Engineering of nickel‐cobalt oxide nanostructures based on biomass material for high performance supercapacitor and catalytic water splitting
Summary The purpose of the present study is to report the synthesis of a porous composite constructed from chicken feathers (CF) and nickel and cobalt salts and its application as a new material for modification of positive electrode surface used in supercapacitor as well as hydrogen and oxygen evol...
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| Veröffentlicht in: | International journal of energy research 2021-07, Vol.45 (9), p.12879-12897 |
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| creator | Abdolahi, Bahare Gholivand, Mohammad Bagher Shamsipur, Mojtaba Amiri, Masoud |
| description | Summary
The purpose of the present study is to report the synthesis of a porous composite constructed from chicken feathers (CF) and nickel and cobalt salts and its application as a new material for modification of positive electrode surface used in supercapacitor as well as hydrogen and oxygen evolution. In this regard, we used waste CF as a biomass precursor and nitrate salts of nickel and cobalt to synthesize a highly porous composite through a solvothermal reaction. After characterization of nanocomposite using different physical and electrochemical techniques, it was used in fabrication of an electrochemical supercapacitor as well as hydrogen and oxygen evolution. The composite demonstrated remarkable electrochemical properties such as fast electrochemical reactions, high conductivity, and high reversibility. In addition, the prepared nanocomposite showed high‐specific capacitance of 2000 F g−1 (with current density of 0.5 mA cm−2 or 1 A g−1) as a supercapacitor. It also shows high energy density about 280 Wh kg−1 and high power density of 55 kW kg−1 as a positive electrode against an active carbon electrode in an asymmetric capacitor at potential range between 0 and 1.5 V. Moreover, the synthesized composite showed noticeable catalytic ability toward hydrogen evolution (HER) and oxygen evolution reaction (OER) with onset potentials of −0.03 and 1.48 V vs reversible hydrogen electrode, respectively. The OER performance of the resulting composite was better than standard platinum electrode. The optimal electrocatalyst (CFAC/Ni&Co oxides) revealed a current density of 10 mA cm−2 at the overpotentials of 87 mV for the HER and a current density of 20 mA at the overpotentials of 230 mV for OER, respectively. Moreover, it also showed a relatively low cell voltage (1.71 V) at a current density of 30 mA cm−2 for the overall water electrolysis.
The purpose of the present study is to report the synthesis of a porous composite constructed from chicken feathers (CF) and nickel and cobalt salts and its application as a new material for modification of positive electrode surface used in supercapacitor as well as hydrogen and oxygen evolution. |
| doi_str_mv | 10.1002/er.6618 |
| format | Article |
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The purpose of the present study is to report the synthesis of a porous composite constructed from chicken feathers (CF) and nickel and cobalt salts and its application as a new material for modification of positive electrode surface used in supercapacitor as well as hydrogen and oxygen evolution. In this regard, we used waste CF as a biomass precursor and nitrate salts of nickel and cobalt to synthesize a highly porous composite through a solvothermal reaction. After characterization of nanocomposite using different physical and electrochemical techniques, it was used in fabrication of an electrochemical supercapacitor as well as hydrogen and oxygen evolution. The composite demonstrated remarkable electrochemical properties such as fast electrochemical reactions, high conductivity, and high reversibility. In addition, the prepared nanocomposite showed high‐specific capacitance of 2000 F g−1 (with current density of 0.5 mA cm−2 or 1 A g−1) as a supercapacitor. It also shows high energy density about 280 Wh kg−1 and high power density of 55 kW kg−1 as a positive electrode against an active carbon electrode in an asymmetric capacitor at potential range between 0 and 1.5 V. Moreover, the synthesized composite showed noticeable catalytic ability toward hydrogen evolution (HER) and oxygen evolution reaction (OER) with onset potentials of −0.03 and 1.48 V vs reversible hydrogen electrode, respectively. The OER performance of the resulting composite was better than standard platinum electrode. The optimal electrocatalyst (CFAC/Ni&Co oxides) revealed a current density of 10 mA cm−2 at the overpotentials of 87 mV for the HER and a current density of 20 mA at the overpotentials of 230 mV for OER, respectively. Moreover, it also showed a relatively low cell voltage (1.71 V) at a current density of 30 mA cm−2 for the overall water electrolysis.
