Catalyzed production of different grade biofuels using metal ions modified activated carbon of cellulosic wastes
[Display omitted] •Activated carbon of cellulosic waste (ACCD) was prepared by carbonization process.•The chemical activation of ACCW with Mn2+ and/or Fe3+ was carried out using an impregnation method.•Catalytic cracking process of WCO using the prepared catalysts (ACCD, ACCD/Mn, and ACCD/Fe).•Chara...
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creator | Altalhi, Amal A. Mohammed, Eslam.A. Morsy, Salwa. Salwa M. Negm, Nabel.A. Farag, Ahmed A. |
description | [Display omitted]
•Activated carbon of cellulosic waste (ACCD) was prepared by carbonization process.•The chemical activation of ACCW with Mn2+ and/or Fe3+ was carried out using an impregnation method.•Catalytic cracking process of WCO using the prepared catalysts (ACCD, ACCD/Mn, and ACCD/Fe).•Characterization of the produced biofuel was established according to ASTM standard specifications.•The engine tests showed that the thermal brake efficiency of the blend B10 was closed to the petroleum diesel.
This work aims to convert waste cooking oil (WCO) into biofuel through a catalytic cracking process. The process of catalytic cracking was catalyzed using activated carbon loaded with iron and manganese ions. Cellulosic waste, as an eco-friendly, cheap, and renewable resource, was used to prepare the activated carbon. FTIR, XRD, TGA, differential thermal analysis, and N2-adsorption/desorption investigations were applied to characterize the prepared catalysts. Characterization of the obtained biofuels was established according to ASTM standard specifications. The engine tests of the different blends of biofuels-traditional diesel were performed. The obtained data confirmed that the biofuel blend contained 10% biofuel (B10) decreased the brake-specific fuel consumption from 651 g/kw.h for regular diesel to 554 g/kw, and raised the thermal brake efficiency from 15% to 17.4%. Therefore, a biofuel-petroleum fuel blend at 10% of biofuel can be presented as a promising fuel blend for the petroleum diesel. |
doi_str_mv | 10.1016/j.fuel.2021.120646 |
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•Activated carbon of cellulosic waste (ACCD) was prepared by carbonization process.•The chemical activation of ACCW with Mn2+ and/or Fe3+ was carried out using an impregnation method.•Catalytic cracking process of WCO using the prepared catalysts (ACCD, ACCD/Mn, and ACCD/Fe).•Characterization of the produced biofuel was established according to ASTM standard specifications.•The engine tests showed that the thermal brake efficiency of the blend B10 was closed to the petroleum diesel.
This work aims to convert waste cooking oil (WCO) into biofuel through a catalytic cracking process. The process of catalytic cracking was catalyzed using activated carbon loaded with iron and manganese ions. Cellulosic waste, as an eco-friendly, cheap, and renewable resource, was used to prepare the activated carbon. FTIR, XRD, TGA, differential thermal analysis, and N2-adsorption/desorption investigations were applied to characterize the prepared catalysts. Characterization of the obtained biofuels was established according to ASTM standard specifications. The engine tests of the different blends of biofuels-traditional diesel were performed. The obtained data confirmed that the biofuel blend contained 10% biofuel (B10) decreased the brake-specific fuel consumption from 651 g/kw.h for regular diesel to 554 g/kw, and raised the thermal brake efficiency from 15% to 17.4%. Therefore, a biofuel-petroleum fuel blend at 10% of biofuel can be presented as a promising fuel blend for the petroleum diesel.