Preparation and characterization of PLA/PBAT/CNC blend nanocomposites
In this study, the effect of cellulose nanocrystals (CNCs) on the properties of polylactide (PLA)/poly(butylene adipate- co -terephthalate) (PBAT) blends was investigated. Samples were prepared via (i) solution casting (SC) and (ii) combination of solution casting and melt mixing through twin-screw...
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| Veröffentlicht in: | Colloid and polymer science 2021-06, Vol.299 (6), p.987-998 |
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| container_title | Colloid and polymer science |
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| creator | Sarul, Deniz Sema Arslan, Dogan Vatansever, Emre Kahraman, Yusuf Durmus, Ali Salehiyan, Reza Nofar, Mohammadreza |
| description | In this study, the effect of cellulose nanocrystals (CNCs) on the properties of polylactide (PLA)/poly(butylene adipate-
co
-terephthalate) (PBAT) blends was investigated. Samples were prepared via (i) solution casting (SC) and (ii) combination of solution casting and melt mixing through twin-screw extruder (mTSE). Scanning electron microscopy images revealed the effect of CNC content on the droplet morphology of PBAT dispersed phase. Rheological analysis showed that 3 wt% of CNC formed a strong network in PLA by SC method. Differential scanning calorimetry results depicted the heterogeneous nucleation effect of CNC on PLA’s crystallization in samples prepared by mTSE. Dynamic mechanical analysis illustrated that CNC enhanced the modulus beyond the glass transition temperature of PLA regardless of the preparation method. The tensile and impact properties also elucidated that the existence of any possible residual solvent in blends could dramatically avoid achievement of improvements in ductility and impact properties. |
| doi_str_mv | 10.1007/s00396-021-04822-9 |
| format | Article |
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co
-terephthalate) (PBAT) blends was investigated. Samples were prepared via (i) solution casting (SC) and (ii) combination of solution casting and melt mixing through twin-screw extruder (mTSE). Scanning electron microscopy images revealed the effect of CNC content on the droplet morphology of PBAT dispersed phase. Rheological analysis showed that 3 wt% of CNC formed a strong network in PLA by SC method. Differential scanning calorimetry results depicted the heterogeneous nucleation effect of CNC on PLA’s crystallization in samples prepared by mTSE. Dynamic mechanical analysis illustrated that CNC enhanced the modulus beyond the glass transition temperature of PLA regardless of the preparation method. The tensile and impact properties also elucidated that the existence of any possible residual solvent in blends could dramatically avoid achievement of improvements in ductility and impact properties.</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-021-04822-9</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Crystallization ; Dynamic mechanical analysis ; Food Science ; Glass transition temperature ; Mixtures ; Morphology ; Nanocomposites ; Nanocrystals ; Nanotechnology and Microengineering ; Nucleation ; Original Contribution ; Physical Chemistry ; Polylactic acid ; Polymer Sciences ; Rheological properties ; Soft and Granular Matter ; Twin screw extruders</subject><ispartof>Colloid and polymer science, 2021-06, Vol.299 (6), p.987-998</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-c8807f8543dd5d376c61af612d9dde571a9a348872a07473e6e88a1856c72d033</citedby><cites>FETCH-LOGICAL-c356t-c8807f8543dd5d376c61af612d9dde571a9a348872a07473e6e88a1856c72d033</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-021-04822-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-021-04822-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Sarul, Deniz Sema</creatorcontrib><creatorcontrib>Arslan, Dogan</creatorcontrib><creatorcontrib>Vatansever, Emre</creatorcontrib><creatorcontrib>Kahraman, Yusuf</creatorcontrib><creatorcontrib>Durmus, Ali</creatorcontrib><creatorcontrib>Salehiyan, Reza</creatorcontrib><creatorcontrib>Nofar, Mohammadreza</creatorcontrib><title>Preparation and characterization of PLA/PBAT/CNC blend nanocomposites</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>In this study, the effect of cellulose nanocrystals (CNCs) on the properties of polylactide (PLA)/poly(butylene adipate-