The purpose of the present study is to report the synthesis of a porous composite constructed from chicken feathers (CF) and nickel and cobalt salts and its application as a new material for modification of positive electrode surface used in supercapacitor as well as hydrogen and oxygen evolution.</description><identifier>ISSN: 0363-907X</identifier><identifier>EISSN: 1099-114X</identifier><identifier>DOI: 10.1002/er.6618</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Inc</publisher><subject>Activated carbon ; Biomass ; Capacitance ; Chemical reactions ; Chemical synthesis ; Cobalt ; Cobalt oxides ; Current density ; Electrocatalysts ; Electrochemical analysis ; Electrochemistry ; Electrodes ; Electrolysis ; Evolution ; Fabrication ; Flux density ; Hydrogen ; Hydrogen evolution ; nanocomposite ; Nanocomposites ; Nickel ; nickel‐cobalt oxide ; Oxides ; Oxygen ; oxygen evolution ; Oxygen evolution reactions ; Platinum ; Salts ; supercapacitor ; Supercapacitors ; Water splitting</subject><ispartof>International journal of energy research, 2021-07, Vol.45 (9), p.12879-12897</ispartof><rights>2021 John Wiley & Sons Ltd</rights><rights>2021 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4258-74baf72150a6d18875d4865294407ff8cc3eb40325650a37f46c4f0577de7ed23</citedby><cites>FETCH-LOGICAL-c4258-74baf72150a6d18875d4865294407ff8cc3eb40325650a37f46c4f0577de7ed23</cites><orcidid>0000-0003-4415-9999</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fer.6618$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fer.6618$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,778,782,1414,27911,27912,45561,45562</link.rule.ids></links><search><creatorcontrib>Abdolahi, Bahare</creatorcontrib><creatorcontrib>Gholivand, Mohammad Bagher</creatorcontrib><creatorcontrib>Shamsipur, Mojtaba</creatorcontrib><creatorcontrib>Amiri, Masoud</creatorcontrib><title>Engineering of nickel‐cobalt oxide nanostructures based on biomass material for high performance supercapacitor and catalytic water splitting</title><title>International journal of energy research</title><description>Summary
The purpose of the present study is to report the synthesis of a porous composite constructed from chicken feathers (CF) and nickel and cobalt salts and its application as a new material for modification of positive electrode surface used in supercapacitor as well as hydrogen and oxygen evolution. In this regard, we used waste CF as a biomass precursor and nitrate salts of nickel and cobalt to synthesize a highly porous composite through a solvothermal reaction. After characterization of nanocomposite using different physical and electrochemical techniques, it was used in fabrication of an electrochemical supercapacitor as well as hydrogen and oxygen evolution. The composite demonstrated remarkable electrochemical properties such as fast electrochemical reactions, high conductivity, and high reversibility. In addition, the prepared nanocomposite showed high‐specific capacitance of 2000 F g−1 (with current density of 0.5 mA cm−2 or 1 A g−1) as a supercapacitor. It also shows high energy density about 280 Wh kg−1 and high power density of 55 kW kg−1 as a positive electrode against an active carbon electrode in an asymmetric capacitor at potential range between 0 and 1.5 V. Moreover, the synthesized composite showed noticeable catalytic ability toward hydrogen evolution (HER) and oxygen evolution reaction (OER) with onset potentials of −0.03 and 1.48 V vs reversible hydrogen electrode, respectively. The OER performance of the resulting composite was better than standard platinum electrode. The optimal electrocatalyst (CFAC/Ni&Co oxides) revealed a current density of 10 mA cm−2 at the overpotentials of 87 mV for the HER and a current density of 20 mA at the overpotentials of 230 mV for OER, respectively. Moreover, it also showed a relatively low cell voltage (1.71 V) at a current density of 30 mA cm−2 for the overall water electrolysis.