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2021.120646</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Activated carbon ; Biodiesel fuels ; Biofuels ; Brakes ; Carbon ; Catalysts ; Catalytic converters ; Catalytic cracking ; Cooking ; Cooking oils ; Diesel ; Diesel engines ; Differential thermal analysis ; Engine tests ; Fuel consumption ; Heterogeneous catalyst ; Manganese ; Manganese ions ; Metal ions ; Oil wastes ; Petroleum ; Renewable resources ; Thermal analysis ; Waste cooking oil</subject><ispartof>Fuel (Guildford), 2021-07, Vol.295, p.120646, Article 120646</ispartof><rights>2021 Elsevier Ltd</rights><rights>Copyright Elsevier BV Jul 1, 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c328t-ea61653eb1e00aad453f7f263630283d7d468ee4918f7795d170ff95b485690b3</citedby><cites>FETCH-LOGICAL-c328t-ea61653eb1e00aad453f7f263630283d7d468ee4918f7795d170ff95b485690b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.fuel.2021.120646$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Altalhi, Amal A.</creatorcontrib><creatorcontrib>Mohammed, Eslam.A.</creatorcontrib><creatorcontrib>Morsy, Salwa. Salwa M.</creatorcontrib><creatorcontrib>Negm, Nabel.A.</creatorcontrib><creatorcontrib>Farag, Ahmed A.</creatorcontrib><title>Catalyzed production of different grade biofuels using metal ions modified activated carbon of cellulosic wastes</title><title>Fuel (Guildford)</title><description>[Display omitted]
•Activated carbon of cellulosic waste (ACCD) was prepared by carbonization process.•The chemical activation of ACCW with Mn2+ and/or Fe3+ was carried out using an impregnation method.•Catalytic cracking process of WCO using the prepared catalysts (ACCD, ACCD/Mn, and ACCD/Fe).•Characterization of the produced biofuel was established according to ASTM standard specifications.•The engine tests showed that the thermal brake efficiency of the blend B10 was closed to the petroleum diesel.
This work aims to convert waste cooking oil (WCO) into biofuel through a catalytic cracking process. The process of catalytic cracking was catalyzed using activated carbon loaded with iron and manganese ions. Cellulosic waste, as an eco-friendly, cheap, and renewable resource, was used to prepare the activated carbon. FTIR, XRD, TGA, differential thermal analysis, and N2-adsorption/desorption investigations were applied to characterize the prepared catalysts. Characterization of the obtained biofuels was established according to ASTM standard specifications. The engine tests of the different blends of biofuels-traditional diesel were performed. The obtained data confirmed that the biofuel blend contained 10% biofuel (B10) decreased the brake-specific fuel consumption from 651 g/kw.h for regular diesel to 554 g/kw, and raised the thermal brake efficiency from 15% to 17.4%. Therefore, a biofuel-petroleum fuel blend at 10% of biofuel can be presented as a promising fuel blend for the petroleum diesel.</description><subject>Activated carbon</subject><subject>Biodiesel fuels</subject><subject>Biofuels</subject><subject>Brakes</subject><subject>Carbon</subject><subject>Catalysts</subject><subject>Catalytic converters</subject><subject>Catalytic cracking</subject><subject>Cooking</subject><subject>Cooking oils</subject><subject>Diesel</subject><subject>Diesel engines</subject><subject>Differential thermal analysis</subject><subject>Engine tests</subject><subject>Fuel consumption</subject><subject>Heterogeneous catalyst</subject><subject>Manganese</subject><subject>Manganese ions</subject><subject>Metal ions</subject><subject>Oil wastes</subject><subject>Petroleum</subject><subject>Renewable resources</subject><subject>Thermal analysis</subject><subject>Waste cooking oil</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouK7-AU8Bz13z0SYteJHFL1jwoueQJpMlS7dZk3Zl_fWm1LOnmcPzvMO8CN1SsqKEivvdyo3QrRhhdEUZEaU4QwtaS15IWvFztCCZKhgX9BJdpbQjhMi6KhfosNaD7k4_YPEhBjuawYceB4etdw4i9APeRm0Btz5MJxIek--3eA9Zw5lNeB8y63OAzvJRD3kzOrZzjIGuG7uQvMHfOg2QrtGF012Cm7-5RJ_PTx_r12Lz_vK2ftwUhrN6KEALKioOLQVCtLZlxZ10THDBCau5lbYUNUDZ0NpJ2VSWSuJcU7VlXYmGtHyJ7ubc_NbXCGlQuzDGPp9UrOJNUxJBZKbYTJkYUorg1CH6vY4nRYmamlU7Nb2tpmbV3GyWHmYp1wFHD1El46E3YH0EMygb_H_6L3CXgtk</recordid><startdate>20210701</startdate><enddate>20210701</enddate><creator>Altalhi, Amal A.</creator><creator>Mohammed, Eslam.A.</creator><creator>Morsy, Salwa. Salwa M.</creator><creator>Negm, Nabel.A.</creator><creator>Farag, Ahmed A.