co
-terephthalate) (PBAT) blends was investigated. Samples were prepared via (i) solution casting (SC) and (ii) combination of solution casting and melt mixing through twin-screw extruder (mTSE). Scanning electron microscopy images revealed the effect of CNC content on the droplet morphology of PBAT dispersed phase. Rheological analysis showed that 3 wt% of CNC formed a strong network in PLA by SC method. Differential scanning calorimetry results depicted the heterogeneous nucleation effect of CNC on PLA’s crystallization in samples prepared by mTSE. Dynamic mechanical analysis illustrated that CNC enhanced the modulus beyond the glass transition temperature of PLA regardless of the preparation method. The tensile and impact properties also elucidated that the existence of any possible residual solvent in blends could dramatically avoid achievement of improvements in ductility and impact properties.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Crystallization</subject><subject>Dynamic mechanical analysis</subject><subject>Food Science</subject><subject>Glass transition temperature</subject><subject>Mixtures</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Nanocrystals</subject><subject>Nanotechnology and Microengineering</subject><subject>Nucleation</subject><subject>Original Contribution</subject><subject>Physical Chemistry</subject><subject>Polylactic acid</subject><subject>Polymer Sciences</subject><subject>Rheological properties</subject><subject>Soft and Granular Matter</subject><subject>Twin screw extruders</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE1LAzEQhoMoWKt_wNOC59jJd_ZYS_2Aoj1U8BZiktUt7WZN1oP-eqMrePM0zPC8M8yD0DmBSwKgZhmA1RIDJRi4phTXB2hCOBOYCCYP0QQYMMyBPh2jk5y3AMBrKSdouU6ht8kObewq2_nKvZbODSG1n-MwNtV6NZ-tr-ab2eJ-UT3vQsE620UX933M7RDyKTpq7C6Hs986RY_Xy83iFq8ebu4W8xV2TMgBO61BNVpw5r3wTEkniW0kob72PghFbG0Z11pRC4orFmTQ2hItpFPUA2NTdDHu7VN8ew95MNv4nrpy0tDypxSCKygUHSmXYs4pNKZP7d6mD0PAfOsyoy5TdJkfXaYuITaGcoG7l5D-Vv-T-gIygWt_</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Sarul, Deniz Sema</creator><creator>Arslan, Dogan</creator><creator>Vatansever, Emre</creator><creator>Kahraman, Yusuf</creator><creator>Durmus, Ali</creator><creator>Salehiyan, Reza</creator><creator>Nofar, Mohammadreza</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20210601</creationdate><title>Preparation and characterization of PLA/PBAT/CNC blend nanocomposites</title><author>Sarul, Deniz Sema ; 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co
-terephthalate) (PBAT) blends was investigated. Samples were prepared via (i) solution casting (SC) and (ii) combination of solution casting and melt mixing through twin-screw extruder (mTSE). Scanning electron microscopy images revealed the effect of CNC content on the droplet morphology of PBAT dispersed phase. Rheological analysis showed that 3 wt% of CNC formed a strong network in PLA by SC method. Differential scanning calorimetry results depicted the heterogeneous nucleation effect of CNC on PLA’s crystallization in samples prepared by mTSE. Dynamic mechanical analysis illustrated that CNC enhanced the modulus beyond the glass transition temperature of PLA regardless of the preparation method. The tensile and impact properties also elucidated that the existence of any possible residual solvent in blends could dramatically avoid achievement of improvements in ductility and impact properties.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00396-021-04822-9</doi><tpages>12</tpages></addata></record> |
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| subjects | Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Crystallization Dynamic mechanical analysis Food Science Glass transition temperature Mixtures Morphology Nanocomposites Nanocrystals Nanotechnology and Microengineering Nucleation Original Contribution Physical Chemistry Polylactic acid Polymer Sciences Rheological properties Soft and Granular Matter Twin screw extruders |
| title | Preparation and characterization of PLA/PBAT/CNC blend nanocomposites |
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