Rheological, thermal and morphological properties of polyethylene terephthalate/polyamide 6/rice husk ash composites

This work deals with the rheological, morphological, and thermal properties of composites having poly(ethylene terephthalate) (PET), polyamide‐6 (PA6), and their blends as matrices, and rice husk ash (RHA) as a filler. The study determines the effect of composition on the change in viscosity and rat...

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Veröffentlicht in:Journal of applied polymer science 2021-09, Vol.138 (36), p.n/a
Hauptverfasser: Matos Costa, Anna Raffaela, Lima, Juliana Cysneiros, Santos, Raquel, Barreto, Lhaira Souza, Henrique, Mariana Alves, Carvalho, Laura Hecker, Almeida, Yêda Medeiros Bastos
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container_end_page n/a
container_issue 36
container_start_page
container_title Journal of applied polymer science
container_volume 138
creator Matos Costa, Anna Raffaela
Lima, Juliana Cysneiros
Santos, Raquel
Barreto, Lhaira Souza
Henrique, Mariana Alves
Carvalho, Laura Hecker
Almeida, Yêda Medeiros Bastos
description This work deals with the rheological, morphological, and thermal properties of composites having poly(ethylene terephthalate) (PET), polyamide‐6 (PA6), and their blends as matrices, and rice husk ash (RHA) as a filler. The study determines the effect of composition on the change in viscosity and rate of degradation during processing in a torque rheometer. Our data indicates that thermal stability and degradation during processing depend on matrix composition and filler concentration. SEM micrographs show both partial adhesion of the filler to the matrices and filler pullout. Optical microscopy shows particle agglomeration and that agglomerate size increased with filler content. FTIR investigates the shifting of absorption bands of PET/PA6 composite after the addition of RHA and attributes the selective dispersion of RHA to the formation of hydrogen bonds. Our data supports the idea that filler employed here is an option to develop polymer composites with improved properties. The effect of the concentration rice husk ash (RHA) on the degradation rate of compounds based on a blend of poly(ethylene terephthalate) (PET) and polyamide‐6 (PA6) were studied using a fast and simple procedure of monitoring polymer degradation under processing conditions using torque rheometry.
doi_str_mv 10.1002/app.50916
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source Wiley Online Library Journals Frontfile Complete
subjects Absorption spectra
Ashes
blends
Composition effects
Degradation
Fillers
Hydrogen bonds
Materials science
Morphology
Optical microscopy
Photomicrographs
Polyamide resins
polyamides
polyesters
Polyethylene terephthalate
Polymer blends
Polymer matrix composites
Polymers
Rheological properties
Rheology
Thermal stability
Thermodynamic properties
title Rheological, thermal and morphological properties of polyethylene terephthalate/polyamide 6/rice husk ash composites
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