dispersive X-ray (EDX) and Fourier transform infrared spectroscopy (FT-IR). In order to obtain maximum 75% chemical oxygen demand (COD) removal for treatment of leachate with the heterogeneous Fenton process, the optimum conditions for H
2
O
2
and Fe
3
O
4
dosages, stirring rate and initial pH parameters were 800 mg/L, 334.54 mg/L, 255 rpm and 3.34, respectively. The results obtained show the heterogeneous Fenton process abides by the second-order model (
R
2
= 0.9896), and the variables mentioned above were confirmed to significantly affect the COD removal efficiency. Response surface graphs show the use of higher pH and chemical agents do not increase the COD removal efficiency. This study proves the applicability of the multi-response optimization program for treatment of leachate from a landfill site representing a serious problem in environmental terms. |
| doi_str_mv | 10.1007/s11270-021-05225-w |
| format | Article |
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3
O
4
nanoparticles used in the heterogeneous Fenton process were completed with scanning electron microscope (SEM), energy dispersive X-ray (EDX) and Fourier transform infrared spectroscopy (FT-IR). In order to obtain maximum 75% chemical oxygen demand (COD) removal for treatment of leachate with the heterogeneous Fenton process, the optimum conditions for H
2
O
2
and Fe
3
O
4
dosages, stirring rate and initial pH parameters were 800 mg/L, 334.54 mg/L, 255 rpm and 3.34, respectively. The results obtained show the heterogeneous Fenton process abides by the second-order model (
R
2
= 0.9896), and the variables mentioned above were confirmed to significantly affect the COD removal efficiency. Response surface graphs show the use of higher pH and chemical agents do not increase the COD removal efficiency. This study proves the applicability of the multi-response optimization program for treatment of leachate from a landfill site representing a serious problem in environmental terms.</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1007/s11270-021-05225-w</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Analytical methods ; Atmospheric Protection/Air Quality Control/Air Pollution ; Biological treatment ; Catalysts ; Chemical agents ; Chemical analysis ; Chemical oxygen demand ; Climate Change/Climate Change Impacts ; Earth and Environmental Science ; Electron microscopes ; Environment ; Environmental monitoring ; Factorial design ; Fourier analysis ; Fourier transforms ; Graphs ; Hydrogen peroxide ; Hydrogeology ; Infrared spectroscopy ; Iron oxides ; Landfill ; Landfills ; Leachates ; Morphology ; Nanoparticles ; Optimization ; Parameters ; pH effects ; Removal ; Response surface methodology ; Scanning electron microscopy ; Soil Science & Conservation ; Waste disposal sites ; Waste treatment ; Wastewater treatment ; Water pollution treatment ; Water Quality/Water Pollution</subject><ispartof>Water, air, and soil pollution, 2021-07, Vol.232 (7), Article 275</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-90f848cb43df1e8bf1eedff0cb41e8e0b2fec6921bc2e190670bba6b04c801ee3</citedby><cites>FETCH-LOGICAL-c319t-90f848cb43df1e8bf1eedff0cb41e8e0b2fec6921bc2e190670bba6b04c801ee3</cites><orcidid>0000-0003-1071-2813</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11270-021-05225-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11270-021-05225-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27915,27916,41479,42548,51310</link.rule.ids></links><search><creatorcontrib>Taşcı, Salih</creatorcontrib><creatorcontrib>Özgüven, Ayşe</creatorcontrib><creatorcontrib>Yıldız, Burçin</creatorcontrib><title>Multi-Response/Multi-Step Optimization of Heterogeneous Fenton Process with Fe3O4 Catalyst for the Treatment of Landfill Leachate</title><title>Water, air, and soil pollution</title><addtitle>Water Air Soil Pollut</addtitle><description>Since conventional biological treatment methods are not sufficient alone to treat landfill leachate, this study investigated the efficacy of the heterogeneous Fenton process as a preliminary treatment technique. With this aim, a two-level factorial design combined with the response surface methodology (RSM) was used to optimize the operating parameters for the heterogeneous Fenton process used for treatment of leachate. The surface morphology and elemental analysis of Fe
3
O
4
nanoparticles used in the heterogeneous Fenton process were completed with scanning electron microscope (SEM), energy dispersive X-ray (EDX) and Fourier transform infrared spectroscopy (FT-IR). In order to obtain maximum 75% chemical oxygen demand (COD) removal for treatment of leachate with the heterogeneous Fenton process, the optimum conditions for H
2
O
2
and Fe
3
O
4
dosages, stirring rate and initial pH parameters were 800 mg/L, 334.54 mg/L, 255 rpm and 3.34, respectively. The results obtained show the heterogeneous Fenton process abides by the second-order model (
R
2
