Amazing example of the retention of an unusual domed structure of PdII 3,5-di(tert-butyl)-2-oxyazobenzene in the crystal and gas phase

The structure of the newly synthesized palladium( ii ) 3,5-di( tert -butyl)-2-oxyazobenzene, PdL 2 , was determined by X-ray diffraction. The metal chelate was found to adopt an unusual domed conformation, with the trans -planar coordination unit at the top. This is the first complex of this class,...

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Veröffentlicht in:	Russian chemical bulletin 2021, Vol.70 (5), p.847-856
Hauptverfasser:	Tkachev, V. V., Bozhenko, K. V., Utenyshev, A. N., Aldoshin, S. M., Gutsev, L. G.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science Coordination Crystal structure Full Article Inorganic Chemistry Organic Chemistry Palladium Quantum chemistry Vapor phases X-ray diffraction
Online-Zugang:	Volltext
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