The purpose of the present study is to report the synthesis of a porous composite constructed from chicken feathers (CF) and nickel and cobalt salts and its application as a new material for modification of positive electrode surface used in supercapacitor as well as hydrogen and oxygen evolution.</description><subject>Activated carbon</subject><subject>Biomass</subject><subject>Capacitance</subject><subject>Chemical reactions</subject><subject>Chemical synthesis</subject><subject>Cobalt</subject><subject>Cobalt oxides</subject><subject>Current density</subject><subject>Electrocatalysts</subject><subject>Electrochemical analysis</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Electrolysis</subject><subject>Evolution</subject><subject>Fabrication</subject><subject>Flux density</subject><subject>Hydrogen</subject><subject>Hydrogen evolution</subject><subject>nanocomposite</subject><subject>Nanocomposites</subject><subject>Nickel</subject><subject>nickel‐cobalt oxide</subject><subject>Oxides</subject><subject>Oxygen</subject><subject>oxygen evolution</subject><subject>Oxygen evolution reactions</subject><subject>Platinum</subject><subject>Salts</subject><subject>supercapacitor</subject><subject>Supercapacitors</subject><subject>Water splitting</subject><issn>0363-907X</issn><issn>1099-114X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kM9KxDAQxoMouK7iKwQ8eJCuSZs27VFk_QMLgijsraTpZDfaTWqSsu7NN9Bn9EnMul49zQzf75sZPoROKZlQQtJLcJOioOUeGlFSVQmlbL6PRiQrsqQifH6Ijrx_ISRqlI_Q59QstAFw2iywVdho-Qrd98eXtI3oArbvugVshLE-uEGGwYHHjfDQYmtwo-1KeI9XIsQNosPKOrzUiyXuwcV-JYwE7Ic4SdELqUPUhWmxFEF0m6AlXm-t2PedDiH-cIwOlOg8nPzVMXq-mT5d3yWzh9v766tZIlmalwlnjVA8pTkRRUvLkuctK4s8rRgjXKlSygwaRrI0LyKSccUKyRTJOW-BQ5tmY3S229s7-zaAD_WLHZyJJ-s0ZzT6Kkoidb6jpLPeO1B17_RKuE1NSb1NuwZXb9OO5MWOXOsONv9h9fTxl_4B1cSDlg</recordid><startdate>202107</startdate><enddate>202107</enddate><creator>Abdolahi, Bahare</creator><creator>Gholivand, Mohammad Bagher</creator><creator>Shamsipur, Mojtaba</creator><creator>Amiri, Masoud</creator><general>John Wiley & Sons, Inc</general><general>Hindawi Limited</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7ST</scope><scope>7TB</scope><scope>7TN</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>F28</scope><scope>FR3</scope><scope>H96</scope><scope>KR7</scope><scope>L.G</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0003-4415-9999</orcidid></search><sort><creationdate>202107</creationdate><title>Engineering of nickel‐cobalt oxide nanostructures based on biomass material for high performance supercapacitor and catalytic water splitting</title><author>Abdolahi, Bahare ; Gholivand, Mohammad Bagher ; Shamsipur, Mojtaba ; Amiri, Masoud</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4258-74baf72150a6d18875d4865294407ff8cc3eb40325650a37f46c4f0577de7ed23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Activated carbon</topic><topic>Biomass</topic><topic>Capacitance</topic><topic>Chemical reactions</topic><topic>Chemical synthesis</topic><topic>Cobalt</topic><topic>Cobalt oxides</topic><topic>Current density</topic><topic>Electrocatalysts</topic><topic>Electrochemical analysis</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Electrolysis</topic><topic>Evolution</topic><topic>Fabrication</topic><topic>Flux density</topic><topic>Hydrogen</topic><topic>Hydrogen evolution</topic><topic>nanocomposite</topic><topic>Nanocomposites</topic><topic>Nickel</topic><topic>nickel‐cobalt oxide</topic><topic>Oxides</topic><topic>Oxygen</topic><topic>oxygen evolution</topic><topic>Oxygen evolution reactions</topic><topic>Platinum</topic><topic>Salts</topic><topic>supercapacitor</topic><topic>Supercapacitors</topic><topic>Water splitting</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Abdolahi, Bahare</creatorcontrib><creatorcontrib>Gholivand, Mohammad