Three new V‐shape dicarboxylate coordination polymers: syntheses, crystal structures and properties
Three new coordination polymers (CPs) with the formulas of [Zn2(SDBA)2(im)4]n (1), [CdCa(SDBA)2(DMA)(H2O)]n ⋅ 2n(DMA) (2) and [Cu(SDBA)0.5(μ2‐OH)]n (3) (H2SDBA=4,4’‐dicarboxybiphenyl sulfone, im=imidazole, DMA=N,N’‐dimethylacetamide) have been synthesized under hydro(solvo)thermal conditions and cha...
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Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 2021-05, Vol.647 (10), p.1110-1117 |
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description | Three new coordination polymers (CPs) with the formulas of [Zn2(SDBA)2(im)4]n (1), [CdCa(SDBA)2(DMA)(H2O)]n ⋅ 2n(DMA) (2) and [Cu(SDBA)0.5(μ2‐OH)]n (3) (H2SDBA=4,4’‐dicarboxybiphenyl sulfone, im=imidazole, DMA=N,N’‐dimethylacetamide) have been synthesized under hydro(solvo)thermal conditions and characterized by elemental analyses, powder x‐ray diffraction analyses, thermogravimetric analyses and single crystal X‐ray structural analyses. CP 1 displays a 1D double chain structure consolidated by N−H⋅⋅⋅O hydrogen bonds, which are further extended into a 3D supramolecular framework via the help of intermolecular N−H⋅⋅⋅O hydrogen bonds. CP 2 features a 2D layered structure based on 1D −[Cd−(COO)2−Ca]n− chains. Interestingly, in this 2D layer there exists large 1D channels that are occupied by the coordinated DMA molecules, coordinated water molecules and free DMA molecules. CP 3 has a 3D framework based on 1D −[Cu−(COO)(μ2‐OH)−Cu]n− chains. The luminescent properties of CPs 1 and 2, gas adsorption properties of 2 a (solvent‐free form of CP 2), and photocatalytic property of CP 3 were also investigated. |
doi_str_mv | 10.1002/zaac.202100017 |
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CP 1 displays a 1D double chain structure consolidated by N−H⋅⋅⋅O hydrogen bonds, which are further extended into a 3D supramolecular framework via the help of intermolecular N−H⋅⋅⋅O hydrogen bonds. CP 2 features a 2D layered structure based on 1D −[Cd−(COO)2−Ca]n− chains. Interestingly, in this 2D layer there exists large 1D channels that are occupied by the coordinated DMA molecules, coordinated water molecules and free DMA molecules. CP 3 has a 3D framework based on 1D −[Cu−(COO)(μ2‐OH)−Cu]n− chains. The luminescent properties of CPs 1 and 2, gas adsorption properties of 2 a (solvent‐free form of CP 2), and photocatalytic property of CP 3 were also investigated.</description><identifier>ISSN: 0044-2313</identifier><identifier>EISSN: 1521-3749</identifier><identifier>DOI: 10.1002/zaac.202100017</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Coordination polymer ; Coordination polymers ; Crystal structure ; Dimethyl acetamide ; Free form ; Gas sorption ; Hydrogen bonds ; Imidazole ; Optical properties ; Photocatalysis ; Single crystals ; Supramolecular framework ; Supramolecular frameworks ; Water chemistry</subject><ispartof>Zeitschrift für anorganische und allgemeine Chemie (1950), 2021-05, Vol.647 (10), p.1110-1117</ispartof><rights>2021 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3177-ebae7fca50fee456b3908e9e55cd4ac888df48b6cb330e60bd5eb66cc8bef84d3</citedby><cites>FETCH-LOGICAL-c3177-ebae7fca50fee456b3908e9e55cd4ac888df48b6cb330e60bd5eb66cc8bef84d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fzaac.202100017$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fzaac.202100017$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Chen, Yu‐Hong</creatorcontrib><title>Three new V‐shape dicarboxylate coordination polymers: syntheses, crystal structures and properties</title><title>Zeitschrift für anorganische und allgemeine Chemie (1950)</title><description>Three new coordination polymers (CPs) with the formulas of [Zn2(SDBA)2(im)4]n (1), [CdCa(SDBA)2(DMA)(H2O)]n ⋅ 2n(DMA) (2) and [Cu(SDBA)0.5(μ2‐OH)]n (3) (H2SDBA=4,4’‐dicarboxybiphenyl sulfone, im=imidazole, DMA=N,N’‐dimethylacetamide) have been synthesized under hydro(solvo)thermal conditions and characterized by elemental analyses, powder x‐ray diffraction analyses, thermogravimetric analyses and single crystal X‐ray structural analyses. CP 1 displays a 1D double chain structure consolidated by N−H⋅⋅⋅O hydrogen bonds, which are further extended into a 3D supramolecular framework via the help of intermolecular N−H⋅⋅⋅O hydrogen bonds. CP 2 features a 2D layered structure based on 1D −[Cd−(COO)2−Ca]n− chains. Interestingly, in this 2D layer there exists large 1D channels that are occupied by the coordinated DMA molecules, coordinated water molecules and free DMA molecules. CP 3 has a 3D framework based on 1D −[Cu−(COO)(μ2‐OH)−Cu]n− chains. The luminescent properties of CPs 1 and 2, gas adsorption properties of 2 a (solvent‐free form of CP 2), and photocatalytic property of CP 3 were also investigated.