Synthesis and structure of DyIII 2,2-bis[2-(dimethylamino)-5-methylphenyl]acetate complexes
2,2-Bis[2-(dimethylamino)-5-methylphenyl]acetic acid, Ar 2 CHCOOH ( 1 ) (Ar = 5-Me-2-Me 2 NC 6 H 3 ), was synthesized by the carboxylation of s[2-(dimethylamino)-5-methylphenyl]-methyl lithium, [Ar 2 CH]Li(TMEDA), with gaseous CO 2 . The reaction of 1 with the cationic bis(alkyl) complex [(Me 3 SiCH...
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| Veröffentlicht in: | Russian chemical bulletin 2021, Vol.70 (5), p.818-829 |
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| container_title | Russian chemical bulletin |
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| creator | Khristolyubov, D. O. Lyubov, D. M. Makhrova, T. V. Cherkasov, A. V. Fukin, G. K. Trifonov, A. A. |
| description | 2,2-Bis[2-(dimethylamino)-5-methylphenyl]acetic acid, Ar
2
CHCOOH (
1
) (Ar = 5-Me-2-Me
2
NC
6
H
3
), was synthesized by the carboxylation of
s[2-(dimethylamino)-5-methylphenyl]-methyl
lithium, [Ar
2
CH]Li(TMEDA), with gaseous CO
2
. The reaction of
1
with the cationic bis(alkyl) complex [(Me
3
SiCH
2
)
2
Dy(THF)
n
][BPh
4
] (2: 1 molar ratio) unexpectedly afforded the tetracarboxylate complex [Dy(O
2
CCHAr
2
)
4
(Et
2
NH
2
)
2
][BPh
4
] (
3
), whereas the trinuclear oxo cluster [Dy
3
O(O
2
CHAr
2
)
6
(THF)
4
][BPh
4
] (
4
) was prepared from [(
o
-Me
2
NC
6
H
4
CH
2
)
2
-Dy(THF)
n
][BPh
4
]. In complex
4
, three Dy
3+
cations are linked by the μ
3
-oxo oxygen atom and six bridging μ
2
-κ
1
-O:κ
1
-O’-carboxylate ligands. According to the X-ray diffraction data, NMe
2
groups of the diphenylmethanide moiety are not coordinated to Dy
3+
cations in complexes
3
and
4
. |
| doi_str_mv | 10.1007/s11172-021-3155-x |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2536534156</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2536534156</sourcerecordid><originalsourceid>FETCH-LOGICAL-c113x-329382c34fc7ccc4bc2daa91d7a6acbbfd0fe4583f783b427d444a94317584a93</originalsourceid><addsrcrecordid>eNp1kMtKxDAUhoMoOI4-gLuCGwWjObk06VK8Dgy4UFeDhDRNnQ69mbTQvr0dKrhydf4D_wU-hM6B3AAh8jYAgKSYUMAMhMDDAVqAkAwnIOFw0iSOsaBKHKOTEHaEEKqUWqDN21h3WxeKEJk6i0Lne9v13kVNHj2Mq9UqotcUp0XYUHyZFZXrtmNpqqJurrDA89tuXT2Wn8a6znQusk3Vlm5w4RQd5aYM7uz3LtHH0-P7_Qtevz6v7u_W2AKwATOaMEUt47mV1lqeWpoZk0AmTWxsmuYZyR0XiuVSsZRTmXHOTcIZSKEmwZboYu5tffPdu9DpXdP7eprUVLBYMA4inlwwu6xvQvAu160vKuNHDUTvGeqZoZ4Y6j1DPUwZOmfC5K2_nP9r_j_0A4wQdME</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2536534156</pqid></control><display><type>article</type><title>Synthesis and structure of DyIII 2,2-bis[2-(dimethylamino)-5-methylphenyl]acetate complexes</title><source>SpringerLink Journals - AutoHoldings</source><creator>Khristolyubov, D. O. ; Lyubov, D. M. ; Makhrova, T. V. ; Cherkasov, A. V. ; Fukin, G. K. ; Trifonov, A. A.</creator><creatorcontrib>Khristolyubov, D. O. ; Lyubov, D. M. ; Makhrova, T. V. ; Cherkasov, A. V. ; Fukin, G. K. ; Trifonov, A. A.</creatorcontrib><description>2,2-Bis[2-(dimethylamino)-5-methylphenyl]acetic acid, Ar
2
CHCOOH (
1
) (Ar = 5-Me-2-Me
2
NC
6
H
3
), was synthesized by the carboxylation of
s[2-(dimethylamino)-5-methylphenyl]-methyl
lithium, [Ar
2
CH]Li(TMEDA), with gaseous CO
2
. The reaction of
1
with the cationic bis(alkyl) complex [(Me
3
SiCH
2
)
2
Dy(THF)
n
][BPh
4
] (2: 1 molar ratio) unexpectedly afforded the tetracarboxylate complex [Dy(O
