Synthesis and structure of homoleptic copper complexes based on fluorinated functionalized 1,3-diketones
Mononuclear copper( ii ) complexes were synthesized based on fluorinated diketonates decorated with a carbonyl or acetal group. The X-ray diffraction data demonstrate the effect of the nature of the fluorinated substituent on the crystal structure of homoleptic copper( ii ) complexes. As opposed to...
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| Veröffentlicht in: | Russian chemical bulletin 2021-05, Vol.70 (5), p.839-846 |
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| container_title | Russian chemical bulletin |
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| creator | Saloutin, V. I. Burgart, Ya. V. Edilova, Yu. O. Slepukhin, P. A. Kudyakova, Yu. S. Bazhin, D. N. |
| description | Mononuclear copper(
ii
) complexes were synthesized based on fluorinated diketonates decorated with a carbonyl or acetal group. The X-ray diffraction data demonstrate the effect of the nature of the fluorinated substituent on the crystal structure of homoleptic copper(
ii
) complexes. As opposed to 1,2,4-triketonate, the acetal moiety of 1,3-diketonate enables intermolecular coordination to the metal centers, thereby making it possible to use 1,3-diketonate in further synthesis of heterometallic structures. |
| doi_str_mv | 10.1007/s11172-021-3157-8 |
| format | Article |
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ii
) complexes were synthesized based on fluorinated diketonates decorated with a carbonyl or acetal group. The X-ray diffraction data demonstrate the effect of the nature of the fluorinated substituent on the crystal structure of homoleptic copper(
ii
) complexes. As opposed to 1,2,4-triketonate, the acetal moiety of 1,3-diketonate enables intermolecular coordination to the metal centers, thereby making it possible to use 1,3-diketonate in further synthesis of heterometallic structures.</description><identifier>ISSN: 1066-5285</identifier><identifier>EISSN: 1573-9171</identifier><identifier>DOI: 10.1007/s11172-021-3157-8</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Carbonyls ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Coordination compounds ; Copper ; Copper compounds ; Crystal structure ; Diketones ; Fluorination ; Full Article ; Inorganic Chemistry ; Organic Chemistry ; Synthesis</subject><ispartof>Russian chemical bulletin, 2021-05, Vol.70 (5), p.839-846</ispartof><rights>Springer Science+Business Media LLC 2021</rights><rights>Springer Science+Business Media LLC 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-23c86ffccaaeec66a0374b1a9cb01c8c1e8fd75951431457bd54d79a3d049ea93</citedby><cites>FETCH-LOGICAL-c316t-23c86ffccaaeec66a0374b1a9cb01c8c1e8fd75951431457bd54d79a3d049ea93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11172-021-3157-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11172-021-3157-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27906,27907,41470,42539,51301</link.rule.ids></links><search><creatorcontrib>Saloutin, V. I.</creatorcontrib><creatorcontrib>Burgart, Ya. V.</creatorcontrib><creatorcontrib>Edilova, Yu. O.</creatorcontrib><creatorcontrib>Slepukhin, P. A.</creatorcontrib><creatorcontrib>Kudyakova, Yu. S.</creatorcontrib><creatorcontrib>Bazhin, D. N.</creatorcontrib><title>Synthesis and structure of homoleptic copper complexes based on fluorinated functionalized 1,3-diketones</title><title>Russian chemical bulletin</title><addtitle>Russ Chem Bull</addtitle><description>Mononuclear copper(
ii
) complexes were synthesized based on fluorinated diketonates decorated with a carbonyl or acetal group. The X-ray diffraction data demonstrate the effect of the nature of the fluorinated substituent on the crystal structure of homoleptic copper(
ii
) complexes. As opposed to 1,2,4-triketonate, the acetal moiety of 1,3-diketonate enables intermolecular coordination to the metal centers, thereby making it possible to use 1,3-diketonate in further synthesis of heterometallic structures.</description><subject>Carbonyls</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Copper compounds</subject><subject>Crystal structure</subject><subject>Diketones</subject><subject>Fluorination</subject><subject>Full Article</subject><subject>Inorganic Chemistry</subject><subject>Organic Chemistry</subject><subject>Synthesis</subject><issn>1066-5285</issn><issn>1573-9171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLxDAUhYsoOI7-AHcFt0Zzm-bRpQy-YMCFug5peut07DQ1SUH99Wao4MrVuQfOOVy-LDsHegWUyusAALIgtADCgEuiDrJFUkYqkHCYbioE4YXix9lJCFtKaaGUWmSb568hbjB0ITdDk4foJxsnj7lr843buR7H2NncunFEn2Q39viJIa9NwCZ3Q972k_PdYGKy7TTY2LnB9N13snDJSNO9Y3QDhtPsqDV9wLNfXWavd7cvqweyfrp_XN2siWUgIimYVaJtrTUG0QphKJNlDaayNQWrLKBqG8krDiWDksu64WUjK8MaWlZoKrbMLubd0buPCUPUWzf59FLQBWeCs0IqkVIwp6x3IXhs9ei7nfFfGqjeA9UzUJ2A6j1QrVKnmDshZYc39H_L_5d-AFGceoo</recordid><startdate>20210501</startdate><enddate>20210501</enddate><creator>Saloutin, V. I.</creator><creator>Burgart, Ya. V.</creator><creator>Edilova, Yu. O.</creator><creator>Slepukhin, P. A.</creator><creator>Kudyakova, Yu. S.</creator><creator>Bazhin, D. N.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210501</creationdate><title>Synthesis and structure of homoleptic copper complexes based on fluorinated functionalized 1,3-diketones</title><author>Saloutin, V. I. ; Burgart, Ya. V. ; Edilova, Yu. O. ; Slepukhin, P. A. ; Kudyakova, Yu. S. ; Bazhin, D. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-23c86ffccaaeec66a0374b1a9cb01c8c1e8fd75951431457bd54d79a3d049ea93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Carbonyls</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Copper compounds</topic><topic>Crystal structure</topic><topic>Diketones</topic><topic>Fluorination</topic><topic>Full Article</topic><topic>Inorganic Chemistry</topic><topic>Organic Chemistry</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Saloutin, V. I.</creatorcontrib><creatorcontrib>Burgart, Ya. V.</creatorcontrib><creatorcontrib>Edilova, Yu. O.</creatorcontrib><creatorcontrib>Slepukhin, P. A.</creatorcontrib><creatorcontrib>Kudyakova, Yu. S.</creatorcontrib><creatorcontrib>Bazhin, D. N.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian chemical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saloutin, V. I.</au><au>Burgart, Ya. V.</au><au>Edilova, Yu. O.</au><au>Slepukhin, P. A.</au><au>Kudyakova, Yu. S.</au><au>Bazhin, D. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and structure of homoleptic copper complexes based on fluorinated functionalized 1,3-diketones</atitle><jtitle>Russian chemical bulletin</jtitle><stitle>Russ Chem Bull</stitle><date>2021-05-01</date><risdate>2021</risdate><volume>70</volume><issue>5</issue><spage>839</spage><epage>846</epage><pages>839-846</pages><issn>1066-5285</issn><eissn>1573-9171</eissn><abstract>Mononuclear copper(
ii
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ii
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| subjects | Carbonyls Chemistry Chemistry and Materials Science Chemistry/Food Science Coordination compounds Copper Copper compounds Crystal structure Diketones Fluorination Full Article Inorganic Chemistry Organic Chemistry Synthesis |
| title | Synthesis and structure of homoleptic copper complexes based on fluorinated functionalized 1,3-diketones |
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