</description><subject>Coordination polymer</subject><subject>Coordination polymers</subject><subject>Crystal structure</subject><subject>Dimethyl acetamide</subject><subject>Free form</subject><subject>Gas sorption</subject><subject>Hydrogen bonds</subject><subject>Imidazole</subject><subject>Optical properties</subject><subject>Photocatalysis</subject><subject>Single crystals</subject><subject>Supramolecular framework</subject><subject>Supramolecular frameworks</subject><subject>Water chemistry</subject><issn>0044-2313</issn><issn>1521-3749</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkM1KxDAUhYMoOI5uXQfc2po0SX_cDYN_MOBmdOEmJOkt06HT1CRlrCsfwWf0SewwoktXlwvfdw4chM4piSkhydW7UiZOSDI-hGYHaEJFQiOW8eIQTQjhPEoYZcfoxPv1DiFCTBAsVw4At7DFz18fn36lOsBlbZTT9m1oVABsrHVl3apQ2xZ3thk24Pw19kMbVuDBX2LjBh9Ug31wvQm9A49VW-LO2Q5cqMGfoqNKNR7Ofu4UPd3eLOf30eLx7mE-W0SG0SyLQCvIKqMEqQC4SDUrSA4FCGFKrkye52XFc50azRiBlOhSgE5TY3INVc5LNkUX-9yx-rUHH-Ta9q4dK2UimOCEF6IYqXhPGWe9d1DJztUb5QZJidxNKXdTyt8pR6HYC9u6geEfWr7MZvM_9xusvXxy</recordid><startdate>20210526</startdate><enddate>20210526</enddate><creator>Chen, Yu‐Hong</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210526</creationdate><title>Three new V‐shape dicarboxylate coordination polymers: syntheses, crystal structures and properties</title><author>Chen, Yu‐Hong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3177-ebae7fca50fee456b3908e9e55cd4ac888df48b6cb330e60bd5eb66cc8bef84d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Coordination polymer</topic><topic>Coordination polymers</topic><topic>Crystal structure</topic><topic>Dimethyl acetamide</topic><topic>Free form</topic><topic>Gas sorption</topic><topic>Hydrogen bonds</topic><topic>Imidazole</topic><topic>Optical properties</topic><topic>Photocatalysis</topic><topic>Single crystals</topic><topic>Supramolecular framework</topic><topic>Supramolecular frameworks</topic><topic>Water chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Yu‐Hong</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Yu‐Hong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Three new V‐shape dicarboxylate coordination polymers: syntheses, crystal structures and properties</atitle><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle><date>2021-05-26</date><risdate>2021</risdate><volume>647</volume><issue>10</issue><spage>1110</spage><epage>1117</epage><pages>1110-1117</pages><issn>0044-2313</issn><eissn>1521-3749</eissn><abstract>Three new coordination polymers (CPs) with the formulas of [Zn2(SDBA)2(im)4]n (1), [CdCa(SDBA)2(DMA)(H2O)]n ⋅ 2n(DMA) (2) and [Cu(SDBA)0.5(μ2‐OH)]n (3) (H2SDBA=4,4’‐dicarboxybiphenyl sulfone, im=imidazole, DMA=N,N’‐dimethylacetamide) have been synthesized under hydro(solvo)thermal conditions and characterized by elemental analyses, powder x‐ray diffraction analyses, thermogravimetric analyses and single crystal X‐ray structural analyses. CP 1 displays a 1D double chain structure consolidated by N−H⋅⋅⋅O hydrogen bonds, which are further extended into a 3D supramolecular framework via the help of intermolecular N−H⋅⋅⋅O hydrogen bonds. CP 2 features a 2D layered structure based on 1D −[Cd−(COO)2−Ca]n− chains. Interestingly, in this 2D layer there exists large 1D channels that are occupied by the coordinated DMA molecules, coordinated water molecules and free DMA molecules. CP 3 has a 3D framework based on 1D −[Cu−(COO)(μ2‐OH)−Cu]n− chains. The luminescent properties of CPs 1 and 2, gas adsorption properties of 2 a (solvent‐free form of CP 2), and photocatalytic property of CP 3 were also investigated.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/zaac.202100017</doi><tpages>8</tpages></addata></record> |
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subjects | Coordination polymer Coordination polymers Crystal structure Dimethyl acetamide Free form Gas sorption Hydrogen bonds Imidazole Optical properties Photocatalysis Single crystals Supramolecular framework Supramolecular frameworks Water chemistry |
title | Three new V‐shape dicarboxylate coordination polymers: syntheses, crystal structures and properties |
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