Surface Modification of Rice Husk Ash by Ethanol-assisted Milling to Reinforce the Properties of Natural Rubber/Butadiene Rubber Composites
R ice husk ash(RHA), obtained by pyrolysis of rice husks, can be used as a potential reinforcing filler for rubber composites. In this work, ball milling in ethanol(ethanol-assisted milling) was used to hydroxylate the surface of RHA, promoting the graft modification of bis-( γ -triethoxysilylpropyl...
Gespeichert in:
| Veröffentlicht in: | Chemical research in Chinese universities 2021-06, Vol.37 (3), p.757-762 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 762 |
|---|---|
| container_issue | 3 |
| container_start_page | 757 |
| container_title | Chemical research in Chinese universities |
| container_volume | 37 |
| creator | Chen, Zhixiao Qian, Miaomiao Liu, Chang Xue, Beichen Yu, Liyun Zhu, Yanchao Wang, Xiaofeng |
| description | R
ice husk ash(RHA), obtained by pyrolysis of rice husks, can be used as a potential reinforcing filler for rubber composites. In this work, ball milling in ethanol(ethanol-assisted milling) was used to hydroxylate the surface of RHA, promoting the graft modification of bis-(
γ
-triethoxysilylpropyl)-tetrasulfide(Si69). The obtained modified RHA(RHA-EM-Si69) was filled into the natural rubber/butadiene rubber(NR/BR) composites, and the filler-rubber interactions were enhanced. In consequence, RHA-EM-Si69 filled NR/BR composites showed overall improvement in the mechanical properties compared with RHA filled NR/BR composites. The tear strength increased from 13.37 kN/m to 34.71 kN/m, and the tensile strength increased from 1.84 MPa to 7.75 MPa. Carbon black(N774) was also used for comparison under the same conditions. This method provides a potential for promoting the value of RHA in rubber industry. |
| doi_str_mv | 10.1007/s40242-021-0341-1 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2540115426</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2540115426</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-39ee77c6ba7d2b2f600fa126a56f824417171ccb538f4f949b4817a87935f4a53</originalsourceid><addsrcrecordid>eNp1kEFOwzAQRS0EEqVwAHaWWJt6HCdplqUqFKkFVGBtOanduqRxsJ1Fz8ClcZVKrFiNNPrvj-YhdAv0HijNR55TxhmhDAhNOBA4QwPGgJIEcjhHgxhKSUE5vURX3u8oTYos4wP08945LSuFl3ZttKlkMLbBVuOVict557_wxG9xecCzsJWNrYn03vig1nhp6to0GxwsXinTaOsiEbYKvznbKheM8seiFxk6J2u86spSudFDF-TaqEadFnhq9631Jih_jS60rL26Oc0h-nycfUznZPH69DydLEiVQBZIUiiV51VWynzNSqYzSrUElsk002PGeXw4h6oq02SsuS54UfIx5HKcF0mquUyTIbrre1tnvzvlg9jZzjXxpGAppwApZ1lMQZ-qnPXeKS1aZ_bSHQRQcXQueuciOhdH5wIiw3rGx2yzUe6v-X_oF9sOhMo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2540115426</pqid></control><display><type>article</type><title>Surface Modification of Rice Husk Ash by Ethanol-assisted Milling to Reinforce the Properties of Natural Rubber/Butadiene Rubber Composites</title><source>Springer Nature - Complete Springer Journals</source><creator>Chen, Zhixiao ; Qian, Miaomiao ; Liu, Chang ; Xue, Beichen ; Yu, Liyun ; Zhu, Yanchao ; Wang, Xiaofeng</creator><creatorcontrib>Chen, Zhixiao ; Qian, Miaomiao ; Liu, Chang ; Xue, Beichen ; Yu, Liyun ; Zhu, Yanchao ; Wang, Xiaofeng</creatorcontrib><description>R
ice husk ash(RHA), obtained by pyrolysis of rice husks, can be used as a potential reinforcing filler for rubber composites. In this work, ball milling in ethanol(ethanol-assisted milling) was used to hydroxylate the surface of RHA, promoting the graft modification of bis-(
γ
-triethoxysilylpropyl)-tetrasulfide(Si69). The obtained modified RHA(RHA-EM-Si69) was filled into the natural rubber/butadiene rubber(NR/BR) composites, and the filler-rubber interactions were enhanced. In consequence, RHA-EM-Si69 filled NR/BR composites showed overall improvement in the mechanical properties compared with RHA filled NR/BR composites. The tear strength increased from 13.37 kN/m to 34.71 kN/m, and the tensile strength increased from 1.84 MPa to 7.75 MPa. Carbon black(N774) was also used for comparison under the same conditions. This method provides a potential for promoting the value of RHA in rubber industry.