= 0.9896), and the variables mentioned above were confirmed to significantly affect the COD removal efficiency. Response surface graphs show the use of higher pH and chemical agents do not increase the COD removal efficiency. This study proves the applicability of the multi-response optimization program for treatment of leachate from a landfill site representing a serious problem in environmental terms.</description><subject>Analytical methods</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Biological treatment</subject><subject>Catalysts</subject><subject>Chemical agents</subject><subject>Chemical analysis</subject><subject>Chemical oxygen demand</subject><subject>Climate Change/Climate Change Impacts</subject><subject>Earth and Environmental Science</subject><subject>Electron microscopes</subject><subject>Environment</subject><subject>Environmental monitoring</subject><subject>Factorial design</subject><subject>Fourier analysis</subject><subject>Fourier transforms</subject><subject>Graphs</subject><subject>Hydrogen peroxide</subject><subject>Hydrogeology</subject><subject>Infrared spectroscopy</subject><subject>Iron oxides</subject><subject>Landfill</subject><subject>Landfills</subject><subject>Leachates</subject><subject>Morphology</subject><subject>Nanoparticles</subject><subject>Optimization</subject><subject>Parameters</subject><subject>pH effects</subject><subject>Removal</subject><subject>Response surface methodology</subject><subject>Scanning electron microscopy</subject><subject>Soil Science & Conservation</subject><subject>Waste disposal sites</subject><subject>Waste treatment</subject><subject>Wastewater treatment</subject><subject>Water pollution treatment</subject><subject>Water Quality/Water 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Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Taşcı, Salih</au><au>Özgüven, Ayşe</au><au>Yıldız, Burçin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Multi-Response/Multi-Step Optimization of Heterogeneous Fenton Process with Fe3O4 Catalyst for the Treatment of Landfill Leachate</atitle><jtitle>Water, air, and soil pollution</jtitle><stitle>Water Air Soil Pollut</stitle><date>2021-07-01</date><risdate>2021</risdate><volume>232</volume><issue>7</issue><artnum>275</artnum><issn>0049-6979</issn><eissn>1573-2932</eissn><abstract>Since conventional biological treatment methods are not sufficient alone to treat landfill leachate, this study investigated the efficacy of the heterogeneous Fenton process as a preliminary treatment technique. With this aim, a two-level factorial design combined with the response surface methodology (RSM) was used to optimize the operating parameters for the heterogeneous Fenton process used for treatment of leachate. The surface morphology and elemental analysis of Fe
3
O
4
nanoparticles used in the heterogeneous Fenton process were completed with scanning electron microscope (SEM), energy dispersive X-ray (EDX) and Fourier transform infrared spectroscopy (FT-IR). In order to obtain maximum 75% chemical oxygen demand (COD) removal for treatment of leachate with the heterogeneous Fenton process, the optimum conditions for H
2
O
2
and Fe
3
O
4
dosages, stirring rate and initial pH parameters were 800 mg/L, 334.54 mg/L, 255 rpm and 3.34, respectively. The results obtained show the heterogeneous Fenton process abides by the second-order model (
R
2
= 0.9896), and the variables mentioned above were confirmed to significantly affect the COD removal efficiency. Response surface graphs show the use of higher pH and chemical agents do not increase the COD removal efficiency. This study proves the applicability of the multi-response optimization program for treatment of leachate from a landfill site representing a serious problem in environmental terms.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11270-021-05225-w</doi><orcidid>https://orcid.org/0000-0003-1071-2813</orcidid></addata></record> |
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| ispartof | Water, air, and soil pollution, 2021-07, Vol.232 (7), Article 275 |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Analytical methods Atmospheric Protection/Air Quality Control/Air Pollution Biological treatment Catalysts Chemical agents Chemical analysis Chemical oxygen demand Climate Change/Climate Change Impacts Earth and Environmental Science Electron microscopes Environment Environmental monitoring Factorial design Fourier analysis Fourier transforms Graphs Hydrogen peroxide Hydrogeology Infrared spectroscopy Iron oxides Landfill Landfills Leachates Morphology Nanoparticles Optimization Parameters pH effects Removal Response surface methodology Scanning electron microscopy Soil Science & Conservation Waste disposal sites Waste treatment Wastewater treatment Water pollution treatment Water Quality/Water Pollution |
| title | Multi-Response/Multi-Step Optimization of Heterogeneous Fenton Process with Fe3O4 Catalyst for the Treatment of Landfill Leachate |
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