2
CCHAr
2
)
4
(Et
2
NH
2
)
2
][BPh
4
] (
3
), whereas the trinuclear oxo cluster [Dy
3
O(O
2
CHAr
2
)
6
(THF)
4
][BPh
4
] (
4
) was prepared from [(
o
-Me
2
NC
6
H
4
CH
2
)
2
-Dy(THF)
n
][BPh
4
]. In complex
4
, three Dy
3+
cations are linked by the μ
3
-oxo oxygen atom and six bridging μ
2
-κ
1
-O:κ
1
-O’-carboxylate ligands. According to the X-ray diffraction data, NMe
2
groups of the diphenylmethanide moiety are not coordinated to Dy
3+
cations in complexes
3
and
4
.</description><identifier>ISSN: 1066-5285</identifier><identifier>EISSN: 1573-9171</identifier><identifier>DOI: 10.1007/s11172-021-3155-x</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Acetic acid ; Carboxylation ; Cations ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Full Article ; Inorganic Chemistry ; Organic Chemistry</subject><ispartof>Russian chemical bulletin, 2021, Vol.70 (5), p.818-829</ispartof><rights>Springer Science+Business Media LLC 2021</rights><rights>Springer Science+Business Media LLC 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c113x-329382c34fc7ccc4bc2daa91d7a6acbbfd0fe4583f783b427d444a94317584a93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11172-021-3155-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11172-021-3155-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Khristolyubov, D. O.</creatorcontrib><creatorcontrib>Lyubov, D. M.</creatorcontrib><creatorcontrib>Makhrova, T. V.</creatorcontrib><creatorcontrib>Cherkasov, A. V.</creatorcontrib><creatorcontrib>Fukin, G. K.</creatorcontrib><creatorcontrib>Trifonov, A. A.</creatorcontrib><title>Synthesis and structure of DyIII 2,2-bis[2-(dimethylamino)-5-methylphenyl]acetate complexes</title><title>Russian chemical bulletin</title><addtitle>Russ Chem Bull</addtitle><description>2,2-Bis[2-(dimethylamino)-5-methylphenyl]acetic acid, Ar
2
CHCOOH (
1
) (Ar = 5-Me-2-Me
2
NC
6
H
3
), was synthesized by the carboxylation of
s[2-(dimethylamino)-5-methylphenyl]-methyl
lithium, [Ar
2
CH]Li(TMEDA), with gaseous CO
2
. The reaction of
1
with the cationic bis(alkyl) complex [(Me
3
SiCH
2
)
2
Dy(THF)
n
][BPh
4
] (2: 1 molar ratio) unexpectedly afforded the tetracarboxylate complex [Dy(O
2
CCHAr
2
)
4
(Et
2
NH
2
)
2
][BPh
4
] (
3
), whereas the trinuclear oxo cluster [Dy
3
O(O
2
CHAr
2
)
6
(THF)
4
][BPh
4
] (
4
) was prepared from [(
o
-Me
2
NC
6
H
4
CH
2
)
2
-Dy(THF)
n
][BPh
4
]. In complex
4
, three Dy
3+
cations are linked by the μ
3
-oxo oxygen atom and six bridging μ
2
-κ
1
-O:κ
1
-O’-carboxylate ligands. According to the X-ray diffraction data, NMe
2
groups of the diphenylmethanide moiety are not coordinated to Dy
3+
cations in complexes
3
and
4
.</description><subject>Acetic acid</subject><subject>Carboxylation</subject><subject>Cations</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Full Article</subject><subject>Inorganic Chemistry</subject><subject>Organic Chemistry</subject><issn>1066-5285</issn><issn>1573-9171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kMtKxDAUhoMoOI4-gLuCGwWjObk06VK8Dgy4UFeDhDRNnQ69mbTQvr0dKrhydf4D_wU-hM6B3AAh8jYAgKSYUMAMhMDDAVqAkAwnIOFw0iSOsaBKHKOTEHaEEKqUWqDN21h3WxeKEJk6i0Lne9v13kVNHj2Mq9UqotcUp0XYUHyZFZXrtmNpqqJurrDA89tuXT2Wn8a6znQusk3Vlm5w4RQd5aYM7uz3LtHH0-P7_Qtevz6v7u_W2AKwATOaMEUt47mV1lqeWpoZk0AmTWxsmuYZyR0XiuVSsZRTmXHOTcIZSKEmwZboYu5tffPdu9DpXdP7eprUVLBYMA4inlwwu6xvQvAu160vKuNHDUTvGeqZoZ4Y6j1DPUwZOmfC5K2_nP9r_j_0A4wQdME</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Khristolyubov, D. O.