Polycyclic Aromatic Hydrocarbons in Soils of Anthracite Deposit Dumps in Siberia
The contents of 19 priority polycyclic aromatic hydrocarbons (PAHs) have been studied in soils (Spolic Technosols) and parent rocks of dumps at the Gorlovskoe anthracite deposit (Novosibirsk region). The bulk content of polyarenes in the analyzed soils is highly variable: from 100 to 74 622 ng/g. Th...
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| Veröffentlicht in: | Eurasian soil science 2021-06, Vol.54 (6), p.875-887 |
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| creator | Sokolov, D. A. Morozov, S. V. Abakumov, E. V. Androkhanov, V. A. |
| description | The contents of 19 priority polycyclic aromatic hydrocarbons (PAHs) have been studied in soils (Spolic Technosols) and parent rocks of dumps at the Gorlovskoe anthracite deposit (Novosibirsk region). The bulk content of polyarenes in the analyzed soils is highly variable: from 100 to 74 622 ng/g. The absence of statistically significant relationships between PAH concentrations and the contents of carbon and physical clay ( |
| doi_str_mv | 10.1134/S1064229321060120 |
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A. ; Morozov, S. V. ; Abakumov, E. V. ; Androkhanov, V. A.</creator><creatorcontrib>Sokolov, D. A. ; Morozov, S. V. ; Abakumov, E. V. ; Androkhanov, V. A.</creatorcontrib><description>The contents of 19 priority polycyclic aromatic hydrocarbons (PAHs) have been studied in soils (Spolic Technosols) and parent rocks of dumps at the Gorlovskoe anthracite deposit (Novosibirsk region). The bulk content of polyarenes in the analyzed soils is highly variable: from 100 to 74 622 ng/g. The absence of statistically significant relationships between PAH concentrations and the contents of carbon and physical clay (<0.01 mm) in the studied soils points to the specific processes of PAH formation upon coal transformation in soil-forming dump deposits. These processes produce bitumen lakes on the surface of dumps, in which the concentration of polyarenes may reach 864.4 mg/g. Cluster analysis with the use of the Jaccard similarity index and single-linkage clustering permitted us to group the studied objects according to the organic matter characteristics; the groups with chemogenic transformation of coal particles were distinguished by the Ward’s method. The principal component analysis proved that phenanthrene and 5–6-nucleus compounds have the closest correlation with the first component, whereas the second component correlates reliably with fluoranthene, naphthalene, anthracene, and pyrene. According to our results, the Phe/(Phe + Chr) ratio appears to be the most promising index for evaluating chemical transformation of coal in soils of anthracite deposits.</description><identifier>ISSN: 1064-2293</identifier><identifier>EISSN: 1556-195X</identifier><identifier>DOI: 10.1134/S1064229321060120</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Analysis ; Anthracene ; Anthracite ; Aromatic compounds ; Aromatic hydrocarbons ; Bituminous materials ; Cluster analysis ; Clustering ; Coal ; Earth and Environmental Science ; Earth Sciences ; Fluoranthene ; Geotechnical Engineering & Applied Earth Sciences ; Lakes ; Naphthalene ; Organic matter ; Phenanthrene ; Polycyclic aromatic hydrocarbons ; Principal components analysis ; Pyrene ; Soil ; Soil analysis ; Soil Chemistry ; Soil formation ; Soils ; Statistical analysis ; Transformations</subject><ispartof>Eurasian soil science, 2021-06, Vol.54 (6), p.875-887</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 1064-2293, Eurasian Soil Science, 2021, Vol. 54, No. 6, pp. 875–887. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Pochvovedenie, 2021, No. 6, pp. 701–714.</rights><rights>COPYRIGHT 2021 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a378t-c1add71bff3d210260f614535ee2b7a4d0351c79bdb6ea78691d307721b5aaee3</citedby><cites>FETCH-LOGICAL-a378t-c1add71bff3d210260f614535ee2b7a4d0351c79bdb6ea78691d307721b5aaee3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1064229321060120$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1064229321060120$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Sokolov, D. A.</creatorcontrib><creatorcontrib>Morozov, S. V.</creatorcontrib><creatorcontrib>Abakumov, E. V.</creatorcontrib><creatorcontrib>Androkhanov, V. A.</creatorcontrib><title>Polycyclic Aromatic Hydrocarbons in Soils of Anthracite Deposit Dumps in Siberia</title><title>Eurasian soil science</title><addtitle>Eurasian Soil Sc</addtitle><description>The contents of 19 priority polycyclic aromatic hydrocarbons (PAHs) have been studied in soils (Spolic Technosols) and parent rocks of dumps at the Gorlovskoe anthracite deposit (Novosibirsk region). The bulk content of polyarenes in the analyzed soils is highly variable: from 100 to 74 622 ng/g. The absence of statistically significant relationships between PAH concentrations and the contents of carbon and physical clay (<0.01 mm) in the studied soils points to the specific processes of PAH formation upon coal transformation in soil-forming dump deposits. These processes produce bitumen lakes on the surface of dumps, in which the concentration of polyarenes may reach 864.4 mg/g. Cluster analysis with the use of the Jaccard similarity index and single-linkage clustering permitted us to group the studied objects according to the organic matter characteristics; the groups with chemogenic transformation of coal particles were distinguished by the Ward’s method. The principal component analysis proved that phenanthrene and 5–6-nucleus compounds have the closest correlation with the first component, whereas the second component correlates reliably with fluoranthene, naphthalene, anthracene, and pyrene. According to our results, the Phe/(Phe + Chr) ratio appears to be the most promising index for evaluating chemical transformation of coal in soils of anthracite deposits.