A new porous heterometallic metal‐organic framework for gas adsorption and luminescence sensing
A new heterometallic metal‐organic framework, namely [Zn2Sr(btc)2(H2O)3]n ⋅ x(solvent) (1 btc=1,3,5‐benzenetricarboxylate), has been solvothermally synthesized and structurally characterized. X‐ray structural analysis reveals that compound 1 exploits heterometallic trinuclear [Zn2Sr(COO)6] clusters...
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| Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 2021-05, Vol.647 (10), p.1077-1082 |
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| container_title | Zeitschrift für anorganische und allgemeine Chemie (1950) |
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| creator | Guo, Li‐Da Liu, Yi Guo, Li‐Jian Cao, Jin‐Jin Li, Wen‐Hong Liu, Ting Qiao, Sen Wang, Bing |
| description | A new heterometallic metal‐organic framework, namely [Zn2Sr(btc)2(H2O)3]n ⋅ x(solvent) (1 btc=1,3,5‐benzenetricarboxylate), has been solvothermally synthesized and structurally characterized. X‐ray structural analysis reveals that compound 1 exploits heterometallic trinuclear [Zn2Sr(COO)6] clusters as secondary building subunits, and displays a 3D framework with 1D channels along crystallographical c axis that can be simplified into a binodal (3,6)‐connected topological network. The activated sample of 1 a shows high CO2 adsorption capacity and high adsorption selectivity of CO2 over N2 at 298 K. Luminescent properties investigations indicate that 1 a can sensitively sensing of CS2 via luminescence quenching. |
| doi_str_mv | 10.1002/zaac.202000367 |
| format | Article |
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X‐ray structural analysis reveals that compound 1 exploits heterometallic trinuclear [Zn2Sr(COO)6] clusters as secondary building subunits, and displays a 3D framework with 1D channels along crystallographical c axis that can be simplified into a binodal (3,6)‐connected topological network. The activated sample of 1 a shows high CO2 adsorption capacity and high adsorption selectivity of CO2 over N2 at 298 K. 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X‐ray structural analysis reveals that compound 1 exploits heterometallic trinuclear [Zn2Sr(COO)6] clusters as secondary building subunits, and displays a 3D framework with 1D channels along crystallographical c axis that can be simplified into a binodal (3,6)‐connected topological network. The activated sample of 1 a shows high CO2 adsorption capacity and high adsorption selectivity of CO2 over N2 at 298 K. Luminescent properties investigations indicate that 1 a can sensitively sensing of CS2 via luminescence quenching.</description><subject>Adsorption</subject><subject>Carbon dioxide</subject><subject>Crystallography</subject><subject>Luminescence</subject><subject>Luminescence quenching</subject><subject>Luminescence sensing</subject><subject>Metal-organic framework</subject><subject>Optical properties</subject><subject>Porous framework</subject><subject>Selectivity</subject><subject>solvothermal synthesis</subject><subject>Structural analysis</subject><issn>0044-2313</issn><issn>1521-3749</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkLtOwzAUhi0EEqWwMltiTvE1Tsao4iZVYoGFxTrEdklJ7GA3qmDiEXhGnoSUIhiZzn-k7z9H-hA6pWRGCWHnbwD1jBFGCOG52kMTKhnNuBLlPpoQIkTGOOWH6Cil1chQIuUEQYW93eA-xDAk_GTXNobOrqFtmxp_h8_3jxCX4MfdRejsJsRn7ELES0gYTAqxXzfBY_AGt0PXeJtq62uLk_Wp8ctjdOCgTfbkZ07R_eXF3fw6W9xe3cyrRVZzqlQGBjg1pTBGCikUo05K5ZzKHTGykFAIpaCoS2WoZaLIneOPwjirOHBjyppP0dnubh_Dy2DTWq_CEP34UjPJpSCizMVIzXZUHUNK0Trdx6aD-Kop0VuNeqtR_2ocC-WusGla-_oPrR-qav7X_QLpiHlM</recordid><startdate>20210526</startdate><enddate>20210526</enddate><creator>Guo, Li‐Da</creator><creator>Liu, Yi</creator><creator>Guo, Li‐Jian</creator><creator>Cao, Jin‐Jin</creator><creator>Li, Wen‐Hong</creator><creator>Liu, Ting</creator><creator>Qiao, Sen</creator><creator>Wang, Bing</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210526</creationdate><title>A new porous heterometallic metal‐organic framework for gas adsorption and luminescence sensing</title><author>Guo, Li‐Da ; Liu, Yi ; Guo, Li‐Jian ; Cao, Jin‐Jin ; Li, Wen‐Hong ; Liu, Ting ; Qiao, Sen ; Wang, Bing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3177-ada31d94dd5454721f557ff76f0d585a8477a8c97d1e2486ff3b4dfe73a3dd9c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Adsorption</topic><topic>Carbon dioxide</topic><topic>Crystallography</topic><topic>Luminescence</topic><topic>Luminescence quenching</topic><topic>Luminescence sensing</topic><topic>Metal-organic framework</topic><topic>Optical properties</topic><topic>Porous framework</topic><topic>Selectivity</topic><topic>solvothermal synthesis</topic><topic>Structural analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guo, Li‐Da</creatorcontrib><creatorcontrib>Liu, Yi</creatorcontrib><creatorcontrib>Guo, Li‐Jian</creatorcontrib><creatorcontrib>Cao, Jin‐Jin</creatorcontrib><creatorcontrib>Li, Wen‐Hong</creatorcontrib><creatorcontrib>Liu, Ting</creatorcontrib><creatorcontrib>Qiao, Sen</creatorcontrib><creatorcontrib>Wang, Bing</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guo, Li‐Da</au><au>Liu, Yi</au><au>Guo, Li‐Jian</au><au>Cao, Jin‐Jin</au><au>Li, Wen‐Hong</au><au>Liu, Ting</au><au>Qiao, Sen</au><au>Wang, Bing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new porous heterometallic metal‐organic framework for gas adsorption and luminescence sensing</atitle><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle><date>2021-05-26</date><risdate>2021</risdate><volume>647</volume><issue>10</issue><spage>1077</spage><epage>1082</epage><pages>1077-1082</pages><issn>0044-2313</issn><eissn>1521-3749</eissn><abstract>A new heterometallic metal‐organic framework, namely [Zn2Sr(btc)2(H2O)3]n ⋅ x(solvent) (1 btc=1,3,5‐benzenetricarboxylate), has been solvothermally synthesized and structurally characterized. X‐ray structural analysis reveals that compound 1 exploits heterometallic trinuclear [Zn2Sr(COO)6] clusters as secondary building subunits, and displays a 3D framework with 1D channels along crystallographical c axis that can be simplified into a binodal (3,6)‐connected topological network. The activated sample of 1 a shows high CO2 adsorption capacity and high adsorption selectivity of CO2 over N2 at 298 K. Luminescent properties investigations indicate that 1 a can sensitively sensing of CS2 via luminescence quenching.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/zaac.202000367</doi><tpages>6</tpages></addata></record> |
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| source | Access via Wiley Online Library |
| subjects | Adsorption Carbon dioxide Crystallography Luminescence Luminescence quenching Luminescence sensing Metal-organic framework Optical properties Porous framework Selectivity solvothermal synthesis Structural analysis |
| title | A new porous heterometallic metal‐organic framework for gas adsorption and luminescence sensing |
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