Synthesis and Characterization of Conducting Poly(2-aminothiazole)/Modified-Clay Nanocomposites

In the present work, poly(2-aminothiazole)/organoclay nanocomposites were synthesized via intercalative in situ oxidative polymerization of 2-aminothiazole using ammonium persulfate as an initiator. A certain kind of co-intercalation of montmorillonite was accomplished by polyhydroxy iron cation and...

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Veröffentlicht in:Polymer science. Series B 2021-05, Vol.63 (3), p.314-321
Hauptverfasser: Leila Mouacher, Yahiaoui, Ahmed, Hachemaoui, Aicha, Dehbi, Abdelkader, Benkouider, Ali Mustapha, Reguig, Adelkarim Bendoukha
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container_end_page 321
container_issue 3
container_start_page 314
container_title Polymer science. Series B
container_volume 63
creator Leila Mouacher
Yahiaoui, Ahmed
Hachemaoui, Aicha
Dehbi, Abdelkader
Benkouider, Ali Mustapha
Reguig, Adelkarim Bendoukha
description In the present work, poly(2-aminothiazole)/organoclay nanocomposites were synthesized via intercalative in situ oxidative polymerization of 2-aminothiazole using ammonium persulfate as an initiator. A certain kind of co-intercalation of montmorillonite was accomplished by polyhydroxy iron cation and its organophilization using cetyltrimethylammonium bromide surfactant. The objective was to evaluate the influence of the organoclays basal spacing on the structural and morphological properties of the synthesized nanocomposites. The presence of iron in nanocomposite was confirmed by XPS analysis. The resulting nanocomposites were fully characterized by FTIR spectroscopy and X-ray diffraction.
doi_str_mv 10.1134/S156009042103012X
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subjects Ammonium peroxodisulfate
Cetyltrimethylammonium bromide
Chemistry
Chemistry and Materials Science
Composites
Iron
Montmorillonite
Nanocomposites
Polymer Sciences
X ray photoelectron spectroscopy
title Synthesis and Characterization of Conducting Poly(2-aminothiazole)/Modified-Clay Nanocomposites
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