Current density enhancement for quantum dot-sensitized solar cells by modulation on the quantum dot loading amount of anatase nanowire array photoelectrodes

A second spin-coating process was employed for CuInS 2 quantum dot (QD)-sensitized TiO 2 nanowire-based solar cells, which is anticipated to increase the QD loading amount of photoelectrodes. And the photoelectrodes had been modulated by the quantum dot dispersion concentration and spin-coating cycl...

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Veröffentlicht in:Journal of solid state electrochemistry 2021-07, Vol.25 (7), p.2087-2096
Hauptverfasser: Wang, Meng, Peng, Zhuoyin, Ning, Zuoqiu, Chen, Jianlin, Li, Wei, Chen, Jian, Huang, Dong
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container_end_page 2096
container_issue 7
container_start_page 2087
container_title Journal of solid state electrochemistry
container_volume 25
creator Wang, Meng
Peng, Zhuoyin
Ning, Zuoqiu
Chen, Jianlin
Li, Wei
Chen, Jian
Huang, Dong
description A second spin-coating process was employed for CuInS 2 quantum dot (QD)-sensitized TiO 2 nanowire-based solar cells, which is anticipated to increase the QD loading amount of photoelectrodes. And the photoelectrodes had been modulated by the quantum dot dispersion concentration and spin-coating cycles. The optical absorption spectra and photoluminescence spectra of different photoelectrodes were investigated, which had exhibited the larger QD loading amount and better charge separation property of photoelectrodes after the second spin-coating process. Meanwhile, a net connection structure had been formed between each nanowire by the suitable QD loading amount of the photoelectrodes, which had simultaneously provided more paths for charge transfer of the solar cells. By optimization, the CuInS 2 QD-sensitized TiO 2 nanowire solar cells prepared from QD dispersion concentration of 30 mg∙mL −1 and two spin-coating cycles had exhibited higher current density value, which had enhanced the photovoltaic conversion efficiency from 3.9 to 5.03%.
doi_str_mv 10.1007/s10008-021-04969-z
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subjects Absorption spectra
Analytical Chemistry
Anatase
Characterization and Evaluation of Materials
Charge transfer
Chemistry
Chemistry and Materials Science
Condensed Matter Physics
Current density
Dispersion
Electrochemistry
Energy Storage
Nanowires
Optimization
Original Paper
Photoluminescence
Photovoltaic cells
Photovoltaic conversion
Physical Chemistry
Quantum dots
Solar cells
Spin coating
Titanium dioxide
title Current density enhancement for quantum dot-sensitized solar cells by modulation on the quantum dot loading amount of anatase nanowire array photoelectrodes
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