Feasible Fabrication of Hollow Micro-vesicles by Non-amphiphilic Macromolecules Based on Interfacial Cononsolvency
Herein we present a new perspective showing that water-soluble liquids, when added to water, undergo transient emulsification before complete dissolution. Thus, non-amphiphilic macromolecules can self-assemble at the two-miscible-phase interface when cononsolvent effect appears. A representative cas...
Gespeichert in:
Veröffentlicht in: | Chinese journal of polymer science 2021-07, Vol.39 (7), p.856-864 |
---|---|
Hauptverfasser: | , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 864 |
---|---|
container_issue | 7 |
container_start_page | 856 |
container_title | Chinese journal of polymer science |
container_volume | 39 |
creator | Wang, Jing-Hong Chen, Rui Zhao, Zi-Qing Shen, Jie Yang, He Luo, Yan Chen, Gao-Jian Chen, Hong Brash, John L. |
description | Herein we present a new perspective showing that water-soluble liquids, when added to water, undergo transient emulsification before complete dissolution. Thus, non-amphiphilic macromolecules can self-assemble at the two-miscible-phase interface when cononsolvent effect appears. A representative case shown here is that when poly(
N
-isopropylacrylamide) (PNIPAm), prepared by aqueous radical polymerization, in methanol solution is added into water, the polymer chains rapidly self-assemble into hollow micro-vesicles based on the cononsolvency at water/methanol interface. This finding provides a subtle strategy to prepare hollow micro-vesicles by non-amphiphilic polymers without template participating. We proposed a new concept “interfacial cononsolvency” to describe the formation process. Due to the easy modification process, sugar-contained PNIPAm chains are synthesized by copolymerization. As an application example, it is shown that these sugar-contained PNIPAm chains can afford “sweet” micro-vesicles (containing glucose residues). And the “sweet” micro-vesicles can well mimick the protocells which are involved in the recognition of bacteria. |
doi_str_mv | 10.1007/s10118-021-2541-z |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2544228582</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2544228582</sourcerecordid><originalsourceid>FETCH-LOGICAL-c359t-7719a639093942e3a6e395689cb1698be8b4e0793aa063eb3a908b34c6dc1d6d3</originalsourceid><addsrcrecordid>eNp1kE1LAzEQhoMoWKs_wFvAczQfu9nNUYu1hVYvel6S7KympJuabJX215tSwZMwMJfneYd5Ebpm9JZRWt0lRhmrCeWM8LJgZH-CRqwQikhOxSkaUV5KUslKnaOLlFaUyqIqqxGKU9DJGQ94qk10Vg8u9Dh0eBa8D9946WwM5AuSsx4SNjv8HHqi15sPl8c7i5c6E-vgwW4PxINO0OKcMe8HiJ22Tns8CX3oU_Bf0NvdJTrrtE9w9bvH6G36-DqZkcXL03xyvyBWlGogVcWUlkJRJVTBQWgJQpWyVtYwqWoDtSmAVkpoTaUAI7SitRGFla1lrWzFGN0cczcxfG4hDc0qbGOfTza5ooLzuqx5ptiRyl-kFKFrNtGtddw1jDaHaptjtU2u9uCxZp8dfnRSZvt3iH_J_0s_vJd9bg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2544228582</pqid></control><display><type>article</type><title>Feasible Fabrication of Hollow Micro-vesicles by Non-amphiphilic Macromolecules Based on Interfacial Cononsolvency</title><source>SpringerNature Journals</source><source>Alma/SFX Local Collection</source><creator>Wang, Jing-Hong ; Chen, Rui ; Zhao, Zi-Qing ; Shen, Jie ; Yang, He ; Luo, Yan ; Chen, Gao-Jian ; Chen, Hong ; Brash, John L.</creator><creatorcontrib>Wang, Jing-Hong ; Chen, Rui ; Zhao, Zi-Qing ; Shen, Jie ; Yang, He ; Luo, Yan ; Chen, Gao-Jian ; Chen, Hong ; Brash, John L.</creatorcontrib><description>Herein we present a new perspective showing that water-soluble liquids, when added to water, undergo transient emulsification before complete dissolution. Thus, non-amphiphilic macromolecules can self-assemble at the two-miscible-phase interface when cononsolvent effect appears. A representative case shown here is that when poly(
N