</creator><creator>Lyubov, D. M.</creator><creator>Makhrova, T. V.</creator><creator>Cherkasov, A. V.</creator><creator>Fukin, G. K.</creator><creator>Trifonov, A. A.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2021</creationdate><title>Synthesis and structure of DyIII 2,2-bis[2-(dimethylamino)-5-methylphenyl]acetate complexes</title><author>Khristolyubov, D. O. ; Lyubov, D. M. ; Makhrova, T. V. ; Cherkasov, A. V. ; Fukin, G. K. ; Trifonov, A. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c113x-329382c34fc7ccc4bc2daa91d7a6acbbfd0fe4583f783b427d444a94317584a93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Acetic acid</topic><topic>Carboxylation</topic><topic>Cations</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Full Article</topic><topic>Inorganic Chemistry</topic><topic>Organic Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khristolyubov, D. O.</creatorcontrib><creatorcontrib>Lyubov, D. M.</creatorcontrib><creatorcontrib>Makhrova, T. V.</creatorcontrib><creatorcontrib>Cherkasov, A. V.</creatorcontrib><creatorcontrib>Fukin, G. K.</creatorcontrib><creatorcontrib>Trifonov, A. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian chemical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khristolyubov, D. O.</au><au>Lyubov, D. M.</au><au>Makhrova, T. V.</au><au>Cherkasov, A. V.</au><au>Fukin, G. K.</au><au>Trifonov, A. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and structure of DyIII 2,2-bis[2-(dimethylamino)-5-methylphenyl]acetate complexes</atitle><jtitle>Russian chemical bulletin</jtitle><stitle>Russ Chem Bull</stitle><date>2021</date><risdate>2021</risdate><volume>70</volume><issue>5</issue><spage>818</spage><epage>829</epage><pages>818-829</pages><issn>1066-5285</issn><eissn>1573-9171</eissn><abstract>2,2-Bis[2-(dimethylamino)-5-methylphenyl]acetic acid, Ar
2
CHCOOH (
1
) (Ar = 5-Me-2-Me
2
NC
6
H
3
), was synthesized by the carboxylation of
s[2-(dimethylamino)-5-methylphenyl]-methyl
lithium, [Ar
2
CH]Li(TMEDA), with gaseous CO
2
. The reaction of
1
with the cationic bis(alkyl) complex [(Me
3
SiCH
2
)
2
Dy(THF)
n
][BPh
4
] (2: 1 molar ratio) unexpectedly afforded the tetracarboxylate complex [Dy(O
2
CCHAr
2
)
4
(Et
2
NH
2
)
2
][BPh
4
] (
3
), whereas the trinuclear oxo cluster [Dy
3
O(O
2
CHAr
2
)
6
(THF)
4
][BPh
4
] (
4
) was prepared from [(
o
-Me
2
NC
6
H
4
CH
2
)
2
-Dy(THF)
n
][BPh
4
]. In complex
4
, three Dy
3+
cations are linked by the μ
3
-oxo oxygen atom and six bridging μ
2
-κ
1
-O:κ
1
-O’-carboxylate ligands. According to the X-ray diffraction data, NMe
2
groups of the diphenylmethanide moiety are not coordinated to Dy
3+
cations in complexes
3
and
4
.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11172-021-3155-x</doi><tpages>12</tpages></addata></record> |
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| issn | 1066-5285 1573-9171 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Acetic acid Carboxylation Cations Chemistry Chemistry and Materials Science Chemistry/Food Science Full Article Inorganic Chemistry Organic Chemistry |
| title | Synthesis and structure of DyIII 2,2-bis[2-(dimethylamino)-5-methylphenyl]acetate complexes |
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