</description><identifier>ISSN: 1005-9040</identifier><identifier>EISSN: 2210-3171</identifier><identifier>DOI: 10.1007/s40242-021-0341-1</identifier><language>eng</language><publisher>Changchun: Jilin University and The Editorial Department of Chemical Research in Chinese Universities</publisher><subject>Analytical Chemistry ; Ashes ; Ball milling ; Butadiene ; Carbon black ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Composite materials ; Ethanol ; Fillers ; Inorganic Chemistry ; Mechanical properties ; Natural rubber ; Organic Chemistry ; Physical Chemistry ; Pyrolysis ; Rubber ; Tear strength ; Tensile strength</subject><ispartof>Chemical research in Chinese universities, 2021-06, Vol.37 (3), p.757-762</ispartof><rights>Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2021</rights><rights>Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-39ee77c6ba7d2b2f600fa126a56f824417171ccb538f4f949b4817a87935f4a53</citedby><cites>FETCH-LOGICAL-c316t-39ee77c6ba7d2b2f600fa126a56f824417171ccb538f4f949b4817a87935f4a53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s40242-021-0341-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s40242-021-0341-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27913,27914,41477,42546,51308</link.rule.ids></links><search><creatorcontrib>Chen, Zhixiao</creatorcontrib><creatorcontrib>Qian, Miaomiao</creatorcontrib><creatorcontrib>Liu, Chang</creatorcontrib><creatorcontrib>Xue, Beichen</creatorcontrib><creatorcontrib>Yu, Liyun</creatorcontrib><creatorcontrib>Zhu, Yanchao</creatorcontrib><creatorcontrib>Wang, Xiaofeng</creatorcontrib><title>Surface Modification of Rice Husk Ash by Ethanol-assisted Milling to Reinforce the Properties of Natural Rubber/Butadiene Rubber Composites</title><title>Chemical research in Chinese universities</title><addtitle>Chem. Res. Chin. Univ</addtitle><description>R
ice husk ash(RHA), obtained by pyrolysis of rice husks, can be used as a potential reinforcing filler for rubber composites. In this work, ball milling in ethanol(ethanol-assisted milling) was used to hydroxylate the surface of RHA, promoting the graft modification of bis-(
γ
-triethoxysilylpropyl)-tetrasulfide(Si69). The obtained modified RHA(RHA-EM-Si69) was filled into the natural rubber/butadiene rubber(NR/BR) composites, and the filler-rubber interactions were enhanced. In consequence, RHA-EM-Si69 filled NR/BR composites showed overall improvement in the mechanical properties compared with RHA filled NR/BR composites. The tear strength increased from 13.37 kN/m to 34.71 kN/m, and the tensile strength increased from 1.84 MPa to 7.75 MPa. Carbon black(N774) was also used for comparison under the same conditions. This method provides a potential for promoting the value of RHA in rubber industry.</description><subject>Analytical Chemistry</subject><subject>Ashes</subject><subject>Ball milling</subject><subject>Butadiene</subject><subject>Carbon black</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Composite materials</subject><subject>Ethanol</subject><subject>Fillers</subject><subject>Inorganic Chemistry</subject><subject>Mechanical properties</subject><subject>Natural rubber</subject><subject>Organic Chemistry</subject><subject>Physical Chemistry</subject><subject>Pyrolysis</subject><subject>Rubber</subject><subject>Tear strength</subject><subject>Tensile strength</subject><issn>1005-9040</issn><issn>2210-3171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kEFOwzAQRS0EEqVwAHaWWJt6HCdplqUqFKkFVGBtOanduqRxsJ1Fz8ClcZVKrFiNNPrvj-YhdAv0HijNR55TxhmhDAhNOBA4QwPGgJIEcjhHgxhKSUE5vURX3u8oTYos4wP08945LSuFl3ZttKlkMLbBVuOVict557_wxG9xecCzsJWNrYn03vig1nhp6to0GxwsXinTaOsiEbYKvznbKheM8seiFxk6J2u86spSudFDF-TaqEadFnhq9631Jih_jS60rL26Oc0h-nycfUznZPH69DydLEiVQBZIUiiV51VWynzNSqYzSrUElsk002PGeXw4h6oq02SsuS54UfIx5HKcF0mquUyTIbrre1tnvzvlg9jZzjXxpGAppwApZ1lMQZ-qnPXeKS1aZ_bSHQRQcXQueuciOhdH5wIiw3rGx2yzUe6v-X_oF9sOhMo</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Chen, Zhixiao</creator><creator>Qian, Miaomiao</creator><creator>Liu, Chang</creator><creator>Xue, Beichen</creator><creator>Yu, Liyun</creator><creator>Zhu, Yanchao</creator><creator>Wang, Xiaofeng</creator><general>Jilin University and The Editorial Department of Chemical Research in Chinese Universities</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210601</creationdate><title>Surface Modification of Rice Husk Ash by Ethanol-assisted Milling to Reinforce the Properties of Natural Rubber/Butadiene Rubber Composites</title><author>Chen, Zhixiao ; Qian, Miaomiao ; Liu, Chang ; Xue, Beichen ; Yu, Liyun ; Zhu, Yanchao ; Wang, Xiaofeng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-39ee77c6ba7d2b2f600fa126a56f824417171ccb538f4f949b4817a87935f4a53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Analytical Chemistry</topic><topic>Ashes</topic><topic>Ball milling</topic><topic>Butadiene</topic><topic>Carbon black</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Composite materials</topic><topic>Ethanol</topic><topic>Fillers</topic><topic>Inorganic Chemistry</topic><topic>Mechanical properties</topic><topic>Natural rubber</topic><topic>Organic Chemistry</topic><topic>Physical Chemistry</topic><topic>Pyrolysis</topic><topic>Rubber</topic><topic>Tear strength</topic><topic>Tensile strength</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Zhixiao</creatorcontrib><creatorcontrib>Qian, Miaomiao</creatorcontrib><creatorcontrib>Liu, Chang</creatorcontrib><creatorcontrib>Xue, Beichen</creatorcontrib><creatorcontrib>Yu, Liyun</creatorcontrib><creatorcontrib>Zhu, Yanchao</creatorcontrib><creatorcontrib>Wang, Xiaofeng</creatorcontrib><collection>CrossRef</collection><jtitle>Chemical research in Chinese universities</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Zhixiao</au><au>Qian, Miaomiao</au><au>Liu, Chang</au><au>Xue, Beichen</au><au>Yu, Liyun</au><au>Zhu, Yanchao</au><au>Wang, Xiaofeng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Surface Modification of Rice Husk Ash by Ethanol-assisted Milling to Reinforce the Properties of Natural Rubber/Butadiene Rubber Composites</atitle><jtitle>Chemical research in Chinese universities</jtitle><stitle>Chem. Res. Chin. Univ</stitle><date>2021-06-01</date><risdate>2021</risdate><volume>37</volume><issue>3</issue><spage>757</spage><epage>762</epage><pages>757-762</pages><issn>1005-9040</issn><eissn>2210-3171</eissn><abstract>R
ice husk ash(RHA), obtained by pyrolysis of rice husks, can be used as a potential reinforcing filler for rubber composites. In this work, ball milling in ethanol(ethanol-assisted milling) was used to hydroxylate the surface of RHA, promoting the graft modification of bis-(
γ
-triethoxysilylpropyl)-tetrasulfide(Si69). The obtained modified RHA(RHA-EM-Si69) was filled into the natural rubber/butadiene rubber(NR/BR) composites, and the filler-rubber interactions were enhanced. In consequence, RHA-EM-Si69 filled NR/BR composites showed overall improvement in the mechanical properties compared with RHA filled NR/BR composites. The tear strength increased from 13.37 kN/m to 34.71 kN/m, and the tensile strength increased from 1.84 MPa to 7.75 MPa. Carbon black(N774) was also used for comparison under the same conditions. This method provides a potential for promoting the value of RHA in rubber industry.</abstract><cop>Changchun</cop><pub>Jilin University and The Editorial Department of Chemical Research in Chinese Universities</pub><doi>10.1007/s40242-021-0341-1</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1005-9040 |
| ispartof | Chemical research in Chinese universities, 2021-06, Vol.37 (3), p.757-762 |
| issn | 1005-9040 2210-3171 |
| language | eng |
| recordid | cdi_proquest_journals_2540115426 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Analytical Chemistry Ashes Ball milling Butadiene Carbon black Chemistry Chemistry and Materials Science Chemistry/Food Science Composite materials Ethanol Fillers Inorganic Chemistry Mechanical properties Natural rubber Organic Chemistry Physical Chemistry Pyrolysis Rubber Tear strength Tensile strength |
| title | Surface Modification of Rice Husk Ash by Ethanol-assisted Milling to Reinforce the Properties of Natural Rubber/Butadiene Rubber Composites |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T07%3A48%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Surface%20Modification%20of%20Rice%20Husk%20Ash%20by%20Ethanol-assisted%20Milling%20to%20Reinforce%20the%20Properties%20of%20Natural%20Rubber/Butadiene%20Rubber%20Composites&rft.jtitle=Chemical%20research%20in%20Chinese%20universities&rft.au=Chen,%20Zhixiao&rft.date=2021-06-01&rft.volume=37&rft.issue=3&rft.spage=757&rft.epage=762&rft.pages=757-762&rft.issn=1005-9040&rft.eissn=2210-3171&rft_id=info:doi/10.1007/s40242-021-0341-1&rft_dat=%3Cproquest_cross%3E2540115426%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2540115426&rft_id=info:pmid/&rfr_iscdi=true |