Analysis of Oxidative Deterioration of Biodiesel Fuel
Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the...
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| Veröffentlicht in: | SAE International journal of fuels and lubricants 2009-04, Vol.1 (1), p.1571-1583, Article 2008-01-2502 |
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| container_title | SAE International journal of fuels and lubricants |
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| creator | Ogawa, Tadao Kajiya, Shuji Kosaka, Satoru Tajima, Ichiro Yamamoto, Masami Okada, Masanori |
| description | Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME. |
| doi_str_mv | 10.4271/2008-01-2502 |
| format | Article |
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The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. 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The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME.</abstract><cop>Warrendale</cop><pub>SAE International</pub><doi>10.4271/2008-01-2502</doi><tpages>13</tpages></addata></record> |
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| identifier | ISSN: 1946-3952 |
| ispartof | SAE International journal of fuels and lubricants, 2009-04, Vol.1 (1), p.1571-1583, Article 2008-01-2502 |
| issn | 1946-3952 1946-3960 1946-3960 |
| language | eng |
| recordid | cdi_proquest_journals_2540592321 |
| source | Jstor Complete Legacy |
| subjects | Alcohols Aldehydes Aliphatic compounds Atoms Biodiesel Biodiesel fuels Biofuels Carbon Cooking Cooking oils Cresols Deterioration Dimers Esters Fatty acids Gas flow Heating Ionization Ions Ketones Low molecular weights Mass spectrometry Mass spectroscopy Molecular weight Oligomers Oxidation |
| title | Analysis of Oxidative Deterioration of Biodiesel Fuel |
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