</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>20210701</creationdate><title>Catalyzed production of different grade biofuels using metal ions modified activated carbon of cellulosic wastes</title><author>Altalhi, Amal A. ; Mohammed, Eslam.A. ; Morsy, Salwa. Salwa M. ; Negm, Nabel.A. ; Farag, Ahmed A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-ea61653eb1e00aad453f7f263630283d7d468ee4918f7795d170ff95b485690b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Activated carbon</topic><topic>Biodiesel fuels</topic><topic>Biofuels</topic><topic>Brakes</topic><topic>Carbon</topic><topic>Catalysts</topic><topic>Catalytic converters</topic><topic>Catalytic cracking</topic><topic>Cooking</topic><topic>Cooking oils</topic><topic>Diesel</topic><topic>Diesel engines</topic><topic>Differential thermal analysis</topic><topic>Engine tests</topic><topic>Fuel consumption</topic><topic>Heterogeneous catalyst</topic><topic>Manganese</topic><topic>Manganese ions</topic><topic>Metal ions</topic><topic>Oil wastes</topic><topic>Petroleum</topic><topic>Renewable resources</topic><topic>Thermal analysis</topic><topic>Waste cooking oil</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Altalhi, Amal A.</creatorcontrib><creatorcontrib>Mohammed, Eslam.A.</creatorcontrib><creatorcontrib>Morsy, Salwa. Salwa M.</creatorcontrib><creatorcontrib>Negm, Nabel.A.</creatorcontrib><creatorcontrib>Farag, Ahmed A.</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Altalhi, Amal A.</au><au>Mohammed, Eslam.A.</au><au>Morsy, Salwa. Salwa M.</au><au>Negm, Nabel.A.</au><au>Farag, Ahmed A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalyzed production of different grade biofuels using metal ions modified activated carbon of cellulosic wastes</atitle><jtitle>Fuel (Guildford)</jtitle><date>2021-07-01</date><risdate>2021</risdate><volume>295</volume><spage>120646</spage><pages>120646-</pages><artnum>120646</artnum><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>[Display omitted]
•Activated carbon of cellulosic waste (ACCD) was prepared by carbonization process.•The chemical activation of ACCW with Mn2+ and/or Fe3+ was carried out using an impregnation method.•Catalytic cracking process of WCO using the prepared catalysts (ACCD, ACCD/Mn, and ACCD/Fe).•Characterization of the produced biofuel was established according to ASTM standard specifications.•The engine tests showed that the thermal brake efficiency of the blend B10 was closed to the petroleum diesel.
This work aims to convert waste cooking oil (WCO) into biofuel through a catalytic cracking process. The process of catalytic cracking was catalyzed using activated carbon loaded with iron and manganese ions. Cellulosic waste, as an eco-friendly, cheap, and renewable resource, was used to prepare the activated carbon. FTIR, XRD, TGA, differential thermal analysis, and N2-adsorption/desorption investigations were applied to characterize the prepared catalysts. Characterization of the obtained biofuels was established according to ASTM standard specifications. The engine tests of the different blends of biofuels-traditional diesel were performed. The obtained data confirmed that the biofuel blend contained 10% biofuel (B10) decreased the brake-specific fuel consumption from 651 g/kw.h for regular diesel to 554 g/kw, and raised the thermal brake efficiency from 15% to 17.4%. Therefore, a biofuel-petroleum fuel blend at 10% of biofuel can be presented as a promising fuel blend for the petroleum diesel.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.fuel.2021.120646</doi></addata></record> |
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subjects | Activated carbon Biodiesel fuels Biofuels Brakes Carbon Catalysts Catalytic converters Catalytic cracking Cooking Cooking oils Diesel Diesel engines Differential thermal analysis Engine tests Fuel consumption Heterogeneous catalyst Manganese Manganese ions Metal ions Oil wastes Petroleum Renewable resources Thermal analysis Waste cooking oil |
title | Catalyzed production of different grade biofuels using metal ions modified activated carbon of cellulosic wastes |
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