-isopropylacrylamide) (PNIPAm), prepared by aqueous radical polymerization, in methanol solution is added into water, the polymer chains rapidly self-assemble into hollow micro-vesicles based on the cononsolvency at water/methanol interface. This finding provides a subtle strategy to prepare hollow micro-vesicles by non-amphiphilic polymers without template participating. We proposed a new concept “interfacial cononsolvency” to describe the formation process. Due to the easy modification process, sugar-contained PNIPAm chains are synthesized by copolymerization. As an application example, it is shown that these sugar-contained PNIPAm chains can afford “sweet” micro-vesicles (containing glucose residues). And the “sweet” micro-vesicles can well mimick the protocells which are involved in the recognition of bacteria.</description><identifier>ISSN: 0256-7679</identifier><identifier>EISSN: 1439-6203</identifier><identifier>DOI: 10.1007/s10118-021-2541-z</identifier><language>eng</language><publisher>Beijing: Chinese Chemical Society and Institute of Chemistry, CAS</publisher><subject>Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Copolymerization ; Industrial Chemistry/Chemical Engineering ; Macromolecules ; Methanol ; Polyisopropyl acrylamide ; Polymer Sciences ; Vesicles</subject><ispartof>Chinese journal of polymer science, 2021-07, Vol.39 (7), p.856-864</ispartof><rights>Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2021</rights><rights>Chinese Chemical Society Institute of Chemistry, Chinese Academy of Sciences 2021.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-7719a639093942e3a6e395689cb1698be8b4e0793aa063eb3a908b34c6dc1d6d3</citedby><cites>FETCH-LOGICAL-c359t-7719a639093942e3a6e395689cb1698be8b4e0793aa063eb3a908b34c6dc1d6d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10118-021-2541-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10118-021-2541-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Wang, Jing-Hong</creatorcontrib><creatorcontrib>Chen, Rui</creatorcontrib><creatorcontrib>Zhao, Zi-Qing</creatorcontrib><creatorcontrib>Shen, Jie</creatorcontrib><creatorcontrib>Yang, He</creatorcontrib><creatorcontrib>Luo, Yan</creatorcontrib><creatorcontrib>Chen, Gao-Jian</creatorcontrib><creatorcontrib>Chen, Hong</creatorcontrib><creatorcontrib>Brash, John L.</creatorcontrib><title>Feasible Fabrication of Hollow Micro-vesicles by Non-amphiphilic Macromolecules Based on Interfacial Cononsolvency</title><title>Chinese journal of polymer science</title><addtitle>Chin J Polym Sci</addtitle><description>Herein we present a new perspective showing that water-soluble liquids, when added to water, undergo transient emulsification before complete dissolution. Thus, non-amphiphilic macromolecules can self-assemble at the two-miscible-phase interface when cononsolvent effect appears. A representative case shown here is that when poly(
N
-isopropylacrylamide) (PNIPAm), prepared by aqueous radical polymerization, in methanol solution is added into water, the polymer chains rapidly self-assemble into hollow micro-vesicles based on the cononsolvency at water/methanol interface. This finding provides a subtle strategy to prepare hollow micro-vesicles by non-amphiphilic polymers without template participating. We proposed a new concept “interfacial cononsolvency” to describe the formation process. Due to the easy modification process, sugar-contained PNIPAm chains are synthesized by copolymerization. As an application example, it is shown that these sugar-contained PNIPAm chains can afford “sweet” micro-vesicles (containing glucose residues). And the “sweet” micro-vesicles can well mimick the protocells which are involved in the recognition of bacteria.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Copolymerization</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Macromolecules</subject><subject>Methanol</subject><subject>Polyisopropyl acrylamide</subject><subject>Polymer Sciences</subject><subject>Vesicles</subject><issn>0256-7679</issn><issn>1439-6203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LAzEQhoMoWKs_wFvAczQfu9nNUYu1hVYvel6S7KympJuabJX215tSwZMwMJfneYd5Ebpm9JZRWt0lRhmrCeWM8LJgZH-CRqwQikhOxSkaUV5KUslKnaOLlFaUyqIqqxGKU9DJGQ94qk10Vg8u9Dh0eBa8D9946WwM5AuSsx4SNjv8HHqi15sPl8c7i5c6E-vgwW4PxINO0OKcMe8HiJ22Tns8CX3oU_Bf0NvdJTrrtE9w9bvH6G36-DqZkcXL03xyvyBWlGogVcWUlkJRJVTBQWgJQpWyVtYwqWoDtSmAVkpoTaUAI7SitRGFla1lrWzFGN0cczcxfG4hDc0qbGOfTza5ooLzuqx5ptiRyl-kFKFrNtGtddw1jDaHaptjtU2u9uCxZp8dfnRSZvt3iH_J_0s_vJd9bg</recordid><startdate>20210701</startdate><enddate>20210701</enddate><creator>Wang, Jing-Hong</creator><creator>Chen, Rui</creator><creator>Zhao, Zi-Qing</creator><creator>Shen, Jie</creator><creator>Yang, He</creator><creator>Luo, Yan</creator><creator>Chen, Gao-Jian</creator><creator>Chen, Hong</creator><creator>Brash, John L.