An interconversion of oxazoline‐amido‐phenolate aluminium complexes: Structural, catalytic activity and density functional theory studies
This paper describes a new mutual transformation mode occurred between two aluminium complexes, L1(AlMe2)2·AlMe3 and (L1AlMe)2, which were generated upon different solvents and bearing the oxazoline‐amido‐phenolate ligand. Density functional theory (DFT) studies support plausible mechanisms. Their c...
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| Veröffentlicht in: | Applied organometallic chemistry 2021-07, Vol.35 (7), p.n/a |
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| container_title | Applied organometallic chemistry |
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| creator | Chen, Ming‐Tsz Chen, Yu‐Yang Huang, Ting‐Hsun Pi, Hui‐Chu Hu, Ching‐Han Chen, Chi‐Tien |
| description | This paper describes a new mutual transformation mode occurred between two aluminium complexes, L1(AlMe2)2·AlMe3 and (L1AlMe)2, which were generated upon different solvents and bearing the oxazoline‐amido‐phenolate ligand. Density functional theory (DFT) studies support plausible mechanisms. Their catalytic studies were investigated towards ring opening polymerization of ε‐caprolactone and l‐lactide with the benzyl alcohol as the initiating reagent.
Two different types of aluminium complexes, L1(AlMe2)2·AlMe3 and (L1AlMe)2 bearing the oxazolineamido‐phenolate ligand were generated upon different solvent synthetic routes. A new round transformation mode between these aluminium complexes as well as the DFT study supported a plausible mechanism. Their catalytic activities towards the ring opening polymerization of ε‐caprolactone and l‐lactide in the presence of benzyl alcohol were investigated. |
| doi_str_mv | 10.1002/aoc.6251 |
| format | Article |
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Two different types of aluminium complexes, L1(AlMe2)2·AlMe3 and (L1AlMe)2 bearing the oxazolineamido‐phenolate ligand were generated upon different solvent synthetic routes. A new round transformation mode between these aluminium complexes as well as the DFT study supported a plausible mechanism. Their catalytic activities towards the ring opening polymerization of ε‐caprolactone and l‐lactide in the presence of benzyl alcohol were investigated.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.6251</identifier><language>eng</language><publisher>Chichester: Wiley Subscription Services, Inc</publisher><subject>aluminium complexes ; Aluminum ; Benzyl alcohol ; Catalytic activity ; Chemistry ; density functional calculations ; Density functional theory ; Reagents ; Ring opening polymerization ; solvent‐induced ; transformation</subject><ispartof>Applied organometallic chemistry, 2021-07, Vol.35 (7), p.n/a</ispartof><rights>2021 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3301-74d83441d746eba17c5a8dc8ed58d552c944fd6e227e3b83e1e32ac976fdac5c3</citedby><cites>FETCH-LOGICAL-c3301-74d83441d746eba17c5a8dc8ed58d552c944fd6e227e3b83e1e32ac976fdac5c3</cites><orcidid>0000-0002-9665-5823 ; 0000-0002-2483-1437 ; 0000-0002-7427-8174 ; 0000-0002-7949-305X ; 0000-0002-1140-0996 ; 0000-0002-2077-5917</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.6251$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.6251$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Chen, Ming‐Tsz</creatorcontrib><creatorcontrib>Chen, Yu‐Yang</creatorcontrib><creatorcontrib>Huang, Ting‐Hsun</creatorcontrib><creatorcontrib>Pi, Hui‐Chu</creatorcontrib><creatorcontrib>Hu, Ching‐Han</creatorcontrib><creatorcontrib>Chen, Chi‐Tien</creatorcontrib><title>An interconversion of oxazoline‐amido‐phenolate aluminium complexes: Structural, catalytic activity and density functional theory studies</title><title>Applied organometallic chemistry</title><description>This paper describes a new mutual transformation mode occurred between two aluminium complexes, L1(AlMe2)2·AlMe3 and (L1AlMe)2, which were generated upon different solvents and bearing the oxazoline‐amido‐phenolate ligand. Density functional theory (DFT) studies support plausible mechanisms. Their catalytic studies were investigated towards ring opening polymerization of ε‐caprolactone and l‐lactide with the benzyl alcohol as the initiating reagent.