</description><subject>Analysis</subject><subject>Anthracene</subject><subject>Anthracite</subject><subject>Aromatic compounds</subject><subject>Aromatic hydrocarbons</subject><subject>Bituminous materials</subject><subject>Cluster analysis</subject><subject>Clustering</subject><subject>Coal</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>Fluoranthene</subject><subject>Geotechnical Engineering & Applied Earth Sciences</subject><subject>Lakes</subject><subject>Naphthalene</subject><subject>Organic matter</subject><subject>Phenanthrene</subject><subject>Polycyclic aromatic hydrocarbons</subject><subject>Principal components analysis</subject><subject>Pyrene</subject><subject>Soil</subject><subject>Soil analysis</subject><subject>Soil Chemistry</subject><subject>Soil formation</subject><subject>Soils</subject><subject>Statistical analysis</subject><subject>Transformations</subject><issn>1064-2293</issn><issn>1556-195X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kF1LwzAUhoMoOKc_wLuC1535bNLLsqkTBAdT8K6k-ZgZbTOT7qL_3owKXojkIi_nvM85LweAWwQXCBF6v0WwoBiXBCcBEYZnYIYYK3JUso_zpFM7P_UvwVWMewiJEFTMwGbj21GNqnUqq4Lv5JDEetTBKxka38fM9dnWuzZm3mZVP3wGqdxgspU5-OiGbHXsDpPJNSY4eQ0urGyjufn55-D98eFtuc5fXp-el9VLLgkXQ66Q1JqjxlqiU2RcQFsgyggzBjdcUg0JQ4qXjW4KI7koSqQJ5ByjhklpDJmDu2nuIfivo4lDvffH0KeVNWaUipIJSJJrMbl2sjW1660fUv70tOmc8r2xLtUrjgTFIm1JAJoAFXyMwdj6EFwnw1gjWJ8uXf-5dGLwxMTk7Xcm_Eb5H_oGXyV-4Q</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Sokolov, D. A.</creator><creator>Morozov, S. V.</creator><creator>Abakumov, E. V.</creator><creator>Androkhanov, V. A.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QL</scope><scope>7ST</scope><scope>7T7</scope><scope>7U9</scope><scope>7UA</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>FR3</scope><scope>H94</scope><scope>H96</scope><scope>L.G</scope><scope>M7N</scope><scope>P64</scope><scope>SOI</scope></search><sort><creationdate>20210601</creationdate><title>Polycyclic Aromatic Hydrocarbons in Soils of Anthracite Deposit Dumps in Siberia</title><author>Sokolov, D. A. ; Morozov, S. V. ; Abakumov, E. V. ; Androkhanov, V. 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A.</creatorcontrib><creatorcontrib>Morozov, S. V.</creatorcontrib><creatorcontrib>Abakumov, E. V.</creatorcontrib><creatorcontrib>Androkhanov, V. A.</creatorcontrib><collection>CrossRef</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Virology and AIDS Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Engineering Research Database</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Eurasian soil science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sokolov, D. A.</au><au>Morozov, S. V.</au><au>Abakumov, E. V.</au><au>Androkhanov, V. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polycyclic Aromatic Hydrocarbons in Soils of Anthracite Deposit Dumps in Siberia</atitle><jtitle>Eurasian soil science</jtitle><stitle>Eurasian Soil Sc</stitle><date>2021-06-01</date><risdate>2021</risdate><volume>54</volume><issue>6</issue><spage>875</spage><epage>887</epage><pages>875-887</pages><issn>1064-2293</issn><eissn>1556-195X</eissn><abstract>The contents of 19 priority polycyclic aromatic hydrocarbons (PAHs) have been studied in soils (Spolic Technosols) and parent rocks of dumps at the Gorlovskoe anthracite deposit (Novosibirsk region). The bulk content of polyarenes in the analyzed soils is highly variable: from 100 to 74 622 ng/g. The absence of statistically significant relationships between PAH concentrations and the contents of carbon and physical clay (<0.01 mm) in the studied soils points to the specific processes of PAH formation upon coal transformation in soil-forming dump deposits. These processes produce bitumen lakes on the surface of dumps, in which the concentration of polyarenes may reach 864.4 mg/g. Cluster analysis with the use of the Jaccard similarity index and single-linkage clustering permitted us to group the studied objects according to the organic matter characteristics; the groups with chemogenic transformation of coal particles were distinguished by the Ward’s method. The principal component analysis proved that phenanthrene and 5–6-nucleus compounds have the closest correlation with the first component, whereas the second component correlates reliably with fluoranthene, naphthalene, anthracene, and pyrene. According to our results, the Phe/(Phe + Chr) ratio appears to be the most promising index for evaluating chemical transformation of coal in soils of anthracite deposits.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1064229321060120</doi><tpages>13</tpages></addata></record> |
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| subjects | Analysis Anthracene Anthracite Aromatic compounds Aromatic hydrocarbons Bituminous materials Cluster analysis Clustering Coal Earth and Environmental Science Earth Sciences Fluoranthene Geotechnical Engineering & Applied Earth Sciences Lakes Naphthalene Organic matter Phenanthrene Polycyclic aromatic hydrocarbons Principal components analysis Pyrene Soil Soil analysis Soil Chemistry Soil formation Soils Statistical analysis Transformations |
| title | Polycyclic Aromatic Hydrocarbons in Soils of Anthracite Deposit Dumps in Siberia |
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