Bagher</creatorcontrib><creatorcontrib>Shamsipur, Mojtaba</creatorcontrib><creatorcontrib>Amiri, Masoud</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Environment Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Oceanic Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Civil Engineering Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>International journal of energy research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Abdolahi, Bahare</au><au>Gholivand, Mohammad Bagher</au><au>Shamsipur, Mojtaba</au><au>Amiri, Masoud</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Engineering of nickel‐cobalt oxide nanostructures based on biomass material for high performance supercapacitor and catalytic water splitting</atitle><jtitle>International journal of energy research</jtitle><date>2021-07</date><risdate>2021</risdate><volume>45</volume><issue>9</issue><spage>12879</spage><epage>12897</epage><pages>12879-12897</pages><issn>0363-907X</issn><eissn>1099-114X</eissn><abstract>Summary
The purpose of the present study is to report the synthesis of a porous composite constructed from chicken feathers (CF) and nickel and cobalt salts and its application as a new material for modification of positive electrode surface used in supercapacitor as well as hydrogen and oxygen evolution. In this regard, we used waste CF as a biomass precursor and nitrate salts of nickel and cobalt to synthesize a highly porous composite through a solvothermal reaction. After characterization of nanocomposite using different physical and electrochemical techniques, it was used in fabrication of an electrochemical supercapacitor as well as hydrogen and oxygen evolution. The composite demonstrated remarkable electrochemical properties such as fast electrochemical reactions, high conductivity, and high reversibility. In addition, the prepared nanocomposite showed high‐specific capacitance of 2000 F g−1 (with current density of 0.5 mA cm−2 or 1 A g−1) as a supercapacitor. It also shows high energy density about 280 Wh kg−1 and high power density of 55 kW kg−1 as a positive electrode against an active carbon electrode in an asymmetric capacitor at potential range between 0 and 1.5 V. Moreover, the synthesized composite showed noticeable catalytic ability toward hydrogen evolution (HER) and oxygen evolution reaction (OER) with onset potentials of −0.03 and 1.48 V vs reversible hydrogen electrode, respectively. The OER performance of the resulting composite was better than standard platinum electrode. The optimal electrocatalyst (CFAC/Ni&Co oxides) revealed a current density of 10 mA cm−2 at the overpotentials of 87 mV for the HER and a current density of 20 mA at the overpotentials of 230 mV for OER, respectively. Moreover, it also showed a relatively low cell voltage (1.71 V) at a current density of 30 mA cm−2 for the overall water electrolysis.
The purpose of the present study is to report the synthesis of a porous composite constructed from chicken feathers (CF) and nickel and cobalt salts and its application as a new material for modification of positive electrode surface used in supercapacitor as well as hydrogen and oxygen evolution.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/er.6618</doi><tpages>19</tpages><orcidid>https://orcid.org/0000-0003-4415-9999</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Activated carbon Biomass Capacitance Chemical reactions Chemical synthesis Cobalt Cobalt oxides Current density Electrocatalysts Electrochemical analysis Electrochemistry Electrodes Electrolysis Evolution Fabrication Flux density Hydrogen Hydrogen evolution nanocomposite Nanocomposites Nickel nickel‐cobalt oxide Oxides Oxygen oxygen evolution Oxygen evolution reactions Platinum Salts supercapacitor Supercapacitors Water splitting |
| title | Engineering of nickel‐cobalt oxide nanostructures based on biomass material for high performance supercapacitor and catalytic water splitting |
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