</creator><general>Chinese Chemical Society and Institute of Chemistry, CAS</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210701</creationdate><title>Feasible Fabrication of Hollow Micro-vesicles by Non-amphiphilic Macromolecules Based on Interfacial Cononsolvency</title><author>Wang, Jing-Hong ; Chen, Rui ; Zhao, Zi-Qing ; Shen, Jie ; Yang, He ; Luo, Yan ; Chen, Gao-Jian ; Chen, Hong ; Brash, John L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-7719a639093942e3a6e395689cb1698be8b4e0793aa063eb3a908b34c6dc1d6d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Copolymerization</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Macromolecules</topic><topic>Methanol</topic><topic>Polyisopropyl acrylamide</topic><topic>Polymer Sciences</topic><topic>Vesicles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Jing-Hong</creatorcontrib><creatorcontrib>Chen, Rui</creatorcontrib><creatorcontrib>Zhao, Zi-Qing</creatorcontrib><creatorcontrib>Shen, Jie</creatorcontrib><creatorcontrib>Yang, He</creatorcontrib><creatorcontrib>Luo, Yan</creatorcontrib><creatorcontrib>Chen, Gao-Jian</creatorcontrib><creatorcontrib>Chen, Hong</creatorcontrib><creatorcontrib>Brash, John L.</creatorcontrib><collection>CrossRef</collection><jtitle>Chinese journal of polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Jing-Hong</au><au>Chen, Rui</au><au>Zhao, Zi-Qing</au><au>Shen, Jie</au><au>Yang, He</au><au>Luo, Yan</au><au>Chen, Gao-Jian</au><au>Chen, Hong</au><au>Brash, John L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Feasible Fabrication of Hollow Micro-vesicles by Non-amphiphilic Macromolecules Based on Interfacial Cononsolvency</atitle><jtitle>Chinese journal of polymer science</jtitle><stitle>Chin J Polym Sci</stitle><date>2021-07-01</date><risdate>2021</risdate><volume>39</volume><issue>7</issue><spage>856</spage><epage>864</epage><pages>856-864</pages><issn>0256-7679</issn><eissn>1439-6203</eissn><abstract>Herein we present a new perspective showing that water-soluble liquids, when added to water, undergo transient emulsification before complete dissolution. Thus, non-amphiphilic macromolecules can self-assemble at the two-miscible-phase interface when cononsolvent effect appears. A representative case shown here is that when poly(
N
-isopropylacrylamide) (PNIPAm), prepared by aqueous radical polymerization, in methanol solution is added into water, the polymer chains rapidly self-assemble into hollow micro-vesicles based on the cononsolvency at water/methanol interface. This finding provides a subtle strategy to prepare hollow micro-vesicles by non-amphiphilic polymers without template participating. We proposed a new concept “interfacial cononsolvency” to describe the formation process. Due to the easy modification process, sugar-contained PNIPAm chains are synthesized by copolymerization. As an application example, it is shown that these sugar-contained PNIPAm chains can afford “sweet” micro-vesicles (containing glucose residues). And the “sweet” micro-vesicles can well mimick the protocells which are involved in the recognition of bacteria.</abstract><cop>Beijing</cop><pub>Chinese Chemical Society and Institute of Chemistry, CAS</pub><doi>10.1007/s10118-021-2541-z</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0256-7679 |
ispartof | Chinese journal of polymer science, 2021-07, Vol.39 (7), p.856-864 |
issn | 0256-7679 1439-6203 |
language | eng |
recordid | cdi_proquest_journals_2544228582 |
source | SpringerNature Journals; Alma/SFX Local Collection |
subjects | Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Copolymerization Industrial Chemistry/Chemical Engineering Macromolecules Methanol Polyisopropyl acrylamide Polymer Sciences Vesicles |
title | Feasible Fabrication of Hollow Micro-vesicles by Non-amphiphilic Macromolecules Based on Interfacial Cononsolvency |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-23T02%3A22%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Feasible%20Fabrication%20of%20Hollow%20Micro-vesicles%20by%20Non-amphiphilic%20Macromolecules%20Based%20on%20Interfacial%20Cononsolvency&rft.jtitle=Chinese%20journal%20of%20polymer%20science&rft.au=Wang,%20Jing-Hong&rft.date=2021-07-01&rft.volume=39&rft.issue=7&rft.spage=856&rft.epage=864&rft.pages=856-864&rft.issn=0256-7679&rft.eissn=1439-6203&rft_id=info:doi/10.1007/s10118-021-2541-z&rft_dat=%3Cproquest_cross%3E2544228582%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2544228582&rft_id=info:pmid/&rfr_iscdi=true |