Two different types of aluminium complexes, L1(AlMe2)2·AlMe3 and (L1AlMe)2 bearing the oxazolineamido‐phenolate ligand were generated upon different solvent synthetic routes. A new round transformation mode between these aluminium complexes as well as the DFT study supported a plausible mechanism. Their catalytic activities towards the ring opening polymerization of ε‐caprolactone and l‐lactide in the presence of benzyl alcohol were investigated.</description><subject>aluminium complexes</subject><subject>Aluminum</subject><subject>Benzyl alcohol</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>density functional calculations</subject><subject>Density functional theory</subject><subject>Reagents</subject><subject>Ring opening polymerization</subject><subject>solvent‐induced</subject><subject>transformation</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kMtqGzEUhkVpoK4b6CMIusmi4-oy1-yMaS4Q8CLJejiWzmAFjeRIGieTVV8g0GfMk2Qcd9vVf_j5OPx8hHznbMEZE7_Aq0UpCv6JzDhrmoxVsvlMZkyUdSZKVnwhX2N8YIw1Jc9n5HXpqHEJg_JujyEa76jvqH-GF2-Nw7c_f6E32k-526LzFhJSsENvnBl6qny_s_iM8ZzepjCoNASwP6mCBHZMRlFQyexNGik4TTW6eLi7wU21d2Bp2qIPI41p0AbjN3LSgY14-i_n5P7i993qKrtZX16vljeZkpLxrMp1LfOc6yovcQO8UgXUWtWoi1oXhVBNnne6RCEqlJtaIkcpQDVV2WlQhZJz8uP4dxf844AxtQ9-CNOe2IpCNnk9CWwm6uxIqeBjDNi1u2B6CGPLWXuQ3U6y24PsCc2O6JOxOP6Xa5fr1Qf_Dh-qhqo</recordid><startdate>202107</startdate><enddate>202107</enddate><creator>Chen, Ming‐Tsz</creator><creator>Chen, Yu‐Yang</creator><creator>Huang, Ting‐Hsun</creator><creator>Pi, Hui‐Chu</creator><creator>Hu, Ching‐Han</creator><creator>Chen, Chi‐Tien</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-9665-5823</orcidid><orcidid>https://orcid.org/0000-0002-2483-1437</orcidid><orcidid>https://orcid.org/0000-0002-7427-8174</orcidid><orcidid>https://orcid.org/0000-0002-7949-305X</orcidid><orcidid>https://orcid.org/0000-0002-1140-0996</orcidid><orcidid>https://orcid.org/0000-0002-2077-5917</orcidid></search><sort><creationdate>202107</creationdate><title>An interconversion of oxazoline‐amido‐phenolate aluminium complexes: Structural, catalytic activity and density functional theory studies</title><author>Chen, Ming‐Tsz ; Chen, Yu‐Yang ; Huang, Ting‐Hsun ; Pi, Hui‐Chu ; Hu, Ching‐Han ; Chen, Chi‐Tien</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3301-74d83441d746eba17c5a8dc8ed58d552c944fd6e227e3b83e1e32ac976fdac5c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>aluminium complexes</topic><topic>Aluminum</topic><topic>Benzyl alcohol</topic><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>density functional calculations</topic><topic>Density functional theory</topic><topic>Reagents</topic><topic>Ring opening polymerization</topic><topic>solvent‐induced</topic><topic>transformation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Ming‐Tsz</creatorcontrib><creatorcontrib>Chen, Yu‐Yang</creatorcontrib><creatorcontrib>Huang, Ting‐Hsun</creatorcontrib><creatorcontrib>Pi, Hui‐Chu</creatorcontrib><creatorcontrib>Hu, Ching‐Han</creatorcontrib><creatorcontrib>Chen, Chi‐Tien</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Ming‐Tsz</au><au>Chen, Yu‐Yang</au><au>Huang, Ting‐Hsun</au><au>Pi, Hui‐Chu</au><au>Hu, Ching‐Han</au><au>Chen, Chi‐Tien</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An interconversion of oxazoline‐amido‐phenolate aluminium complexes: Structural, catalytic activity and density functional theory studies</atitle><jtitle>Applied organometallic chemistry</jtitle><date>2021-07</date><risdate>2021</risdate><volume>35</volume><issue>7</issue><epage>n/a</epage><issn>0268-2605</issn><eissn>1099-0739</eissn><abstract>This paper describes a new mutual transformation mode occurred between two aluminium complexes, L1(AlMe2)2·AlMe3 and (L1AlMe)2, which were generated upon different solvents and bearing the oxazoline‐amido‐phenolate ligand. Density functional theory (DFT) studies support plausible mechanisms. Their catalytic studies were investigated towards ring opening polymerization of ε‐caprolactone and l‐lactide with the benzyl alcohol as the initiating reagent.
Two different types of aluminium complexes, L1(AlMe2)2·AlMe3 and (L1AlMe)2 bearing the oxazolineamido‐phenolate ligand were generated upon different solvent synthetic routes. A new round transformation mode between these aluminium complexes as well as the DFT study supported a plausible mechanism. Their catalytic activities towards the ring opening polymerization of ε‐caprolactone and l‐lactide in the presence of benzyl alcohol were investigated.</abstract><cop>Chichester</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aoc.6251</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-9665-5823</orcidid><orcidid>https://orcid.org/0000-0002-2483-1437</orcidid><orcidid>https://orcid.org/0000-0002-7427-8174</orcidid><orcidid>https://orcid.org/0000-0002-7949-305X</orcidid><orcidid>https://orcid.org/0000-0002-1140-0996</orcidid><orcidid>https://orcid.org/0000-0002-2077-5917</orcidid></addata></record> |
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| subjects | aluminium complexes Aluminum Benzyl alcohol Catalytic activity Chemistry density functional calculations Density functional theory Reagents Ring opening polymerization solvent‐induced transformation |
| title | An interconversion of oxazoline‐amido‐phenolate aluminium complexes: Structural, catalytic activity and density functional theory studies |
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