Catalyzed production of different grade biofuels using metal ions modified activated carbon of cellulosic wastes

[Display omitted] •Activated carbon of cellulosic waste (ACCD) was prepared by carbonization process.•The chemical activation of ACCW with Mn2+ and/or Fe3+ was carried out using an impregnation method.•Catalytic cracking process of WCO using the prepared catalysts (ACCD, ACCD/Mn, and ACCD/Fe).•Chara...

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Veröffentlicht in:Fuel (Guildford) 2021-07, Vol.295, p.120646, Article 120646
Hauptverfasser: Altalhi, Amal A., Mohammed, Eslam.A., Morsy, Salwa. Salwa M., Negm, Nabel.A., Farag, Ahmed A.
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container_start_page 120646
container_title Fuel (Guildford)
container_volume 295
creator Altalhi, Amal A.
Mohammed, Eslam.A.
Morsy, Salwa. Salwa M.
Negm, Nabel.A.
Farag, Ahmed A.
description [Display omitted] •Activated carbon of cellulosic waste (ACCD) was prepared by carbonization process.•The chemical activation of ACCW with Mn2+ and/or Fe3+ was carried out using an impregnation method.•Catalytic cracking process of WCO using the prepared catalysts (ACCD, ACCD/Mn, and ACCD/Fe).•Characterization of the produced biofuel was established according to ASTM standard specifications.•The engine tests showed that the thermal brake efficiency of the blend B10 was closed to the petroleum diesel. This work aims to convert waste cooking oil (WCO) into biofuel through a catalytic cracking process. The process of catalytic cracking was catalyzed using activated carbon loaded with iron and manganese ions. Cellulosic waste, as an eco-friendly, cheap, and renewable resource, was used to prepare the activated carbon. FTIR, XRD, TGA, differential thermal analysis, and N2-adsorption/desorption investigations were applied to characterize the prepared catalysts. Characterization of the obtained biofuels was established according to ASTM standard specifications. The engine tests of the different blends of biofuels-traditional diesel were performed. The obtained data confirmed that the biofuel blend contained 10% biofuel (B10) decreased the brake-specific fuel consumption from 651 g/kw.h for regular diesel to 554 g/kw, and raised the thermal brake efficiency from 15% to 17.4%. Therefore, a biofuel-petroleum fuel blend at 10% of biofuel can be presented as a promising fuel blend for the petroleum diesel.
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Salwa M. ; Negm, Nabel.A. ; Farag, Ahmed A.</creator><creatorcontrib>Altalhi, Amal A. ; Mohammed, Eslam.A. ; Morsy, Salwa. Salwa M. ; Negm, Nabel.A. ; Farag, Ahmed A.</creatorcontrib><description>[Display omitted] •Activated carbon of cellulosic waste (ACCD) was prepared by carbonization process.•The chemical activation of ACCW with Mn2+ and/or Fe3+ was carried out using an impregnation method.•Catalytic cracking process of WCO using the prepared catalysts (ACCD, ACCD/Mn, and ACCD/Fe).•Characterization of the produced biofuel was established according to ASTM standard specifications.•The engine tests showed that the thermal brake efficiency of the blend B10 was closed to the petroleum diesel. This work aims to convert waste cooking oil (WCO) into biofuel through a catalytic cracking process. The process of catalytic cracking was catalyzed using activated carbon loaded with iron and manganese ions. 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Salwa M.</au><au>Negm, Nabel.A.</au><au>Farag, Ahmed A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalyzed production of different grade biofuels using metal ions modified activated carbon of cellulosic wastes</atitle><jtitle>Fuel (Guildford)</jtitle><date>2021-07-01</date><risdate>2021</risdate><volume>295</volume><spage>120646</spage><pages>120646-</pages><artnum>120646</artnum><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>[Display omitted] •Activated carbon of cellulosic waste (ACCD) was prepared by carbonization process.•The chemical activation of ACCW with Mn2+ and/or Fe3+ was carried out using an impregnation method.•Catalytic cracking process of WCO using the prepared catalysts (ACCD, ACCD/Mn, and ACCD/Fe).•Characterization of the produced biofuel was established according to ASTM standard specifications.•The engine tests showed that the thermal brake efficiency of the blend B10 was closed to the petroleum diesel. 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subjects Activated carbon
Biodiesel fuels
Biofuels
Brakes
Carbon
Catalysts
Catalytic converters
Catalytic cracking
Cooking
Cooking oils
Diesel
Diesel engines
Differential thermal analysis
Engine tests
Fuel consumption
Heterogeneous catalyst
Manganese
Manganese ions
Metal ions
Oil wastes
Petroleum
Renewable resources
Thermal analysis
Waste cooking oil
title Catalyzed production of different grade biofuels using metal ions modified activated carbon of cellulosic wastes
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